scholarly journals Electrocatalytic Oxidation of Ascorbic Acid Using a Poly(aniline-co-m-ferrocenylaniline) Modified Glassy Carbon Electrode

Sensors ◽  
2011 ◽  
Vol 11 (11) ◽  
pp. 10166-10179 ◽  
Author(s):  
Sanoe Chairam ◽  
Worawit Sriraksa ◽  
Maliwan Amatatongchai ◽  
Ekasith Somsook
Keyword(s):  
Ascorbic Acid ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Electrocatalytic Oxidation ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode ◽  
Poly Aniline

scholarly journals Electrochemical antioxidant screening and evaluation based on guanine and chitosan immobilized MoS2 nanosheet modified glassy carbon electrode (guanine/CS/MoS2/GCE)

2020 ◽  
Vol 18 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Ping Tang ◽  
Xiaosheng Tang ◽  
Shiyong Mei ◽  
Yixi Xie ◽  
Liangliang Liu ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Antioxidant Capacity ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Oxidation Peak ◽  
Modified Glassy Carbon Electrode ◽  
Peak Current ◽  
Oxidation Peak Current ◽  
Antioxidant Capacities

AbstractIn this study, an electrochemical biosensor based on guanine and chitosan immobilized MoS2 nanosheet modified glassy carbon electrode (guanine/CS/MoS2/GCE) was developed and employed for antioxidant screening and antioxidant capacity evaluation. The oxidation peak current of guanine was improved and nearly tripled after modifications of chitosan and MoS2 nanosheet. The immobilized guanine could be damaged by hydroxyl radicals generated in Fenton solution. However, in the presence of antioxidants, the guanine was protected and the oxidation peak current of guanine increased. This process mimics the mechanism of antioxidant protection in human body. The factors affecting preparation of sensor and detection of antioxidant capacity were optimized. At the optimum conditions, the guanine/CS/MoS2/GCE showed wide linear range, low detection limit, satisfactory reproducibility and stability for detection. Ascorbic acid was used as a model antioxidant to evaluate the antioxidant capacity. A good linearity was observed with a correlation coefficient of 0.9959 in the concentrations between 0.5 and 4.0 mg L-1. The antioxidant capacities of three flavonoids were also tested and the rank of antioxidant capacities was ascorbic acid (51.84%), quercetin (45.82%), fisetin (34.39%) and catechin (16.99%). Due to the rapid measurement and low cost, this sensor could provide an available sensing platform for antioxidant screening and evaluation.

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