scholarly journals Governing Constraints of Chromium(VI) Formation from Chromium(III)-Bearing Minerals in Soils and Sediments

Soil Systems ◽  
2019 ◽  
Vol 3 (4) ◽  
pp. 74 ◽  
Author(s):  
Debra Hausladen ◽  
Sarah Fakhreddine ◽  
Scott Fendorf

The potential for geogenic Cr(VI) contamination is vast, yet it is difficult to predict susceptible environments as groundwater Cr(VI) concentrations vary significantly, even within a given aquifer, due to physical and hydrologic heterogeneity. The physical structure of soils and sediments exerts a dominant control on Cr(VI) production by dictating the separation distance of reactive phases, the diffusion distance from Cr(VI) generation sites to advecting groundwater, and by influencing infiltration rates and porewater velocity. Here, we used a dual-pore domain model to investigate the relative control of these parameters on Cr(VI) production. The reaction distance between Cr(III)-bearing minerals and Mn oxides predominantly controls Cr(VI) export to advecting groundwater, while changes in diffusion distance between sites of Cr(VI) generation and advective flow channels generally have little impact on steady-state Cr(VI) concentrations. Changes in Cr(VI) diffusion distance can, however, increase the time required for groundwater Cr(VI) concentrations to reach a steady-state; thus, under fluctuating hydrologic and biogeochemical conditions, long diffusion distances still have the potential to suppress Cr(VI) supply to advecting water. Furthermore, we show that high porewater flow velocities effectively dilute Cr(VI) diffusing from soil/sediment aggregates, thus minimizing Cr(VI) concentrations relative to lower porewater velocities. The strong control that the physical/hydrologic parameters exert on Cr(VI) production appears to overwhelm the impact of Cr(III)-mineral solubility within soils and sediments.

Author(s):  
Gražina ŽIBIENĖ ◽  
Alvydas ŽIBAS ◽  
Goda BLAŽAITYTĖ

The construction of dams in rivers negatively affects ecosystems because dams violate the continuity of rivers, transform the biological and physical structure of the river channels, and the most importantly – alter the hydrological regime. The impact on the hydrology of the river can occur through reducing or increasing flows, altering seasonality of flows, changing the frequency, duration and timing of flow events, etc. In order to determine the extent of the mentioned changes, The Indicators of Hydrologic Alteration (IHA) software was used in this paper. The results showed that after the construction of Angiriai dam, such changes occurred in IHA Parameters group as: the water conditions of April month decreased by 31 %; 1-day, 3-days, 7-days and 30-days maximum flow decreased; the date of minimum flow occurred 21 days later; duration of high and low pulses and the frequency of low pulses decreased, but the frequency of high pulses increased, etc. The analysis of the Environmental Flow Components showed, that the essential differences were recorded in groups of the small and large floods, when, after the establishment of the Šušvė Reservoir, the large floods no longer took place and the probability of frequency of the small floods didn’t exceed 1 time per year.


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 367
Author(s):  
Konstantinos Giannokostas ◽  
Yannis Dimakopoulos ◽  
Andreas Anayiotos ◽  
John Tsamopoulos

The present work focuses on the in-silico investigation of the steady-state blood flow in straight microtubes, incorporating advanced constitutive modeling for human blood and blood plasma. The blood constitutive model accounts for the interplay between thixotropy and elasto-visco-plasticity via a scalar variable that describes the level of the local blood structure at any instance. The constitutive model is enhanced by the non-Newtonian modeling of the plasma phase, which features bulk viscoelasticity. Incorporating microcirculation phenomena such as the cell-free layer (CFL) formation or the Fåhraeus and the Fåhraeus-Lindqvist effects is an indispensable part of the blood flow investigation. The coupling between them and the momentum balance is achieved through correlations based on experimental observations. Notably, we propose a new simplified form for the dependence of the apparent viscosity on the hematocrit that predicts the CFL thickness correctly. Our investigation focuses on the impact of the microtube diameter and the pressure-gradient on velocity profiles, normal and shear viscoelastic stresses, and thixotropic properties. We demonstrate the microstructural configuration of blood in steady-state conditions, revealing that blood is highly aggregated in narrow tubes, promoting a flat velocity profile. Additionally, the proper accounting of the CFL thickness shows that for narrow microtubes, the reduction of discharged hematocrit is significant, which in some cases is up to 70%. At high pressure-gradients, the plasmatic proteins in both regions are extended in the flow direction, developing large axial normal stresses, which are more significant in the core region. We also provide normal stress predictions at both the blood/plasma interface (INS) and the tube wall (WNS), which are difficult to measure experimentally. Both decrease with the tube radius; however, they exhibit significant differences in magnitude and type of variation. INS varies linearly from 4.5 to 2 Pa, while WNS exhibits an exponential decrease taking values from 50 mPa to zero.


2021 ◽  
Vol 5 (EICS) ◽  
pp. 1-29
Author(s):  
Arthur Sluÿters ◽  
Jean Vanderdonckt ◽  
Radu-Daniel Vatavu

Intra-platform plasticity regularly assumes that the display of a computing platform remains fixed and rigid during interactions with the platform in contrast to reconfigurable displays, which can change form depending on the context of use. In this paper, we present a model-based approach for designing and deploying graphical user interfaces that support intra-platform plasticity for reconfigurable displays. We instantiate the model for E3Screen, a new device that expands a conventional laptop with two slidable, rotatable, and foldable lateral displays, enabling slidable user interfaces. Based on a UML class diagram as a domain model and a SCRUD list as a task model, we define an abstract user interface as interaction units with a corresponding master-detail design pattern. We then map the abstract user interface to a concrete user interface by applying rules for the reconfiguration, concrete interaction, unit allocation, and widget selection and implement it in JavaScript. In a first experiment, we determine display configurations most preferred by users, which we organize in the form of a state-transition diagram. In a second experiment, we address reconfiguration rules and widget selection rules. A third experiment provides insights into the impact of the lateral displays on a visual search task.


2016 ◽  
Vol 2016 ◽  
pp. 1-19 ◽  
Author(s):  
Xiaohui Jia ◽  
Minghui Jiang ◽  
Lei Shi

From the perspective of the interactive cooperation among subjects, this paper portrays the process of cooperative innovation in industrial cluster, in order to capture the correlated equilibrium relationship among them. Through the utilization of two key tools, evolutionary stable strategy and replicator dynamics equations, this paper considers the cost and gains of cooperative innovation and the amount of government support as well as other factors to build and analyze a classic evolutionary game model. On this basis, the subject’s own adaptability is introduced, which is regarded as the system noise in the stochastic evolutionary game model so as to analyze the impact of adaptability on the game strategy selection. The results show that, in the first place, without considering subjects’ adaptability, their cooperation in industrial clusters depends on the cost and gains of innovative cooperation, the amount of government support, and some conditions that can promote cooperation, namely, game steady state. In the second place after the introduction of subjects’ adaptability, it will affect both game theory selection process and time, which means that the process becomes more complex, presents the nonlinear characteristics, and helps them to make faster decisions in their favor, but the final steady state remains unchanged.


Author(s):  
Dipankar Dua ◽  
Brahmaji Vasantharao

Industrial and aeroderivative gas turbines when used in CHP and CCPP applications typically experience an increased exhaust back pressure due to pressure losses from the downstream balance-of-plant systems. This increased back pressure on the power turbine results not only in decreased thermodynamic performance but also changes power turbine secondary flow characteristics thus impacting lives of rotating and stationary components of the power turbine. This Paper discusses the Impact to Fatigue and Creep life of free power turbine disks subjected to high back pressure applications using Siemens Energy approach. Steady State and Transient stress fields have been calculated using finite element method. New Lifing Correlation [1] Criteria has been used to estimate Predicted Safe Cyclic Life (PSCL) of the disks. Walker Strain Initiation model [1] is utilized to predict cycles to crack initiation and a fracture mechanics based approach is used to estimate propagation life. Hyperbolic Tangent Model [2] has been used to estimate creep damage of the disks. Steady state and transient temperature fields in the disks are highly dependent on the secondary air flows and cavity dynamics thus directly impacting the Predicted Safe Cyclic Life and Overall Creep Damage. A System-level power turbine secondary flow analyses was carried out with and without high back pressure. In addition, numerical simulations were performed to understand the cavity flow dynamics. These results have been used to perform a sensitivity study on disk temperature distribution and understand the impact of various back pressure levels on turbine disk lives. The Steady Sate and Transient Thermal predictions were validated using full-scale engine test and have been found to correlate well with the test results. The Life Prediction Study shows that the impact on PSCL and Overall Creep damage for high back pressure applications meets the product design standards.


2018 ◽  
Vol 22 (3) ◽  
pp. 194-211 ◽  
Author(s):  
Yongqi Feng ◽  
Tianshu Zhang

Purpose The purpose of this paper is to provide a better understanding of the driving forces and structural changes of China as a market provider for Korea. This paper gives the answers for the following questions: How do China’s final demands trigger the growth of its imports from Korea? And what’s the impact of China’s final demands on the import in different industries? Design/methodology/approach Based on the Multi-Regional Input-Output model and World Input-Output Table database, this paper constructs the non-competitive imports input-output (IO) table of China to Korea. According to this table, we can calculate the induced imports coefficient and comprehensive induced import coefficients of China’s four final demands for imports from Korea in the 56 industries in China. Findings Among the four driving forces, the strongest one is changes in inventories and valuables. The impact of final consumption expenditure and fixed capital formation is much lower than that of changes in inventories and valuables, but they have a broader impact for the 56 industries. This paper finds out the China’s import induction of the final demands to Korea peaked in 2005 and 2010 and decreased greatly in 2014, so the position of China as market provider for Korea will no longer rise substantially, contrarily it will be in a steady state. Originality/value First, this paper constructs the non-competitive IO table to analyze the market provider issues between two countries and provides practical ways and methods for studies on the issues of imports and market provider. Second, this paper investigates the different roles of four final demands on driving force of China as market provider for Korea and the structural changes of China as a market provider for Korea among 56 industries from 2000 to 2014.


2021 ◽  
pp. 146808742110395
Author(s):  
José Galindo ◽  
Vicente Dolz ◽  
Javier Monsalve-Serrano ◽  
Miguel Angel Bernal Maldonado ◽  
Laurent Odillard

The aftertreatment systems used in internal combustion engines need high temperatures for reaching its maximum efficiency. By this reason, during the engine cold start period or engine restart operation, excessive pollutant emissions levels are emitted to the atmosphere. This paper evaluates the impact of using a new cylinder deactivation strategy on a Euro 6 turbocharged diesel engine running under cold conditions (−7°C) with the aim of improving the engine warm-up process. This strategy is evaluated in two parts. First, an experimental study is performed at 20°C to analyze the effect of the cylinder deactivation strategy at steady-state and during an engine cold start at 1500 rpm and constant load. In particular, the pumping losses, pollutant emissions levels and engine thermal efficiency are analyzed. In the second part, the engine behavior is analyzed at steady-state and transient conditions under very low ambient temperatures (−7°C). In these conditions, the results show an increase of the exhaust temperatures of around 100°C, which allows to reduce the diesel oxidation catalyst light-off by 250 s besides of reducing the engine warm-up process in approximately 120 s. This allows to reduce the CO and HC emissions by 70% and 50%, respectively, at the end of the test.


2012 ◽  
Vol 10 (H16) ◽  
pp. 140-140
Author(s):  
Julio Angel Fernández

AbstractWe analyze the flux of new and evolved long-period comets (LPCs) reaching the Earth's neighborhood (perihelion distances q < 1.3 AU), their physical lifetimes, and their implications as regards to the amount of meteoritic matter that is being deposited in the near-Earth region. The flux of LPCs with q < 1.3 au is found to be of about 340 ± 40, brighter than absolute total magnitude 8.6 (radius R ~ 0.6 km) (Fernández and Sosa 2012). Bearing in mind that most of these comets disintegrate into meteoritic matter, this represents a large contribution to the interplanetary dust complex which requires an amount of matter of about 10 tons s−1 to keep it in steady state. These aspects, as well as the impact rate with Earth of meteoroids of LPC origin, will be discussed in this presentation.


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