scholarly journals Ce-Doped-MgAl Superhydrophobic Layered Double Hydroxide for Enhanced Corrosion Resistance Properties

Solids ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 76-86
Author(s):  
Muhammad Ahsan Iqbal ◽  
Humaira Asghar ◽  
Michele Fedel
Keyword(s):  
Thin Films ◽  
Contact Angle ◽  
Corrosion Resistance ◽  
Layered Double Hydroxide ◽  
Electrochemical Impedance ◽  
Morphological Characteristics ◽  
Aluminum Surface ◽  
Water Contact ◽  
Growth Method ◽  
Double Hydroxide

Double doped layered double hydroxide thin films were developed directly on the aluminum substrate in two steps: Initially cerium-based MgAl-layered double hydroxide (LDH) were synthesized directly on the anodic aluminum surface via the in situ growth method, and were then modified with the stearate anions through an ion-exchange mechanism to achieve compact multifunctional protective thin films. The structural and morphological characteristics of the developed LDH films were investigated, and the surface contact angle measurements (CA) and self-cleaning properties were analyzed. The obtained double doped LDH film displayed the superhydrophobic characteristic with a water contact angle of ~155°. Furthermore, the superhydrophobic behavior of LDH on exposure to UV radiation (λ = 310 nm) was examined to evaluate outdoor applications. Long-term Electrochemical Impedance Spectroscopy (EIS) analysis was performed to understand the corrosion resistance properties. The introduction of double doped LDHs demonstrates significantly higher corrosion resistance properties than only cerium-modified LDHs and has shown superior stability against 0.1 M NaCl solution.

scholarly journals Development of Multifunctional CoAl Based Layered Double Hydroxide Protective Film on Aluminum Alloy

2021 ◽  
Vol 2 (4) ◽  
pp. 708-720
Author(s):  
Muhammad Ahsan Iqbal ◽  
Humaira Asghar ◽  
Michele Fedel
Keyword(s):  
Contact Angle ◽  
Layered Double Hydroxide ◽  
Electrochemical Impedance ◽  
Protective Film ◽  
Structural Variations ◽  
Water Contact ◽  
Transfer Resistance ◽  
Surface Protection ◽  
Double Hydroxide

A protective CoAl-layered double hydroxide (LDH) thin film was developed directly on the aluminum substrate. Further, the low-surface-energy molecules (1H, 1H, 2H, 2H perfluorododecyl trichlorosilane) were incorporated inside the LDH network through an anion exchange mechanism to obtain a superhydrophobic CoAl-LDH surface. The developed films were characterized by scanning electron microscopy (SEM-EDS), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR), and additional contact angle measurements were made to evaluate the superhydrophobicity of modified CoAl-LDHs against different solutions. The water contact angle (WCA) of the modified CoAl-LDH surface was observed to be about 153° and remained sufficiently stable after long-term immersion in NaCl solution. The effect of excessive ultrasonication on film structural variations and superhydrophobicity was also analyzed for outdoor applications. The high charge transfer resistance observed from the analysis of long-term electrochemical impedance spectroscopy (EIS) indicates the significant corrosion-resistance properties of the developed CoAl-LDHs. This research on protective CoAl-LDHs will bring insights into the understanding of new aspects of surface protection and implementation in many engineering applications.

In situ growth of a CaAl-NO3−-layered double hydroxide film directly on an aluminum alloy for corrosion resistance

2020 ◽  
Vol 49 (13) ◽  
pp. 3956-3964 ◽  
Author(s):  
Muhammad Ahsan Iqbal ◽  
Luyi Sun ◽  
Anna Marie LaChance ◽  
Hao Ding ◽  
Michele Fedel
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Layered Double Hydroxide ◽  
In Situ Growth ◽  
Structural Geometry ◽  
Hydroxide Film ◽  
Growth Method ◽  
Double Hydroxide ◽  
First Time

In this study, a calcium–aluminum-layered double hydroxide (CaAl-LDH) thin film was grown on an AA6082 aluminum alloy, for the very first time, by using a facile in situ growth method in an effort to investigate the CaAl-LDH structural geometry and corresponding corrosion resistance properties.

scholarly journals Protective Cerium-Based Layered Double Hydroxides Thin Films Developed on Anodized AA6082

2020 ◽  
Vol 2020 ◽  
pp. 1-12
Author(s):  
Muhammad Ahsan Iqbal ◽  
Michele Fedel
Keyword(s):  
Thin Films ◽  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Barrier Properties ◽  
Hot Water ◽  
Aluminum Surface ◽  
Anodized Aluminum ◽  
Immersion Period ◽  
Double Hydroxides

In this work, CeMgAl-LDHs protective thin films were developed directly on the anodized aluminum surface, and on the “hot water-sealed” anodized aluminum specimens. The synthesized coatings were investigated by SEM-EDS and XRD and through long-term electrochemical impedance spectroscopy (EIS) spectra. The growth of CeMgAl-LDHs into/onto the micropores/defects of anodized film was found to significantly improve the LDH barrier properties with delaying coating degradation compared to LDHs developed on the “hot water-sealed” surface. The unmodified LDHs “without cerium addition” were also developed to compare the influence of cerium on the structural and electrochemical properties of LDHs. It is also noteworthy that LDHs grown on the anodized surface provided dense and finer growth, while the addition of cerium ions was found to exhibit influential higher long-term corrosion resistance properties after the 1200 h immersion period.

scholarly journals Effect of Synthesis Conditions on the Controlled Growth of MgAl–LDH Corrosion Resistance Film: Structure and Corrosion Resistance Properties

Coatings ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 30 ◽  
Author(s):  
Muhammad Ahsan Iqbal ◽  
Michele Fedel
Keyword(s):  
Corrosion Resistance ◽  
Layered Double Hydroxide ◽  
Treatment Time ◽  
Electrochemical Impedance ◽  
Hydrothermal Process ◽  
Crystallization Time ◽  
Oriented Growth ◽  
Electrochemical Impedance Spectra ◽  
Energy Dispersion Spectroscopy ◽  
Double Hydroxide

In this study, a series of MgAl–layered double hydroxide (LDH) thin films were synthesized by a single step hydrothermal process at different synthetic conditions on AA6082, and the combined effect of reaction temperatures and crystallization times on in situ growth MgAl–LDH structural geometry, growth rate, and more importantly on the corresponding corrosive resistance properties are briefly discussed. The synthesis of LDH was performed at reaction temperatures of 40, 60, 80, and 100 °C, while the treatment time was varied at 12, 18, and 24 h. The as-prepared synthetic coatings were characterized by scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR), while the corresponding corrosion protection efficiency of the developed coating was studied through potentiodynamic polarization studies and electrochemical impedance spectra. The findings demonstrated that extended crystallization time and reaction temperature impart a significant effect on the oriented growth of layered double hydroxide, the surface morphology, and on the film thickness, which had a remarkable influence on the LDH corrosion resistance ability. The LDH coated specimen developed at 100 °C for 18 h reaction time showed a more compact and dense structure compared to the traditional platelet structure obtained at 80 °C for 24 h crystallization time, and interestingly that compact structure exhibited the lowest corrosion current density, up to five orders of magnitude lower than that of bare AA6082.

scholarly journals Chlorides Entrapment Capability of Various In-Situ Grown NiAl-LDHs: Structural and Corrosion Resistance Properties

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 384 ◽  
Author(s):  
Muhammad Ahsan Iqbal ◽  
Luyi Sun ◽  
Humaira Asghar ◽  
Michele Fedel
Keyword(s):  
Corrosion Resistance ◽  
Ion Exchange ◽  
Electrochemical Impedance ◽  
Barrier Properties ◽  
Aluminum Surface ◽  
Molar Ratios ◽  
Potentiodynamic Curves ◽  
Double Hydroxide ◽  
Surface Morphologies ◽  
Platelet Structure

In this work, various NiAl-LDH thin films, exhibiting specific surface morphologies, were developed directly on aluminum AA 6082 substrate to understand the two main characteristics of layered double hydroxide (LDH), i.e., ion-exchange behavior and barrier properties, which are found to have a significant influence on the LDH corrosion resistance properties. The as-prepared NiAl-LDH films were analyzed through the scanning electronic microscope (SEM), X-ray diffraction (XRD), while the corrosion behavior of the synthesized films was investigated by the electrochemical impedance spectroscopy (EIS) and potentiodynamic curves. The results indicated that NiAl-LDH microcrystals grow in various fashions, from porous relatively flat domains to well-developed platelet structure, with the variation of nickel nitrate to ammonium nitrate salts molar ratios. The LDH structure is observed in all cases and is found to cover the aluminum surface uniformly in the lamellar order. All the developed NiAl-LDHs are found to enhance the corrosion resistance of the aluminum substrate, specifically, a well-developed platelet structure is found to be more effective in chloride adsorptive and entrapment capabilities, which caused higher corrosion resistance compared to other developed NiAl-LDHs. The comparison of the synthesized NiAl-LDH morphologies on their ion-exchange capabilities, barrier effect and their combined effect on corrosion resistance properties is reported.

scholarly journals Hydrophobic Modification of Graphene Oxide and Its Effect on the Corrosion Resistance of Silicone-Modified Epoxy Resin

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 89
Author(s):  
Wei Yuan ◽  
Qian Hu ◽  
Jiao Zhang ◽  
Feng Huang ◽  
Jing Liu
Keyword(s):  
Contact Angle ◽  
Corrosion Resistance ◽  
Graphene Oxide ◽  
Physical Properties ◽  
Epoxy Resin ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
X Ray ◽  
Modified Graphene Oxide ◽  
Modified Epoxy

This study modified graphene oxide (GO) with hydrophilic octadecylamine (ODA) via covalent bonding to improve its dispersion in silicone-modified epoxy resin (SMER) coatings. The structural and physical properties of ODA-GO were characterized by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and contact angle tests. The ODA-GO composite materials were added to SMER coatings by physical mixing. FE-SEM, water absorption, and contact angle tests were used to evaluate the physical properties of the ODA-GO/SMER coatings, while salt spray, electrochemical impedance spectroscopy (EIS), and scanning Kelvin probe (SKP) methods were used to test the anticorrosive performance of ODA-GO/SMER composite coatings on Q235 steel substrates. It was found that ODA was successfully grafted onto the surfaces of GO. The resulting ODA-GO material exhibited good hydrophobicity and dispersion in SMER coatings. The anticorrosive properties of the ODA-GO/SMER coatings were significantly improved due to the increased interfacial adhesion between the nanosheets and SMER, lengthening of the corrosive solution diffusion path, and increased cathodic peeling resistance. The 1 wt.% ODA-GO/SMER coating provided the best corrosion resistance than SMER coatings with other amounts of ODA-GO (including no addition). After immersion in 3.5 wt.% NaCl solution for 28 days, the low-frequency end impedance value of the 1 wt.% ODA-GO/SMER coating remained high, at 6.2 × 108 Ω·cm2.

scholarly journals ESTUDIO DE LA RESISTENCIA A LA CORROSION DEL ALUMINIO 6063 ANODIZADO

2017 ◽  
Vol 22 (2) ◽  
pp. 17
Author(s):  
Karín Paucar Cuba ◽  
Hugo Rojas Flores ◽  
Abel Vergara Sotomayor
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Sulfuric Acid ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Aluminum Surface ◽  
Equivalent Circuits ◽  
Acid Salt ◽  
Mass Losses ◽  
Palabras Clave

El estudio de la resistencia a la corrosión del anodizado de una aleación de aluminio (AA6063) en ácido sulfúrico a diferentes tiempos de anodizado: 30, 45 y 60 min. se realizó usando la espectroscopia de impedancia electroquímica (EIE) y el ensayo de niebla salina ácida. (ASTM B287). Los datos obtenidos por EIE y su correlación con los circuitos equivalentes más apropiados permitieron determinar los parámetros asociados a la capa porosa y a la capa barrera del óxido protector formado sobre la superficie del aluminio en estudio. La exposición de las muestras anodizadas durante 250h a una niebla salina ácida permitió observar variaciones en su masa. De los resultados obtenidos por EIE y las pérdidas de masa de las muestras anodizadas se estableció que la película de anodizado de 45 minutos mostró una mayor resistencia a la corrosión en comparación con la obtenida a 60 y 30 min., respectivamente. Palabras clave.- Aluminio, Anodizado, Impedancia electroquímica, Niebla salina ácida. ABSTRACTThe study of the corrosion resistance of anodized on aluminum alloy (AA6063) in sulfuric acid to different times: 30, 45 and 60 min. was performed using electrochemical impedance spectroscopy (EIS) and the acid salt spray test (ASTM B287). The EIS’data and its correlation with the most appropriate equivalent circuits allowed to determine the parameters associated with the porous layer and the oxide layer protective barrier formed on the aluminum surface under study. Exposure of the samples anodized for a 250h salt spray acid allowed to observe changes in their mass. From the results obtained by EIS and the mass losses of the anodized samples was established that the anodized film of 45 minutes showed higher corrosion resistance compared to that obtained at 60 and 30 min, respectively. Keywords.- Aluminum, Anodized, Electrochemical impedance, Acid salt spray.

scholarly journals A Superhydrophilic Aluminum Surface with Fast Water Evaporation Based on Anodic Alumina Bundle Structures via Anodizing in Pyrophosphoric Acid

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3497 ◽  
Author(s):  
Daiki Nakajima ◽  
Tatsuya Kikuchi ◽  
Taiki Yoshioka ◽  
Hisayoshi Matsushima ◽  
Mikito Ueda ◽  
...  
Keyword(s):  
Contact Angle ◽  
Oxide Film ◽  
High Speed ◽  
Porous Alumina ◽  
Aluminum Surface ◽  
Water Evaporation ◽  
Water Contact ◽  
Initial Stage ◽  
Angle Measuring ◽  
Pyrophosphoric Acid

A superhydrophilic aluminum surface with fast water evaporation based on nanostructured aluminum oxide was fabricated via anodizing in pyrophosphoric acid. Anodizing aluminum in pyrophosphoric acid caused the successive formation of a barrier oxide film, a porous oxide film, pyramidal bundle structures with alumina nanofibers, and completely bent nanofibers. During the water contact angle measurements at 1 s after the water droplet was placed on the anodized surface, the contact angle rapidly decreased to less than 10°, and superhydrophilic behavior with the lowest contact angle measuring 2.0° was exhibited on the surface covered with the pyramidal bundle structures. As the measurement time of the contact angle decreased to 200–33 ms after the water placement, although the contact angle slightly increased in the initial stage due to the formation of porous alumina, at 33 ms after the water placement, the contact angle was 9.8°, indicating that superhydrophilicity with fast water evaporation was successfully obtained on the surface covered with the pyramidal bundle structures. We found that the shape of the pyramidal bundle structures was maintained in water without separation by in situ high-speed atomic force microscopy measurements.

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