scholarly journals Effect of Mechanical Pre-Treatment of the Agricultural Substrates on Yield of Biogas and Kinetics of Anaerobic Digestion

2018 ◽  
Vol 10 (10) ◽  
pp. 3669 ◽  
Author(s):  
Józef Szlachta ◽  
Hubert Prask ◽  
Małgorzata Fugol ◽  
Adam Luberański
Keyword(s):  
Anaerobic Digestion ◽  
Biogas Production ◽  
Gompertz Model ◽  
Model Parameters ◽  
Production Potential ◽  
Pre Treatment ◽  
Sorghum Silage ◽  
Kinetics Of ◽  
Degree Of Fragmentation ◽  
Modified Gompertz Model

The effect of mechanical pre-treatment of nine different agricultural substrates minced to particle sizes of 1.5 mm, 5 mm and 10 mm on biogas and methane yields and fermentation kinetics was investigated. The results showed, that for five of the nine tested substrates (grass, Progas rye, Palazzo rye, tall wheatgrass, beet), a higher biogas production was obtained for the degree of fragmentation of 10 mm compared to fragmentation of 5 mm and 1.5 mm. For fragmentation of 5 mm, the highest biogas production was achieved for sorghum silage, Atletico maize and Cannavaro maize—649.80, 735.59 and 671.83 Nm3/Mg VS, respectively. However, for the degree of fragmentation of 1.5 mm, the highest biogas production (510.43 Nm3/Mg volatile solid (VS)) was obtained with Topinambur silage. The modified Gompertz model fitted well the kinetics of anaerobic digestion of substrates and show a significant dependence of the model parameters Hmax (biogas production potential) and Rmax (maximum rate of biogas production) on the degree of substrate fragmentation.

scholarly journals Effects of Salt on Anaerobic Digestion of Food Waste with Different Component Characteristics and Fermentation Concentrations

Energies ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 3571 ◽  
Author(s):  
Li ◽  
Huang ◽  
Liu ◽  
Huang ◽  
Maurer ◽  
...  
Keyword(s):  
Anaerobic Digestion ◽  
Food Waste ◽  
Food Processing ◽  
Biogas Production ◽  
Gompertz Model ◽  
Salt Addition ◽  
Vs Removal ◽  
Processing Effects ◽  
Kinetics Of ◽  
Modified Gompertz Model

Effects of salt on anaerobic digestion are dosage-dependent. As salt is a widely used condiment in food processing, effects of salt are bound to be considered when food waste is digested. In this study, salt addition effects (0, 2, 4, 6, 9, 12 g∙L−1) on biogas and methane yields and kinetics of biogas production were researched. Meanwhile, component characteristics (food waste featured in carbohydrate, protein and fat, respectively) and fermentation concentrations (5 and 8 gVS∙L−1) were also taken into consideration. Results showed that 2–4 g∙L−1 salt addition was the optimal addition dosage for AD systems as they not only have the maximum biogas and methane yields, but also the maximum vs. removal in most cases. Also, according to the results of a modified Gompertz model, which is used to predict biogas and methane production rates, suitable salt addition can accelerate biogas production, improving the maximum biogas production rate (Rmax). Factorial design (2 × 2) proved that interaction of salt and fermentation concentrations was significant for food waste featured with carbohydrate and with protein (p <0.05). High salt addition and fermentation concentration can break the AD system when the feeding material was food waste featured with carbohydrate, but for food waste featured with protein, interaction of fermentation concentrations and salt addition can alleviate inhibition degrees.

scholarly journals Application of Modified Gompertz Model to Study on Biogas production from middle temperature co-digestion of pig manure and dead pigs

2019 ◽  
Vol 118 ◽  
pp. 03022
Author(s):  
Hongguang Zhu ◽  
Jing Yang ◽  
Cheng Xiaowei
Keyword(s):  
Anaerobic Digestion ◽  
Degradation Rate ◽  
Biogas Production ◽  
Raw Materials ◽  
Gompertz Model ◽  
Gas Production ◽  
Raw Material ◽  
Pig Manure ◽  
Middle Temperature ◽  
Modified Gompertz Model

The dead pig is an organic waste rich in oil and protein, and is an ideal anaerobic digestion raw material. This study based on single factor ANOVA and Modified Gompertz model. It investigated the effects of the ratio of dead pigs on biogas production by middle temperature co-digestion of pig manure and dead pigs. And the biogas production potential was determined. The results showed that there was no significant correlation between the ratio of dead pigs and the biogas production. The ratio would significantly affect the average methane content and degradation rate. When the addition ratio was in the range of 3 to 15%, the biogas production was between 191.39 and 202.44 (L/kg VS). The average contents of methane were 50.67%, 50.35%, 41.83%, 45.53% and 44.57%, respectively. The time required to reach 80% of the biogas production was 28, 34, 36, 65 and 63 days, respectively. The degradation rate of the raw materials was generally decreased with the increase of the addition ratio. The results of Modified Gompertz model fitting showed that the mixed raw materials had a fully anaerobic digestion with high utilization rate and short hysteresis in the range of 0 ~ 9%. Therefore, a hydraulic retention time (HRT) of 30 days and the addition ratio was in the range of 0 to 6% could be recommended for a continuous digester. It could get a better gas production and higher raw material utilization.

scholarly journals Effects of Substrate to Inoculum Ration on Biogas Production from Anaerobic Co-digestion of Office Paper and Cow Manure

2019 ◽  
pp. 1-15
Author(s):  
Autumn R. Elniski ◽  
Siddharth G. Chatterjee ◽  
Chanchal Mondal ◽  
Klaus Doelle
Keyword(s):  
Anaerobic Digestion ◽  
Biogas Production ◽  
Time Lag ◽  
Industrial Applications ◽  
Process Models ◽  
Future Research ◽  
Model Parameters ◽  
Cow Manure ◽  
Production Potential ◽  
Office Paper

Anaerobic digestion can utilize renewable resources to produce energy in the form of biogas. Cow manure inoculum contains the microorganisms needed for this application and unrecycled paper waste can be used as a substrate. The use of these feedstocks together is not well studied. Finding ideal operating parameters and modelling biogas production is vital for future integration of anaerobic digestion. The use of various models when examining anaerobic digestion is important to ensure the best models are used for future research and industrial applications. Office paper and cow manure were combined at the different substrate to inoculum ratios with a total solids content of 6% at 38.4°C for 15 days. Four models (Time-Lag, No-Lag, Modified Gompertz, and Modified Logistic) were fitted to the experimental data to find which model best represented each biogas production process. Models varied in the accuracy of their fit to the data and no single model had the lowest RMSE values for each treatment. The digester containing a paper to manure ratio of 2:1 produced the most biogas (82 mL biogas/g VS), but the 5:1 reactor had the greatest biogas production potential over a longer period based on the model parameters (maximum cumulative biogas yield and biogas production potential). More biogas was produced in this study compared to other works reported in the literature, showing that this combination of co-digestion substrates could be expanded upon in the future. New models need to be examined or developed for these systems to better represent this co-digestion process for future research and commercial applications.

scholarly journals Performance and Kinetic Model of a Single-Stage Anaerobic Digestion System Operated at Different Successive Operating Stages for the Treatment of Food Waste

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 600 ◽  
Author(s):  
Sagor Kumar Pramanik ◽  
Fatihah Binti Suja ◽  
Mojtaba Porhemmat ◽  
Biplob Kumar Pramanik
Keyword(s):  
Experimental Data ◽  
Anaerobic Digestion ◽  
Kinetic Model ◽  
Removal Efficiency ◽  
Food Waste ◽  
Biogas Production ◽  
Gompertz Model ◽  
Methane Yield ◽  
Biogas Yield ◽  
Modified Gompertz Model

A large quantity of food waste (FW) is generated annually across the world and results in environmental pollution and degradation. This study investigated the performance of a 160 L anaerobic biofilm single-stage reactor in treating FW. The reactor was operated at different hydraulic retention times (HRTs) of 124, 62, and 35 days under mesophilic conditions. The maximum biogas and methane yield achieved was 0.934 L/g VSadded and 0.607 L CH4/g VSadded, respectively, at an HRT of 124 days. When HRT decreased to 62 days, the volatile fatty acid (VFA) and ammonia accumulation increased rapidly whereas pH, methane yield, and biogas yield decreased continuously. The decline in biogas production was likely due to shock loading, which resulted in scum accumulation in the reactor. A negative correlation between biogas yield and volatile solid (VS) removal efficiency was also observed, owing to the floating scum carrying and urging the sludge toward the upper portion of the reactor. The highest VS (79%) and chemical oxygen demand (COD) removal efficiency (80%) were achieved at an HRT of 35 days. Three kinetic models—the first-order kinetic model, the modified Gompertz model, and the logistic function model—were used to fit the cumulative biogas production experimental data. The kinetic study showed that the modified Gompertz model had the best fit with the experimental data out of the three models. This study demonstrates that the stability and performance of the anaerobic digestion (AD) process, namely biogas production rate, methane yield, intermediate metabolism, and removal efficiency, were significantly affected by HRTs.

Alkali pre-treatment of Sorghum Moench for biogas production

2013 ◽  
Vol 67 (9) ◽  
Author(s):  
Karina Michalska ◽  
Stanisław Ledakowicz
Keyword(s):  
Anaerobic Digestion ◽  
Chemical Oxygen Demand ◽  
Volatile Fatty Acids ◽  
Biogas Production ◽  
Oxygen Demand ◽  
Total Phenolic ◽  
Methane Generation ◽  
Pre Treatment ◽  
Alkali Hydrolysis ◽  
Almost All

AbstractThis work studies the influence of the alkali pre-treatment of Sorghum Moench — a representative of energy crops used in biogas production. Solutions containing various concentrations of sodium hydroxide were used to achieve the highest degradation of lignocellulosic structures. The results obtained after chemical pre-treatment indicate that the use of NaOH leads to the removal of almost all lignin (over 99 % in the case of 5 mass % NaOH) from the biomass, which is a prerequisite for efficient anaerobic digestion. Several parameters, such as chemical oxygen demand, total organic carbon, total phenolic content, volatile fatty acids, and general nitrogen were determined in the hydrolysates thus obtained in order to define the most favourable conditions. The best results were obtained for the Sorghum treated with 5 mass % NaOH at 121°C for 30 min The hydrolysate thus achieved consisted of high total phenolic compounds concentration (ca. 4.7 g L−1) and chemical oxygen demand value (ca. 45 g L−1). Although single alkali hydrolysis causes total degradation of glucose, a combined chemical and enzymatic pre-treatment of Sorghum leads to the release of large amounts of this monosaccharide into the supernatant. This indicates that alkali pre-treatment does not lead to complete cellulose destruction. The high degradation of lignin structure in the first step of the pre-treatment rendered the remainder of the biomass available for enzymatic action. A comparison of the efficiency of biogas production from untreated Sorghum and Sorghum treated with the use of NaOH and enzymes shows that chemical hydrolysis improves the anaerobic digestion effectiveness and the combined pre-treatment could have great potential for methane generation.

scholarly journals Kinetics of Anaerobic Digestion of Dairy Fat Waste with Saponification Pre-Treatment

2019 ◽  
Vol 13 (2) ◽  
pp. 112 ◽  
Author(s):  
Rifki Wahyu Kurnianto ◽  
Wiratni Budhijanto ◽  
Rochim Bakti Cahyono
Keyword(s):  
Anaerobic Digestion ◽  
Lipid Content ◽  
Alternative Energy ◽  
Organic Waste ◽  
High Lipid Content ◽  
Dairy Fat ◽  
High Lipid ◽  
Pre Treatment ◽  
Kinetics Of ◽  
Floating Layer

Anaerobic digestion has been an attractive field of research in the era of energy crisis. Biogas, which is the product of anaerobic digestion, provides alternative energy, while at the same time it also prevents pollution due to organic waste accumulation. Among various organic wastes, dairy fat waste is a potential substrate for anaerobic digestion. Fat waste has high theoretical biogas potential because of its high lipid content. However, anaerobic digestion of organic waste with high lipid content is quite challenging. The main obstacle in anaerobic digestion of fat waste is its tendency to form insoluble floating layer on top of the liquid phase. This phenomenon hinders the access of hydrolytic bacteria to the substrate. Saponification is one of the methods to increase the solubility of the floating layer and hence to improve the availability of substrate for the bacteria. Saponification changes the lipid content into soap which has both polar and non-polar functional groups and the polar side will increase the solubility of the substrate in water. This study evaluated the effect of different dosage of base added as the reactant during saponification pre-treatment on the productivity of anaerobic digestion of dairy fat waste. The kinetics of the anaerobic digestion process was analyzed by mean of mathematical model. The variations of the alkaline dosages studied for saponification pre-treatment were 0.04 mol base/g sCOD; 0.02 mol base/g sCOD; and no pre-treatment for control reactor. This study proved that saponification increased the solubility of dairy fat waste. This result was confirmed by the hydrolysis constant value (kH) of 0.00782/day for reactor with saponification, which was twenty times of magnitude higher than the kH value of 0.00032/day in the reactor without saponification. However, the exposure to high pH during the saponification pre-treatment might somewhat inhibit indigenous acidogenic bacteria in the waste which results in lower methane yield in the reactors with saponification to be compared to the control reactor. A B S T R A KPeruraian anaerobik merupakan salah satu bidang riset yang sangat menarik perhatian dalam era krisis energi. Biogas tidak hanya menyediakan energi alternatif, tetapi juga dapat mencegah pencemaran akibat limbah organik. Limbah lemak susu adalah substrat yang potensial untuk proses peruraian anaerobik karena memiliki potensi biogas teoritis yang tinggi akibat kandungan lemaknya yang tinggi. Namun, peruraian anaerobik dari limbah organik dengan kandungan lemak yang tinggi memiliki tantangan tersendiri. Hambatan utama dalam peruraian anaerobik dari limbah lemak susu adalah kecenderungan untuk membentuk lapisan padatan yang tidak larut dan mengapung di bagian atas fase cair. Fenomena ini menghambat akses bakteri hidrolisis terhadap substrat. Saponifikasi adalah salah satu cara untuk meningkatkan kelarutan lapisan padatan tersebut, sehingga meningkatkan ketersediaan substrat untuk bakteri. Saponifikasi akan mengubah kandungan lemak menjadi sabun yang memiliki gugus fungsi polar maupun non-polar. Gugus fungsi yang bersifat polar akan meningkatkan kelarutan substrat dalam air. Studi ini mengevaluasi pengaruh dari berbagai dosis larutan basa yang ditambahkan sebagai reaktan selama perlakuan awal saponifikasi terhadap peruraian anaerobik limbah lemak susu. Kinetika proses peruraian anaerobik dianalisis dengan menggunakan model matematika. Variasi dosis yang diamati pengaruhnya untuk perlakuan awal saponifikasi adalah 0,04 mol basa/g sCOD; 0,02 mol basa/g sCOD; dan nol (tanpa perlakuan awal saponifikasi). Dari penelitian ini, terbukti bahwa saponifikasi berhasil meningkatkan kelarutan limbah lemak susu dan juga ditunjukkan oleh nilai konstanta hidrolisis (kH) 0,00782/hari lebih tinggi dua puluh kali lipat dibandingkan dengan nilai kH 0,00032/hari pada reaktor tanpa saponifikasi. Akan tetapi, penelitian ini juga mengindikasikan bahwa bakteri asidogenik bawaan substrat terhambat kinerjanya oleh paparan pH yang tinggi selama perlakuan awal saponifikasi berlangsung sehingga hasil gas metan yang diperoleh lebih rendah daripada reaktor kontrol.

scholarly journals Theoretical and Experimental Results on the Recovery of Potato Processing Residuals by Anaerobic Digestion

2019 ◽  
Vol 70 (7) ◽  
pp. 2524-2529 ◽  
Author(s):  
Andreea D. Dima ◽  
Carmen Mateescu ◽  
Oana C. Parvulescu ◽  
Eduard M. Lungulescu ◽  
Nicoleta O. Nicula
Keyword(s):  
Anaerobic Digestion ◽  
Gompertz Model ◽  
Economic Feasibility ◽  
Potato Processing ◽  
Biomethane Potential ◽  
Potato Waste ◽  
Cone Model ◽  
Treatment Technologies ◽  
Negative Environmental Impact ◽  
Modified Gompertz Model

Anaerobic digestion of organic matter with high moisture content has proven to be a suitable method for disposal of wet organic residuals with several advantages compared to other treatment technologies. This paper aimed at evaluating the theoretical and experimental biomethane potential of food processing residuals that are responsible for negative environmental impact, with exemplification for the potato processing waste. The biomethane potential is a useful parameter to assess the economic efficiency of anaerobic digestion processes as it can considerably influence the efficiency and the economic feasibility of the energy recovery technologies. Both experimental and theoretical biomethane potentials of potato waste in mesophilic anaerobic digestion as well as biodegradability of the substrate were estimated. Moreover, effects of microalgal extract addition on the digestion of potato waste were examined in an attempt to stimulate the anaerobic digestion. Cone model and a modified Gompertz model were used to predict the dynamics of biomethane production.

scholarly journals Reaction Kinetics Modelling for Dry Anaerobic Digestion of Hura Crepitans Invasive Species Lignocellulosic Biomass

2021 ◽  
Author(s):  
Akinola David Olugbemide ◽  
Blaž Likozar ◽  
Ana Oberlintner ◽  
Uroš Novak ◽  
Ekebafe Lawrence
Keyword(s):  
Anaerobic Digestion ◽  
Invasive Plant ◽  
Biogas Production ◽  
Test Procedure ◽  
Gompertz Model ◽  
Agricultural Crop ◽  
Kinetic Predictions ◽  
Hura Crepitans ◽  
The Impact ◽  
Dry Anaerobic Digestion

Abstract In this research study, the impact of the feedstock to the inoculum (F/I) amount ratio in the dry anaerobic digestion (DAD) of Hura crepitans leaves was evaluated. Measured biogas volumes, as well as the chemical kinetic predictions for exponential, logistic and Gompertz model, depicting the agreement of the simulations over time, were also determined. From the F/I equivalents 2, 4 and 6 at 22 % of packed total solids, which were considered in analysis test procedure, the DAD digester with F/I number 4 was the most promising in terms of biogas’ production rate. Its daily methane/carbon dioxide was 690 mL, while cumulative generation productivity was greater than 2 L/sample, respectively. On the other hand, the DAD reaction with F/I contained 6, recorded the lowest related expressed primary matter of < 1 L. An associated early commencement of the organic material breakdown in all bio vessels was indicative of a good start-up phase, which is one of the challenges, often encountered in DAD process. Furthermore, applied experimental methods revealed the direct correlation phenomena between biodegradability physical constants, measured molecular CH4/CO2 synthesis and simulations. Hura crepitans being an invasive plant species makes its lignocellulosic fractions desired in terms of valorisation, as it is not competing with agricultural crop products. Modelling can, moreover, contribute to consecutive operation optimisation, scaling and integrating, also taking dynamics under consideration. As opposed to bio-refining wood residues, where individual cellulose, hemicellulose or lignin biopolymers can be attained, degradation to yield CH4 is robust, as well as compatible in combustion.

scholarly journals Influence of a steam-explosion pre-treatment on the methane yield and kinetics of anaerobic digestion of two-phase olive mil solid waste or alperujo

2016 ◽  
Vol 102 ◽  
pp. 361-369 ◽  
Author(s):  
Bárbara Rincón ◽  
Guillermo Rodríguez-Gutiérrez ◽  
Lucía Bujalance ◽  
Juan Fernández-Bolaños ◽  
Rafael Borja
Keyword(s):  
Anaerobic Digestion ◽  
Solid Waste ◽  
Steam Explosion ◽  
Methane Yield ◽  
Two Phase ◽  
Pre Treatment ◽  
Kinetics Of

scholarly journals Opportunity of Biogas Production from Solid Organic Wastes through Anaerobic Digestion

2018 ◽  
Vol 65 ◽  
pp. 05025 ◽  
Author(s):  
Sagor Kumar Pramanik ◽  
Fatihah Binti Suja ◽  
Biplob Kumar Pramanik ◽  
Shahrom Bindi Md Zain
Keyword(s):  
Anaerobic Digestion ◽  
Biogas Production ◽  
Nutrient Balance ◽  
Organic Wastes ◽  
Organic Loading Rate ◽  
Biogas Yield ◽  
Carbon And Nitrogen ◽  
Potential Risks ◽  
Nitrogen Ratio ◽  
Pre Treatment

Solid organic wastes create potential risks to environmental pollution and human health due to the uncontrolled discharge of huge quantities of hazardous wastes from numerous sources. Now-a-days, anaerobic digestion (AD) is considered as a verified and effective alternative compared to other techniques for treating solid organic waste. The paper reviewed the biological process and parameters involved in the AD along with the factors could enhance the AD process. Hydrolysis is considered as a rate-limiting phase in the complex AD process. The performance and stability of AD process is highly influenced by various operating parameters like temperature, pH, carbon and nitrogen ratio, retention time, and organic loading rate. Different pre-treatment (e.g. mechanical, chemical and biological) could enhance the AD process and the biogas yield. Co-digestion can also be used to provide suitable nutrient balance inside the digester. Challenges of the anaerobic digestion for biogas production are also discussed.

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