scholarly journals Interdigitated Electrode for Electrical Characterization of Commercial Pseudo-Binary Biodiesel–Diesel Blends

Sensors ◽  
2021 ◽  
Vol 21 (21) ◽  
pp. 7288
Author(s):  
Inocêncio Sanches dos Santos-Neto ◽  
Christian Diniz Carvalho ◽  
Gilberto Balby Araújo Filho ◽  
Cassio Daniel Salomão Silva Andrade ◽  
Giselle Cutrim de Oliveira Santos ◽  
...  

Non-standard diesel blends can be harmful to the environment and human health. In this context, a simple analytical method to estimate the biodiesel mixture ratio in diesel was developed based on impedance spectroscopy (IS) associated with interdigitated sensors. In this article, four different interdigitated sensors with varied comb spacing (G) were simulated using the COMSOL Multiphysics software. Based on finite element simulations, four interdigitated electrode architectures were manufactured and evaluated. The best geometry was chosen according to theoretical data simulations, and its interdigitated electrodes were manufactured for the compositional evaluation of pseudo-binary biodiesel–diesel mixtures. According to the X-ray powder diffraction technique, the deposition of the conductive layer (Au0) over the surface of the dielectric substrate (SiO2) did not alter its phase composition. In the analysis of AFM and SEM, it was possible to observe irregular edges on the electrodes, possibly related to the manufacturing process of the thin layers and mechanical stability. Another characteristic observed in the AFM images was the height of the step of the gold layer of the sensor. Several cross sections were obtained, and the mean step value was 225.71 ± 0.0032 nm. Although there were differences in the roughness, the whole sensor had nanometric roughness. Based on the finite element method simulation performed, it can be assumed that the geometric parameters more suitable for the manufacturing of the electrode are W = 20 µm, L = 1000 µm, G = 50 µm, and N = 40 digits. The electrical characterization performed by impedance spectroscopy showed that we could differentiate between biodiesel and diesel fuels and their pseudo-binary mixtures in the low-frequency region.

Author(s):  
Inocêncio Santos Neto ◽  
Christian Carvalho ◽  
Gilberto Filho ◽  
Cássio Andrade ◽  
Allan Barros ◽  
...  

Non-standard diesel blends can be harmful to the environment and human health. In this context, a simple analytical method to estimate the biodiesel mixture ratio in diesel was developed based on the impedance spectroscopy (IS) associated with the interdigitated sensors. In this article, four different interdigitated sensors, variable comb spacing (G), were simulated using the COMSOL Multiphysics software. Based on finite element simulations, four interdigitated electrode architectures by manufactured and evaluated. According to the X-ray powder diffraction technique, the deposition of the conductive layer (Au°) over the surface of the dielectric substrate (SiO2) did not alter its phase composition. In the analysis of AFM and SEM, it was possible to observe irregular edges on the electrodes, possibly related to thin layers' manufacturing process and mechanical stability. Another characteristic observed in the AFM images was the height of the step of the gold layer of the sensor. Several cross-sections were obtained, and the mean step value is 225.71 ± 0.0032 nm. Although there are differences in the roughness, the whole sensor has nanometric roughness. Based on the finite element method simulation performed, it can be assumed that the geometric parameters more suitable for the manufacturing of the electrode are: W = 20 µm, L = 1000 µm, G = 50 µm e N = 40 digits. The electrical characterization performed by impedance spectroscopy showed that we could differentiate between biodiesel and diesel fuels and their pseudo-binary mixtures in the low-frequency region.


2021 ◽  
Author(s):  
Carlos Marino ◽  
Juan Basbus ◽  
Ana L. Larralde ◽  
Jose Antonio Alonso ◽  
Maria Teresa Fernandez-Diaz ◽  
...  

This work presents the results of the structural characterization of LaSrGa1-xMgxO4-δ oxides with x=0.0-0.2 (LSGM'); these oxides with layered K2NiF4-type structure are potential electrolytes of oxygen ions with applications in...


Author(s):  
Márton Tamás Birosz ◽  
Mátyás Andó ◽  
Sudhanraj Jeganmohan

AbstractDesigning components is a complex task, which depends on the component function, the raw material, and the production technology. In the case of rotating parts with higher RPM, the creep and orientation are essential material properties. The PLA components made with the material extrusion process are more resistant than VeroWhite (material jetting) and behave similarly to weakly cross-linked elastomers. Also, based on the tensile tests, Young’s modulus shows minimal anisotropy. Multilinear isotropic hardening and modified time hardening models are used to create the finite element model. Based on the measurements, the finite element method simulation was identified. The deformation in the compressor wheel during rotation became definable. It was concluded that the strain of the compressor wheel manufactured with material extrusion technology is not significant.


2011 ◽  
Vol 90-93 ◽  
pp. 1264-1271
Author(s):  
Xiao Feng Li ◽  
Jun Yi Du

The ground structure, elastic and electronic properties of several phases of NbN are determined based on ab initio total-energy calculations within the framework of density functional theory. Among the five crystallographic structures that have been investigated, the hexagonal phases have been found to be more stable than the cubic ones. The calculated equilibrium structural parameters are in good agreement with the available experimental results. The elastic constants of five structures in NbN are calculated, which are in consistent with the obtained theoretical and experimental data. The corresponding Debye temperature and elastic ansitropies are also obtained. The Debye temperature of NbN in various structures consistent with available experimental and theoretical data, in which the Debye temperature of δ-NbN is highest. The anisotropies of ZB-NbN, NaCl-NbN, CsCl-NbN gradually increases. For hexagonal structure, the anisotropies of ε-NbN are stronger than that of δ-NbN. The electronic structures of NbN under pressure are investigated. It is found that NbN have metallization and the hybridizations of atoms in NbN under pressure become stronger.


Author(s):  
Shaoyang Dong ◽  
Xiong (Bill) Yu

Frost heave can cause serious damage to civil infrastructure. For example, interactions of soil and water pipes under frozen conditions have been found to significantly accelerate pipe fracture. Frost heave may cause the retaining walls along highways to crack and even fail in cold climates. This paper describes a holistic model to simulate the temperature, stress, and deformation in frozen soil and implement a model to simulate frost heave and stress on water pipelines. The frozen soil behaviors are based on a microstructure-based random finite element model, which holistically describes the mechanical behaviors of soils subjected to freezing conditions. The new model is able to simulate bulk behaviors by considering the microstructure of soils. The soil is phase coded and therefore the simulation model only needs the corresponding parameters of individual phases. This significantly simplifies obtaining the necessary parameters for the model. The capability of the model in simulating the temperature distribution and volume change are first validated with laboratory scale experiments. Coupled thermal-mechanical processes are introduced to describe the soil responses subjected to sub-zero temperature on the ground surface. This subsequently changes the interaction modes between ground and water pipes and leads to increase of stresses on the water pipes. The effects of cracks along a water pipe further cause stress concentration, which jeopardizes the pipe’s performance and leads to failure. The combined effects of freezing ground and traffic load are further evaluated with the model.


Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2015 ◽  
Author(s):  
Xianshi Zeng ◽  
Rufang Peng ◽  
Yanlin Yu ◽  
Zuofu Hu ◽  
Yufeng Wen ◽  
...  

Using first-principles calculations based on density functional theory, the elastic constants and some of the related physical quantities, such as the bulk, shear, and Young’s moduli, Poisson’s ratio, anisotropic factor, acoustic velocity, minimum thermal conductivity, and Debye temperature, are reported in this paper for the hexagonal intermetallic compound Ti 3 Al. The obtained results are well consistent with the available experimental and theoretical data. The effect of pressure on all studied parameters was investigated. By the mechanical stability criteria under isotropic pressure, it is predicted that the compound is mechanically unstable at pressures above 71.4 GPa. Its ductility, anisotropy, and Debye temperature are enhanced with pressure.


Ionics ◽  
2003 ◽  
Vol 9 (3-4) ◽  
pp. 238-241 ◽  
Author(s):  
M. J. Ribeiro ◽  
A. A. L. Ferreira ◽  
J. M. Ferreira ◽  
J. A. Labrincha

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