scholarly journals Comprehensive Study of Reclaimed Soil, Plant, and Water Chemistry Relationships in Highly S-Contaminated Post Sulfur Mine Site Jeziórko (Southern Poland)

2018 ◽  
Vol 10 (7) ◽  
pp. 2442 ◽  
Author(s):  
Marcin Pietrzykowski ◽  
Justyna Likus-Cieślik

The aim of the work was a comprehensive study of the soils (pH, EC, SOC, NT, ST), surface waters (pH, EC, Ca2+ Mg2+, Na+, NO3−, SO42−, Cl−, HCO3−), and reactions of trees and herbaceous plants in the restored forest ecosystem of a former sulfur mine. Common birch and Scots pine growth reaction, vitality (according to IUFRO standards- International Union of Forest Research Organizations), nutrient supply (Na, K, P, Ca, Mg, K), and Calamagrostis epigejos (L.) Roth chemical composition (Na, K, P, Ca, Mg, K) were assayed. The chemistry dynamics (pH, EC, DOC, NT, Ca, Mg, and S at the beginning and end of the experiment) of soil leaching and the sulfur load leached from the sulfur-contaminated soil substrates were evaluated. The remediation effects of birch and pine litter were assayed in an experiment under controlled conditions. It was found that reclamation was effective in the majority of the post-mining site; however, hotspots with sulfur contamination reaching even 45,000 mg kg−1, pH < 2.0 and electrical conductivity (EC) of 6500 µS cm−1 were reported. Surface waters typically displayed elevated concentrations of sulfate ions (average 935.13 mg L−1), calcium ions (up to 434 mg L−1), and high EC (average 1797 µS cm−1), which was related both to sulfur contamination and the sludge lime that was used in neutralization. Calamagrostis epigejos was found to be a species that adapted well to the conditions of elevated soil salinity and sulfur concentration. It was observed that the application of organic matter had a significant beneficial impact on the chemistry of soil solutions, but did not show a remediation effect by increased sulfur leaching in a short-term study.

Author(s):  
Marcin Pietrzykowski ◽  
Justyna Likus-Cieślik

Sulfur contamination of topsoil, spatial distribution of contamination and surface water chemistry were investigated on an area of over 200 ha of a new forest ecosystem. Common birch and Scots pine growth reaction, vitality and nutrients supply, as well as wood small-reed (Calamagrostis epigejos (L.) Roth) chemical composition were assayed. The chemistry dynamics of soil leaching and the sulfur load leached from the sulfur contaminated soil-substrates were analyzed. The remediation effect of the birch and pine litter was assayed in an experiment under controlled conditions. It was found that reclamation was effective in a majority of the post-mining site, however hot-spots with sulfur contamination reaching even 45,000 mg kg-1, pH &lt;2.0, and EC 6,500 &micro;S cm-1 were reported. Surface waters typically displayed elevated concentrations of sulfate ions (average 935.13 mg L-1), calcium ions (up to 434 mg L-1) and high EC (average 1.795 &micro;S cm-1), which was connected both with sulfur contamination and sludge lime used in neutralization. Wood small-reed was found to be species adapting well to the conditions of elevated soil salinity and sulfur concentration. We noted that an addition of organic matter had a significant impact on the chemistry of soil solutions but did not indicate in short term experiment a remediation effect by increased sulfur leaching.


2020 ◽  
Vol 175 ◽  
pp. 12022
Author(s):  
Guriyat Podvolotskaya ◽  
Sergey Belopukhov ◽  
Vitaly Savich ◽  
Andrey Sorokin ◽  
Nikolay Tyutrin

Soil solutions and the surface waters are characterized by properties, processes and regimes. Soil solutions of different soils and their surface water have different biological activity and change the activity of dissolved stimulants and inhibitors. The object of the study are soil solutions of the main types of soils obtained in the model experiments with the ratio of soils: water equal to 1:1 and 1: 2, soil solutions and surface water in the flooding of soils with water for 1 week – 3 months. The research method consisted in the assessment of pH, Eh, activity of K, NO3, NH4, Ca, Mg by conventional methods, assessment of concentrations of water-soluble compounds extracted from soils by ionite membranes, in the assessment of biological activity of solutions using biotests. The following is suggested for additional evaluation: the using of cation and anion membranes, determination of interrelation between the properties of waters, equation of pair correlation and multiply regression. The informative value of the gradient of surface water concentrations at different distances from the floor of the reservoir, at different depths of the overwatered soils is shown. The mobility of Ca, Mg, Fe, Mn in soils and the content of their water-soluble forms depends on both pH and Eh, whose influence on the content of water-soluble forms of the considered cations shows the effects of synergy and antagonism. The rate of change in the composition of soil solutions during soil flooding depends on a combination of soil properties, temperature, and duration of flooding. Soil solutions of different soils and their surface waters have differentrates.


2020 ◽  
Author(s):  
Jing Fang

&lt;p&gt;Pathways for the physical disintegration of biochar (BC) and the release of water dispersible BC colloids (WDBC) have received much attention due to their unique impacts on carbon loss and contaminant. However, the current understanding of the mechanisms involved in WDBC formation and associated influencing factors is rather limited. This study systematically explored the formation and colloidal stability of WDBC in various&amp;#160;solutions. Results showed that the WDBC yield decreased in the order BC400&amp;#160;(400&amp;#8451;)&gt; BC700 (&amp;#8451;)&gt; BC200(200&amp;#8451;)&amp;#160;at a solution ionic strength (IS) &amp;#8804; 1 mM&amp;#160;&amp;#65288;NaCl&amp;#65289;. With the exception of BC200, increasing IS (0.1&amp;#8211;20 mM&amp;#160;NaCl) and decreasing pH (3.0&amp;#8211;10.0) significantly inhibited WDBC yield. Release and sedimentation dominated the WDBC formation processes with the former being more susceptible to solution chemistry. The test results of 22 soil solutions showed&amp;#160;that&amp;#160;the yields of WDBC from BC400 were considerable, while the yield of WDBC from BC700 could be neglected. Principal component analysis showed that the yield of WDBC in soil solutions was closely related to the contents of dissolved organic carbon, Fe and Al ions of soil solutions. WDBC&amp;#160;had high colloidal stability and could stabilize well in natural surface waters and soil solutions.&amp;#160;These findings represent new knowledge regarding the physical decomposition and the fate of BC in the environment.&lt;/p&gt;


2001 ◽  
Vol 16 (5) ◽  
pp. 513-529 ◽  
Author(s):  
Frédéric Gérard ◽  
Jean-Pierre Boudot ◽  
Jacques Ranger

1988 ◽  
Vol 17 (4) ◽  
pp. 534-543 ◽  
Author(s):  
A. D. Karathanasis ◽  
V. P. Evangelou ◽  
Y. L. Thompson

1994 ◽  
Vol 158 ◽  
pp. 237-252 ◽  
Author(s):  
Jean-Pierre Boudot ◽  
Denis Merlet ◽  
James Rouiller ◽  
Ouafae Maitat

2016 ◽  
Vol 38 (2) ◽  
pp. 14-18
Author(s):  
V.I. Savich ◽  
◽  
V.A. Chernikov ◽  
G.B. Podvolotskaya ◽  
◽  
...  

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