scholarly journals Experimental Evaluation of Modified Sulfur Concrete for Achieving Sustainability in Industry Applications

2018 ◽  
Vol 11 (1) ◽  
pp. 70 ◽  
Author(s):  
Margareth Dugarte ◽  
Gilberto Martinez-Arguelles ◽  
Jaime Torres
Keyword(s):  
Compressive Strength ◽  
Chemical Resistance ◽  
Chemical Properties ◽  
Industrial Applications ◽  
Northern Region ◽  
Significant Loss ◽  
Experimental Program ◽  
Portland Cement Concrete ◽  
Chemical Attack ◽  
Short Service Life

Portland cement concrete (PCC) has been the most widely used concrete in the construction industry. However, PCC has a short service life under some aggressive environments, leading to the need of costly repairs. The purpose of this research was to implement local materials to produce a modified sulfur concrete (MSC) with better performance in industrial applications. Several modified sulfur concrete mixtures were prepared using natural aggregates from the northern region of Colombia, and sulfur cement by combination of sulfur with a modifier, with the objective of achieving the best performance based on mechanical strength and chemical resistance. To achieve this purpose, an experimental program based on a k-factorial design was used to determine the optimal mix design based on the results of the compressive strength. The mixture presenting the best results was then examined further with standardized tests to determine its physical, mechanical, and chemical properties (compressive strength, abrasion resistance, bulk density, absorption, and chemical resistance). Final results showed that the sulfur concrete mixture is very resistant to chemical attack and an outstanding substitute for PCC. The results indicated that there is no significant loss in weight and no relevant variation in compressive strength after the specimens were immersed in sulfuric acid and sulfate solutions. In addition, similar results were obtained for the slabs located in chemicals plants whose conditions were assessed during a 60-day period of exposure.

scholarly journals Evaluation of Thermal Effects on Slag Cement Concrete’s Strength Properties

2021 ◽  
Vol 1 (3) ◽  
pp. 11-15
Author(s):  
Michael Tiza
Keyword(s):  
Compressive Strength ◽  
Thermal Resistance ◽  
Concrete Strength ◽  
Strength Loss ◽  
Strength Properties ◽  
Industrial Applications ◽  
Significant Loss ◽  
Cement Concrete ◽  
Slag Cement ◽  
Hardness Property

The physical, chemical, and mechanical characteristics of concrete change with heat-fire. The effect of thermal load on Slag cement concrete output must be measured because of the crucial role of thermal resistance in concrete structure performance and operation. This work examines the thermal resistance of Slag cement concrete. The concrete cubes were produced and cured for 28 days and then subjected to varying temperatures range of 100°C, 150°C, 200°C, 250°C, and 300°C. Hardness and compressive strength were measured at 30, 45, and 60 minutes; the sample results were compared to those of ordinary Portland cement used for the study. The findings of this experiment demonstrate that strength loss was 0.45% at 100 °C, 1.75% at 150 °C, 2.67% at 200°C, 5.98% at 250°C and 12.04 % at 300 °C, the hardness property increased from 100° to 150°C but decreased with higher temperatures. However, average concrete loss at 300 °C exceeds 20 percent of its compressive strength. This means that higher temperatures have adverse effects on concrete strength. From the test, however, it has been noted that there was an insignificant loss of strength of concrete at temperatures below 250°C and however, above 250 °C, a significant loss of concrete strength was observed. The results indicate that slag concrete has a significantly higher thermal resistance potential than traditional concrete and can be used even in industrial applications.

scholarly journals Modificación de las propiedades de matrices cementantes mediante la adición de partículas de nanosílice

2016 ◽  
Vol 6 (2) ◽  
pp. 101-115
Author(s):  
L. Y. Gómez-Zamorano ◽  
C. E. Castillo-Linton
Keyword(s):  
Compressive Strength ◽  
Silica Nanoparticles ◽  
Chemical Properties ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Chemical Attack ◽  
Nanosilica Particles ◽  
And Chemical Properties

Modificación de las propiedades de matrices cementantes mediante la adición de partículas de nanosíliceRESUMENEste trabajo de investigación evaluó el efecto de la adición de nanopartículas de sílice (NS) a dos matrices cementantes, base cemento portland ordinario y cemento sulfoaluminoso, con el fin de establecer su influencia en las propiedades mecánicas y de resistencia química de dichos materiales. Para esto, se adicionaron las NS en dosificaciones de 0.30% a 5.0% en peso. Los resultados indicaron que la resistencia a la compresión y al ataque químico por sulfatos, se ven mejoradas debido a la adición de NS. La resistencia al ataque químico por sulfatos se mejoró de forma importante con la presencia de NS en comparación al cemento sin adiciones. Este resultado sugiere que ambas matrices presentaron una mayor densificación.Palabras claves: Reactividad, materiales cementosos suplementarios. Effect of the addition of nanosilica particles on the properties of two cementitious matricesABSTRACTThis research focused on evaluating the effect of adding silica nanoparticles (NS) to two cementitious matrices, as ordinary portland and sulfoaluminate cement, in order to establish their influence on the mechanical and chemical properties. To conduct this evaluation, the NS were added in dosages of 0.30-to-5.0% by mass relative to cement. The results indicated that the compressive strength and resistance to chemical attack by sulfates were improved due to the addition of silica nanoparticles, in both matrices. Finally, the resistance to chemical attack by sulfates showed an improvement with the addition of silica nanoparticles when comparing with pure cement, suggesting an increase in the densification.Keywords: Reactivity, supplementary cementitious materials. Modificação das propriedades de matrizes cimentícias através da adição de partículas de nanosílicaRESUMOEste estudo avaliou o efeito da adição de nanopartículas de sílica (NS) em duas matrizes cimentícias, base cimento Portland comum e cimento sulfoaluminoso, a fim de estabelecer a sua influência sobre as propriedades de resistência mecânica e química dos referidos materiais. Para isso, foram adicionadas as NS em dosagens de 0,30% a 5,0% em massa. Os resultados indicaram que a resistência à compressão e ao ataque químico por sulfatos são aumentadas devido à adição do NS. A resistência ao ataque químico por sulfatos melhorou significativamente com a presença de NS em comparação com o cimento sem adições. Este resultado sugere que ambas as matrizes apresentaram uma maior densificação.Palavras-clave: Reatividade, materiais cimentícios suplementares.

scholarly journals The Flexural and Compressive Strength of Recycled Concrete

2018 ◽  
Vol 2 (1) ◽  
pp. 24-27
Author(s):  
Nouf Jassim Alsabbagh
Keyword(s):  
Compressive Strength ◽  
Recycled Concrete ◽  
Recycled Aggregates ◽  
Partial Replacement ◽  
Experimental Program ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Sustainable Solutions ◽  
Coarse Aggregates ◽  
Construction And Demolition Wastes

Limitations in natural resources have drawn the necessity to develop sustainable solutions for the future of the concrete industry. Kuwait has joined the world’s effort to encourage recycling by reducing the amounts of construction and demolition wastes sent to landfills, through the usage of recycled aggregates in Portland Cement concrete mixes. In this research, an experimental program was designed to test the effect of substituting virgin coarse aggregates with recycled aggregates obtained from demolished concrete. Four different concrete mixes were designed at a strength of 30MPa, with different partial replacement percentages of 100%, 50%, and 0%. All mixes were tested for workability. Samples were cast from each mix and tested for the flexural strength as well as the compressive strength; all results were compared to a control mix. Results demonstrated that in spite of the slight effect noted on both flexural and compressive strength, good quality concrete can still be achieved.

Surface Modification of Poly (alkyl/Arylphosphazene) Thin Films

2000 ◽  
Vol 629 ◽  
Author(s):  
John V. St. John ◽  
Patty Wisian-Neilson
Keyword(s):  
Thin Films ◽  
Surface Modification ◽  
Chemical Resistance ◽  
Chemical Properties ◽  
Inorganic Polymers ◽  
Thin Polymer Films ◽  
Hydrophilic Interactions ◽  
Carboxylic Acid Groups ◽  
Polymer Interface ◽  
Thin Polymer

ABSTRACTPoly (methylphenylphosphazene) (PMPP) is an example of a unique class of inorganic polymers with alternating – (P=N)– backbones. Chemical modification of bulk PMPP can result in changes of physical properties such as chemical resistance, onset temperature of thermal degradation, elasticity, and flexibility. Surface modification of PMPP allows tailoring of the chemical properties at the polymer interface while maintaining the integrity of the bulk polymer. In this research, PMPP thin films were treated to form carboxylate or carboxylic acid groups at the surface. Surface modification was monitored by following changes in contact angle. The hydrophobic/hydrophilic interactions of carboxylated PMPP surfaces allow for mesoscale interactions of thin polymer films.

Isatin: A Scaffold with Innumerable Biodiversity

2020 ◽  
Vol 20 ◽  
Author(s):  
Priyobrata Nath ◽  
Agnish Mukherjee ◽  
Sougata Mukherjee ◽  
Sabyasachi Banerjee ◽  
Samarpita Das ◽  
...  
Keyword(s):  
Biological Effects ◽  
Scientific Information ◽  
Research Work ◽  
Chemical Properties ◽  
Industrial Applications ◽  
Biologically Relevant ◽  
Extensive Information ◽  
Relevant Compound ◽  
A Minor ◽  
Clinical Conditions

: Isatin is an endogenous and a significant category of fused heterocyclic component, widely been a part of several potential biologically useful synthetics. Since its discovery, tons of research work has been conducted with respect to the synthesis, chemical properties, and biological and industrial applications. It contains indole nucleus having both lactam and keto moiety which while being a part of a molecular framework exerted several biological effects, viz.; antimicrobial, antitubercular, anticonvulsant, anticancer etc. Isatin derivatives are synthetically significant substrates, which can be utilized for the synthesis of huge diversified chemical entities of which few members emerged to be a drug. The reason for this review is to provide extensive information pertaining to the chemistry and its significance in altering several pathological states of isatin and its derivatives. A Structure Activity Relationships study thus developed through a gamut of scientific information indicates the importance of mostly electron withdrawing groups, halogens, nitro, alkoxy and to a minor extent groups with positive inductive effects, such as methyl at position 1, 5, 6 and 7 of isatin in alleviating several clinical conditions. It is also observed from the survey that the presence of two oxo groups at position 2 and 3 sometimes become insignificant as fusion with a heterocycle at those position resulted in a biologically relevant compound.

Oxa-Michael polyaddition of vinylsulfonylethanol for aliphatic polyethersulfones

2021 ◽  
Author(s):  
Nicole Ziegenbalg ◽  
Ruth Lohwasser ◽  
Giovanni D’Andola ◽  
Torben Adermann ◽  
Johannes Christopher Brendel
Keyword(s):  
Refractive Index ◽  
High Temperature ◽  
Flame Retardant ◽  
Chemical Resistance ◽  
High Refractive Index ◽  
Industrial Applications ◽  
Interesting Class ◽  
The Common ◽  
Flame Retardant Properties

Polyethersulfones are an interesting class of polymers for industrial applications due to their unusual properties such as a high refractive index, flame-retardant properties, high temperature and chemical resistance. The common...

Micro-Ribbons and Micro-Wires Silica Synthesis Using Bottom-Top Technique

2020 ◽  
Vol 1008 ◽  
pp. 33-38
Author(s):  
Marwa Nabil ◽  
Hussien A. Motaweh
Keyword(s):  
Selection Process ◽  
Chemical Properties ◽  
Industrial Applications ◽  
Preparation Process ◽  
Pure Silica ◽  
One Step ◽  
Materials Used ◽  
Sonication Technique ◽  
Silica Synthesis ◽  
Physical And Chemical

Silica is one of the most important materials used in many industries. The basic factor on which the selection process depends is the structural form, which is dependent on the various physical and chemical properties. One of the common methods in preparing pure silica is that it needs more than one stage to ensure the preparation process completion. The goal of this research is studying the nucleation technique (Bottom-top) for micro-wires and micro-ribbons silica synthesis. The silica nanoand microstructures are prepared using a duality (one step); a combination of alkali chemical etching process {potassium hydroxide (3 wt %) and n-propanol (30 Vol %)} and the ultra-sonication technique. In addition, the used materials in the preparation process are environmentally friendly materials that produce no harmful residues. The powder product is characterized using XRD, FTIR, Raman spectrum and SEM for determining the shape of architectures. The most significant factor of the nucleation mechanism is the sonication time of silica powder production during the dual technique. The product stages are as follows; silica nanoparticles (21-38 nm), nanoclusters silica (46 – 67 nm), micro-wires silica (1.17 – 6.29 μm), and micro-ribbons silica (19.4 – 54.1 μm). It's allowing for use in environmental applications (multiple wastewater purification, multiple uses in air filters, as well as many industrial applications).

Ultrasonic Test on Recycled Concrete: Relationship among Ultrasonic Waves Velocity, Compressive Strength and Elastic Modulus

2014 ◽  
Vol 894 ◽  
pp. 45-49 ◽  
Author(s):  
Luisa Pani ◽  
Lorena Francesconi
Keyword(s):  
Compressive Strength ◽  
Elastic Modulus ◽  
Ultrasonic Wave ◽  
Ultrasonic Test ◽  
Ultrasonic Waves ◽  
Recycled Concrete ◽  
Recycled Aggregates ◽  
Experimental Program ◽  
Static Modulus ◽  
Cylindrical Samples

In this paper an experimental program has been carried out in order to compare compressive strength fcand elastic static modulus Ecof recycled concrete with ultrasonic waves velocity Vp, to establish the possibility of employing nondestructive ultrasonic tests to qualify recycled concrete. 9 mix of concrete with different substitution percentage of recycled aggregates instead of natural ones and 27 cylindrical samples have been made. At first ultrasonic tests have been carried out on cylindrical samples, later elastic static modulus Ecand compressive strength fchave been experimentally evaluated. The dynamic elastic modulus Edhas been determined in function of ultrasonic wave velocity Vp; furthermore the correlations among Ed, Ec, fce Vphave been determined. It has been demonstrated that ultrasonic tests are suitable for evaluating different deformative and resisting concrete performances even when variations are small.

scholarly journals Waste Tire Particles and Gamma Radiation as Modifiers of the Mechanical Properties of Concrete

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Eduardo Sadot Herrera-Sosa ◽  
Gonzalo Martínez-Barrera ◽  
Carlos Barrera-Díaz ◽  
Epifanio Cruz-Zaragoza
Keyword(s):  
Mechanical Properties ◽  
Gamma Radiation ◽  
Chemical Properties ◽  
Plain Concrete ◽  
Cement Matrix ◽  
Portland Cement Concrete ◽  
High Concentration ◽  
Good Tool ◽  
Waste Tire ◽  
Physical And Chemical

In polymer reinforced concrete, the Young’s modulus of both polymers and cement matrix is responsible for the detrimental properties of the concrete, including compressive and tensile strength, as well as stiffness. A novel methodology for solving such problems is based on use of ionizing radiation, which has proven to be a good tool for improvement on physical and chemical properties of several materials including polymers, ceramics, and composites. In this work, particles of 0.85 mm and 2.80 mm obtained from waste tire were submitted at 250 kGy of gamma radiation in order to modify their physicochemical properties and then used as reinforcement in Portland cement concrete for improving mechanical properties. The results show diminution on mechanical properties in both kinds of concrete without (or with) irradiated tire particles with respect to plain concrete. Nevertheless such diminutions (from 2 to 16%) are compensated with the use of high concentration of waste tire particles (30%), which ensures that the concrete will not significantly increase the cost.

Effects of Loading Percentage of Polyurethane in Lightweight Concrete

2013 ◽  
Vol 357-360 ◽  
pp. 1082-1085 ◽  
Author(s):  
Kamarul Aini Mohd Sari ◽  
Sohif Mat ◽  
Khairiah Haji Badri ◽  
Muhammad Fauzi Mohd Zain
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Lightweight Concrete ◽  
Palm Kernel ◽  
Physical And Mechanical Properties ◽  
Concrete Mixture ◽  
Experimental Program ◽  
Polymer Concrete ◽  
Optimum Level ◽  
Methylene Diphenyl Diisocyanate

An experimental program was performed to obtain the density, compressive strength, and thermal conductivity of palm-based lightweight concrete. Palm-based polyurethane (PU) particles were used as lightweight aggregates in creating concrete systems. Concrete systems contain palm kernel oil-based polyol (PKO-p) reacted with 2,4-methylene diphenyl diisocyanate (MDI). In this study, polymer concrete was improved to achieve the optimum level of PU with the lowest possible density. The PU particles in the concrete mixture comprised of 1% to 5% w/w with density of less than 1800 kg/m3. The PU particles were 5 mm in size. The ratio of PKO-p to MDI was set at 1:1 and the loading of the concrete mixture was set at 3% w/w to produce lightweight concrete. The resulting concrete has excellent compressive strength (17.5 MPa) and thermal conductivity (0.24 W/mK). Results show that the PU particle dosage has the most significant effect on the physical and mechanical properties of concrete.

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