scholarly journals Streambank Legacy Sediments in Surface Waters: Phosphorus Sources or Sinks?

Soil Systems ◽  
2020 ◽  
Vol 4 (2) ◽  
pp. 30
Author(s):  
Shreeram Inamdar ◽  
Nathan Sienkiewicz ◽  
Alyssa Lutgen ◽  
Grant Jiang ◽  
Jinjun Kan
Keyword(s):  
Surface Waters ◽  
Stream Water ◽  
Phosphorus Concentration ◽  
Phosphorus Sorption ◽  
Upland Soils ◽  
P Leaching ◽  
Sorption Index ◽  
Legacy Sediment ◽  
Quality Threshold ◽  
Source Sink

Streambank legacy sediments can contribute substantial amounts of sediments to Mid-Atlantic waterways. However, there is uncertainty about the sediment-bound P inputs and the fate of legacy sediment P in surface waters. We compared legacy sediment P concentrations against other streambank sediments and upland soils and evaluated a variety of P indices to determine if legacy sediments are a source or sink of P to surface waters. Legacy sediments were collected from 15 streambanks in the mid-Atlantic USA. Total P and M3P concentrations and % degree of phosphorus saturation (DPS) values for legacy sediments were lower than those for upland soils. % DPS values for legacy sediments were below the water quality threshold for P leaching. Phosphorus sorption index (PSI) values for legacy sediments indicated a large capacity for P sorption. On the other hand, equilibrium phosphorus concentration (EPC0) for legacy sediments suggested that they could be a source or a sink depending on stream water P concentrations. Anoxic conditions resulted in a greater release of P from legacy sediments compared to oxic conditions. These results suggest that legacy sediment P behavior could be highly variable and watershed models will need to account for this variability to reliably quantify the source-sink behavior of legacy sediments in surface waters.

scholarly journals Phosphorus Sorption Behavior of Torrefied Agricultural Byproducts under Sonicated Versus Non-Sonicated Conditions

2017 ◽  
Vol 6 (4) ◽  
pp. 1 ◽  
Author(s):  
Jehangir H. Bhadha ◽  
Stephen P. Jennewein ◽  
Raju Khatiwada
Keyword(s):  
Crop Production ◽  
Phosphorus Concentration ◽  
Sorption Behavior ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Concentration Maximum ◽  
Major Nutrients ◽  
P Leaching ◽  
Palm Fronds ◽  
Total P

The application of agrichar derived from organic feedstocks has the potential to improve soil fertility and crop production by providing major nutrients like phosphorus (P) to the crop, and in some cases also reducing P leaching. The effect of agrichar on the leaching of P in soils is not uniform and can vary depending on the type of agrichar and amount applied. The objective of this study was to (i) evaluate the behavior of four agrichars (rice hulls RH, palm fronds PF, horse bedding HB, and bagasse BG) for their ability to retain/release P and (ii) determine the effect of wet sonication on P sorption behavior. The feedstocks were torrefied at 500 °C using a top-lit updraft gasifier and used in multiple batch incubation experiments to evaluate equilibrium phosphorus concentration, maximum P sorption capacity (Smax), and adsorption/desorption potential. Both, RH (12.6 g kg-1) and HB (11.5 g kg-1) contained 10-15 times higher total P concentration than PF and BG, rendering RH and HB as potentially suitable products to be used as soil amendments. However, this initial P content of the agrichar seemed to have an overriding effect on the P sorption behavior of the agrichar. PF had Smax of 676 (±127) mg kg-1 for the non-sonicated agrichar, and 237 (±91) mg kg-1 following sonication. There was significant increase in CEC for PF and BG agrichar upon sonication. PF agrichar increased from 27 (±3) cmolc kg-1 to 41 (±4) cmolc kg-1 with sonication. Similarly, BG agrichar CEC increased from 21 (±2) cmolc kg-1 to 45 (±5) cmolc kg-1 with sonication. Initial total P and Ca concentration and their ratios was found to play significant roles on P adsorption and desorption. Major cations like Ca, Fe, Al and Mn are found to act as active sorption site for phosphorus controlling its fate and mobility along with compounding effects of other physicochemical parameters.

Phosphorus Sorption-Desorption Characteristics of Selected Acid Upland Soils in Indonesia

2005 ◽  
Vol 51 (6) ◽  
pp. 787-799 ◽  
Author(s):  
Arief Hartono ◽  
Shinya Funakawa ◽  
Takashi Kosaki
Keyword(s):  
Phosphorus Sorption ◽  
Upland Soils

scholarly journals DOC-dynamics in a small headwater catchment as driven by redox fluctuations and hydrological flow paths – are DOC exports mediated by iron reduction/oxidation cycles?

2013 ◽  
Vol 10 (2) ◽  
pp. 891-904 ◽  
Author(s):  
K.-H. Knorr
Keyword(s):  
Ionic Strength ◽  
Pore Water ◽  
Surface Waters ◽  
Iron Reduction ◽  
Stream Water ◽  
Riparian Wetlands ◽  
Pore Waters ◽  
Flow Paths ◽  
Discharge Patterns ◽  
Iron Concentrations

Abstract. Dissolved organic carbon (DOC) exports from many catchments in Europe and North-America are steadily increasing. Several studies have sought to explain this observation. As possible causes, a decrease in acid rain or sulfate deposition, concomitant reductions in ionic strength and increasing temperatures were identified. DOC often originates from riparian wetlands; but here, despite higher DOC concentrations, ionic strength in pore waters usually exceeds that in surface waters. In the catchment under study, DOC concentrations were synchronous with dissolved iron concentrations in pore and stream water. This study aims at testing the hypothesis that DOC exports are mediated by iron reduction/oxidation cycles. Following the observed hydrographs, δ18O of water and DOC fluorescence, the wetlands were identified as the main source of DOC. Antecedent biogeochemical conditions, i.e., water table levels in the wetlands, influenced the discharge patterns of nitrate, iron and DOC during an event. The correlation of DOC with pH was positive in pore waters, but negative in surface waters; it was negative for DOC with sulfate in pore waters, but only weak in surface waters. Though, the positive correlation of DOC with iron was universal for pore and surface water. The decline of DOC and iron concentrations in transition from anoxic wetland pore water to oxic stream water suggests a flocculation of DOC with oxidising iron, leading to a drop in pH in the stream during high DOC fluxes. The pore water did not per se differ in pH. There is, thus, a need to consider processes more thoroughly of DOC mobilisation in wetlands when interpreting DOC exports from catchments. The coupling of DOC with iron fluxes suggested that increased DOC exports could at least, in part, be caused by increasing activities in iron reduction, possibly due to increases in temperature, increasing wetness of riparian wetlands, or by a shift from sulfate dominated to iron reduction dominated biogeochemical regimes.

scholarly journals Stream plant chemistry as indicator of acid sulphate soils in Sweden

2008 ◽  
Vol 14 (1) ◽  
pp. 83 ◽  
Author(s):  
K. LAX
Keyword(s):  
Surface Waters ◽  
Stream Water ◽  
Low Ph ◽  
Fontinalis Antipyretica ◽  
Acid Sulphate ◽  
Fine Grained ◽  
Acid Sulphate Soils ◽  
Trace Element Chemistry ◽  
Study Results ◽  
The Impact

Results from the biogeochemical mapping (roots of aquatic plants and Fontinalis antipyretica) conducted by the Geological Survey of Sweden (SGU) reflects the metal load of surface waters draining acid sulphate (AS) soils in Sweden. In this study, results from the biogeochemical, soil geochemical and Quaternary mapping programmes at SGU were used to investigate the impact of fine-grained deposits hosting AS soils on stream water trace element chemistry in two separate areas. In the area around Lake Mälaren, postglacial sediments contain the highest levels of most trace elements studied. Owing to the low pH of AS soils and subsequent leaching, levels of nickel (Ni), cobalt (Co), copper (Cu), sulphur (S), yttrium (Y), uranium (U), tungsten (W), and molybdenum (Mo) were significantly elevated in aquatic roots. Levels were lower in the Skellefteå area, which may be explained by lower concentrations in source deposits. Concentrations of arsenic (As) and lead (Pb) were normal or impoverished in biogeochemical samples from postglacial, finegrained sediment areas. Maps based on ratios (Ni:Pb or Y:Pb) in biogeochemical samples can, together with results from Quaternary mapping, be used to predict areas with AS soils in Sweden.;

scholarly journals QUALITY CHARACTERISTICS OF SURFACE WATERS AT ASPROLAKKAS RIVER BASIN, N.E. CHALKIDIKI, GREECE

2017 ◽  
Vol 43 (4) ◽  
pp. 1737
Author(s):  
E. Kelepertzis ◽  
A. Argyraki ◽  
E. Daftsis ◽  
D. Ballas
Keyword(s):  
Surface Waters ◽  
Water Samples ◽  
Major Ions ◽  
Stream Water ◽  
Water Discharge ◽  
Sampling Period ◽  
Quality Characteristics ◽  
Sampling Point ◽  
The Past ◽  
Surface Water Samples

The present study reports on a four sampling period (April 2008-July 2008-November 2008-February 2009) study of water quality in streams of NE Chalkidiki. A total of 80 surface water samples were collected and analysed for the major ions Ca2+, Mg2+, K+, Na+, Cl- , HCO3 - , SO4 2-, NO3 - and the trace elements Pb, Fe, Cd, Cu, Cr, Ni, Zn, Mn and As. Also pH, Electrical Conductivity (EC), Total Dissolved Solids (TDS), Temperature, as well as the stream water discharge at each sampling point, were determined in the field. The treatment and the subsequent evaluation of the data showed that the water samples are divided into three separate groups, reflecting the chemistry of water in the three sub-basins of the area i.e., Kokkinolakkas, Kerasia and Piavitsa. The water of the first one is possibly affected by the past mining activities of the area, whereas samples from the other two reflect the influence of sulphide mineralization on the hydrogeochemistry of the corresponding streams. No effect of the seasonal differentiation of stream water discharge was observed.

scholarly journals Unraveling Aquatic Quality Controls of a Nearly Undisturbed Mediterranean Island (Samothraki, Greece)

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 473 ◽  
Author(s):  
Nikolaos T. Skoulikidis ◽  
Anastasia Lampou ◽  
Sofia Laschou
Keyword(s):  
Biological Activity ◽  
Surface Waters ◽  
Stream Flow ◽  
Stream Water ◽  
Sedimentary Rocks ◽  
Atmospheric Humidity ◽  
Groundwater Aquifers ◽  
Mediterranean Island ◽  
Atmospheric Inputs ◽  
Steep Slopes

Due to its rough, mountainous relief, Samothraki remains one of the last minimally disturbed islands in the Mediterranean. This paper examines the hydrogeochemical regime of the island’s surface waters as it results from geological, morphological, and hydro(geo)logical controls within a frame of minimally disturbed environmental conditions. Shallow, fractured groundwater aquifers, in combination with steep slopes and predominant weathering resistant rocks, bring about flashy stream regimes with remarkably low solute concentrations. Streams and springs revealed hydrochemical similarities. Contrary to streams chiefly draining sedimentary rocks, streams underlined by granite and ophiolite rocks do not respond hydrochemically to geochemical differences. Using ion proportions instead of concentrations, geochemical fingertips of magmatic stream basins were detected. Atmospheric inputs largely affect stream and spring composition, e.g., by 75% regarding sodium. Only 20% of dissolved oxygen and pH variance was assigned to biological activity, while nutrient levels were consistent with the undisturbed conditions of the island, except nitrate. Small mountainous springs and brooks fed by restricted, fractured groundwater aquifers with perennial flow, despite scarce summer rainfalls, may be fueled by cloud and fog condensation. High night-day stream flow differences, high atmospheric humidity predominately occurring during the night, and low stream water travel times point out toward this phenomenon.

scholarly journals Variability of dissolved CO<sub>2</sub> in the Pang and Lambourn Chalk rivers

2007 ◽  
Vol 11 (1) ◽  
pp. 328-339 ◽  
Author(s):  
J. Griffiths ◽  
J. Nutter ◽  
A. Binley ◽  
N. Crook ◽  
A. Young ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Seasonal Variation ◽  
Surface Waters ◽  
Temporal Variability ◽  
Stream Water ◽  
Spatial And Temporal Variability ◽  
Dissolved Carbon ◽  
Dissolved Carbon Dioxide ◽  
Borehole Water ◽  
Carbon Dioxide Co2

Abstract. This paper presents the results of a two-year field campaign to determine the spatial and temporal variability of groundwater interaction with surface waters in two Cretaceous Chalk catchments (the Pang and Lambourn) in the Upper Thames in Berkshire, UK, based on measurement of dissolved carbon dioxide (CO2). Average stream water concentrations of dissolved CO2 were up to 35 times the concentration at atmospheric equilibrium. Mean groundwater concentrations of 85 and 70 times the atmospheric equilibrium were determined from borehole water sampled in the Pang and Lambourn respectively. Diurnal and seasonal variation of in-stream concentration of dissolved CO2 is not significant enough to mask the signal from groundwater inputs.

Effect of Mixing Soil Aggregates on the Phosphorus Concentration in Surface Waters

2002 ◽  
Vol 31 (4) ◽  
pp. 1294-1299 ◽  
Author(s):  
R.O. Maguire ◽  
A.C. Edwards ◽  
J.T. Sims ◽  
P.J.A. Kleinman ◽  
A.N. Sharpley
Keyword(s):  
Surface Waters ◽  
Soil Aggregates ◽  
Phosphorus Concentration

Reduced leaching of nitrate, ammonium, and phosphorus in a sandy soil by fly ash amendment

Soil Research ◽  
2002 ◽  
Vol 40 (7) ◽  
pp. 1201 ◽  
Author(s):  
S. M. Pathan ◽  
L. A. G. Aylmore ◽  
T. D. Colmer
Keyword(s):  
Fly Ash ◽  
Sandy Soil ◽  
Nutrient Management ◽  
Soil Phosphorus ◽  
Sandy Soils ◽  
Phosphorus Sorption ◽  
Native Soil ◽  
Extractable P ◽  
P Leaching ◽  
Amended Soil

Low ionic sorption capacities and high hydraulic conductivities of sandy soils contribute to the potential for leaching of nutrients applied to these soils. Batch sorption experiments were used to examine NO3–, NH4+, and P sorption/desorption isotherms for Karrakatta sand and Kwinana fly ash. Column experiments assessed leaching of these nutrients from this sandy soil, when amended with 4 rates (0, 5, 10, and 20%, wt/wt) of fly ash. The sorption of NO3–, NH4+, and P was higher for fly ash than the sandy soil. Phosphorus sorption was greatest for unweathered fly ash, followed by weathered fly ash and then the soil; for example, sorption from a solution containing 20 mg/L P was 90%, 28%, and 14%, respectively. Desorption of P was much slower in the unweathered fly ash than weathered fly ash or the soil. Leachates collected from columns containing fly ash amended soil (5, 10, and 20%, wt/wt) generally had lower concentrations of NO3– and NH4+ than leachates from non-amended soil. Prior to adding fertiliser, the concentration of P was greater in leachate from fly ash amended soil than from the native soil, due to fly ash (weathered) itself containing 92.5 mg/kg of extractable P. However, from day 35 onwards, the concentration of P was lower in leachates from soil amended with 10% or 20% fly ash than from non-amended soil. Thus, fly ash amendment retarded NO3–, NH4+, and P leaching in the sandy soil and may therefore be a useful tool for improvement of nutrient management in sandy soils.

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