scholarly journals Improving the Surface-Enhanced Raman Scattering Performance of Silver Nanodendritic Substrates with Sprayed-On Graphene-Based Coatings

Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3404 ◽  
Author(s):  
Aida Mohammadi ◽  
Danielle Nicholls ◽  
Aristides Docoslis
Keyword(s):  
Graphene Oxide ◽  
Raman Scattering ◽  
Artificial Saliva ◽  
Spray Coating ◽  
Surface Enhanced Raman Scattering ◽  
Enhancement Effect ◽  
Sers Substrate ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

This study examines the improvements in surface-enhanced Raman scattering (SERS) performance achieved when silver nanodendritic structures are coated with various graphene-based materials, namely graphene oxide (GO), reduced graphene oxide (rGO), and graphene nanoplatelets (GNPs). The tests are performed on our unique SERS-active substrates, prepared on the surface of planar microelectrode chips using an electric field-guided Ag nanoparticle assembly process. The graphene-based materials are introduced into the substrate by means of an in-house spray-coating technique. The SERS enhancement effect of each coating is examined as a function of spray nozzle passes (N) and optimal values are identified for each coating type. The enhancements found for GO, rGO, and GNP (6–9 graphene layers thick) coatings are 2.3 (N = 25), 2.5 (N = 5), and 1.6 (N = 1), respectively. Additionally, in comparison with their uncoated counterparts, substrates coated with rGO (N = 5) are shown to enhance the intensity of the methamphetamine (5 ppb) spectrum in artificial saliva by approximately 3-fold. Overall, it can be concluded that the introduction of GO or rGO to the SERS substrate using spray-coating, a simple and also scalable method, can produce substantial SERS performance enhancement.

A facile surface enhanced Raman scattering substrate based on silver deposited sandpaper

2019 ◽  
Vol 33 (21) ◽  
pp. 1950239 ◽  
Author(s):  
Dongdong Yuan ◽  
Shu Chen ◽  
Yanan Wu ◽  
Junqiao Wang
Keyword(s):  
Silver Nanoparticles ◽  
Raman Scattering ◽  
Surface Enhanced Raman Scattering ◽  
Excitation Wavelength ◽  
Enhancement Effect ◽  
Sers Substrate ◽  
Sers Enhancement ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Flexible surface enhanced Raman scattering (SERS) substrate was prepared by modification of sandpaper with silver nanoparticles. Under 633 nm excitation wavelength, the SERS enhancement effect of sandpapers which were treated with silver nanoparticles were evaluated by collecting Raman signals of probed molecules. The results demonstrate that the SERS enhancement effect of white (12,000 meshes) is better than that of pink (8000 meshes) sandpaper under the same condition; when the concentration of probe molecules is [Formula: see text] mol/L, white sandpaper has the best SERS enhancement; the Raman scattering spectrum has better signal when the silver sol is 15 [Formula: see text].

scholarly journals Fast and Low-Cost Surface-Enhanced Raman Scattering (SERS) Method for On-Site Detection of Flumetsulam in Wheat

Molecules ◽  
2020 ◽  
Vol 25 (20) ◽  
pp. 4662
Author(s):  
Mingming Han ◽  
Hongmei Lu ◽  
Zhimin Zhang
Keyword(s):  
Raman Scattering ◽  
Pesticide Residues ◽  
Low Cost ◽  
Surface Enhanced Raman Scattering ◽  
Enhancement Effect ◽  
Sers Substrate ◽  
Surface Enhanced ◽  
Cost Surface ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

The pesticide residues in agri-foods are threatening people’s health. This study aims to establish a fast and low-cost surface-enhanced Raman scattering (SERS) method for the on-site detection of flumetsulam in wheat. The two-step modified concentrated gold nanoparticles (AuNPs) acted as the SERS substrate with the aid of NaCl and MgSO4. NaCl is served as the activator to modify AuNPs, while MgSO4 is served as the aggregating agent to form high-density hot spots. The activation and aggregation are two essential collaborative procedures to generate remarkable SERS enhancement and achieve the trace-level detection of flumetsulam. This method exhibits good enhancement effect with an enhancement factor of 106 and wide linear range (5–1000 μg/L). With simple pretreatment, the flumetsulam residue in real wheat samples can be successfully detected with the limit of detection (LOD) down to 0.01 μg/g, which is below the maximum residue limit of flumetsulam in wheat (0.05 μg/g) set in China. The recovery of flumetsulam residue in wheat ranges from 88.3% to 95.6%. These results demonstrate that the proposed SERS method is a powerful technique for the detection of flumetsulam in wheat, which implies the great application potential in the rapid detection of other pesticide residues in various agri-foods.

Hydrophilic-hydrophobic graphitic carbon nitride@silver hybrid substrate for recyclable surface-enhanced Raman scattering-based detection without coffee ring effect

The Analyst ◽  
2021 ◽  
Author(s):  
Yanjia Jiang ◽  
Huimin Sun ◽  
Chenjie Gu ◽  
Yongling Zhang ◽  
Tao Jiang
Keyword(s):  
Raman Scattering ◽  
Carbon Nitride ◽  
Surface Enhanced Raman Scattering ◽  
Graphitic Carbon Nitride ◽  
Sers Substrate ◽  
Organic P ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
Coffee Ring Effect

There is a growing interest in developing a multifunctional surface-enhanced Raman scattering (SERS) substrate to deal with the challenge of the pretreatment-free detection and degradation of hazardous molecules in organic...

scholarly journals Development of Effectual Substrates for SERS by Nanostructures-on flexible surfaces

2021 ◽  
Vol 2114 (1) ◽  
pp. 012084
Author(s):  
Hammad R. Humud ◽  
Fatimah Jumaah Moaen
Keyword(s):  
Raman Scattering ◽  
Ag Nanoparticles ◽  
Surface Enhanced Raman Scattering ◽  
Wave Number ◽  
Plasmonic Nanostructures ◽  
Sers Substrate ◽  
Two Dimensional ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering

Abstract The current study examines recent advancements in surface-enhanced Raman scattering (SERS), a technique that employs flexible surfaces as an active substrate, this surfaces consist from two-dimensional thermo-plasmonic grating. With 53 nm Au layer (was deposited on the 2D grating structure of the PDMS by the PVD method). The explosive wire technique was used to preparing Ag nanoparticles that were used for the purpose of SERS. The effect of the plasmonic nanostructures on the absorption spectra and Surface - Enhanced Raman Scattering (SERS) activities was examined. Rhodamine 6G dye was used as a probe molecule. X-Ray diffraction (XRD) was used to examine the structural characteristics of the nanoparticles. The morphology was assessed using Field Emission Scanning Electron Microscopy(FESEM). A twin beam UV-Vis Spectrophotometer was used to measure the absorption of the combined Rh6G dye (concentration 1×10“–6M) with the nanostructures. a Sunshine Raman microscope system and a 50mm objective lens, used for investigating the Raman spectra of the Rh6G combined with nanostructures. The results showed that the enhancement factor (EF) for SERS of R6G (1×M) reached to (2.2×10 3) When using Ag nanoparticles and (0.08 × 103) when R6G deposited directly on the flexible substrates without nanostructures at the wave number (1650 cm−1), we produced a recyclable, homogeneous, and highly sensitive SERS substrate with dependable reproducibility. For the SERS substrate, a surface made up of two-dimensional (2D) flexible grating substrates was chosen to provide multiple modalities in electrical and medicinal applications.

scholarly journals Performance Improving Method of Aligned Silver Nanorod by Grafting Au@Ag Core–Shell Nanoparticles for Surface-Enhanced Raman Scattering

NANO ◽  
2017 ◽  
Vol 12 (11) ◽  
pp. 1750131 ◽  
Author(s):  
Jian Chen ◽  
Peitao Dong ◽  
Chaoguang Wang ◽  
Chenyu Zhang ◽  
Junfeng Wang ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Surface Enhanced Raman Scattering ◽  
Core Shell ◽  
Sers Substrate ◽  
Shell Nanoparticles ◽  
Simple Method ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Enhanced Raman Scattering ◽  
Core Shell Nanoparticles

A simple method for improving surface-enhanced Raman scattering (SERS) performance of aligned silver nanorod (Ag NR) array was investigated. This method was to construct a kind of hybrid substrate by grafting Au@Ag core–shell nanoparticles (NPs) into Ag NR array using poly(2-vinylphridine) (P2VPy) as a bridging agent. The hybrid substrate yielded excellent SERS performance as its detection limit improved from 10[Formula: see text] M to 10[Formula: see text] M using trans-1,2-bis(4-pyridyl)ethylene (BPE) as probe molecule, which was increased by two orders of magnitude compared with Ag NR array substrate. The significant improvement of SERS performance of Ag NR arrays was attributed to the addition of Au@Ag core–shell NPs. As a result of surface plasmon resonance generated by the interaction of electromagnetic (EM) (IAEM) filed between NP and NR structures, increasing hotspots were found at the connections of NPs and NRs, the gaps of adjacent rods, and the gaps of two particles consequently. These results were validated by the finite difference time domain (FDTD) calculation. Besides, hybrid substrate shows good performance in stability and reproducibility. The proposed method was simple and robust, which promoted SERS performance of Ag NR array effectively, showing great potential in the application of SERS substrate fabrication and SERS-based bio-chemical sensing.

Sign in / Sign up

Export Citation Format

Share Document