scholarly journals New Insight into the Influence of Rhamnolipid Bio-Surfactant on the Carbonate Rock/Water/Oil Interaction at Elevated Temperature

Resources ◽  
2018 ◽  
Vol 7 (4) ◽  
pp. 75
Author(s):  
Sina Rezaei Gomari ◽  
Kamal Elyasi Gomari ◽  
Meez Islam ◽  
David Hughes
Keyword(s):  
High Temperature ◽  
Elevated Temperature ◽  
Carbonate Rock ◽  
Contact Angles ◽  
Water Soluble ◽  
Water Flooding ◽  
Wettability Alteration ◽  
Surfactant Solutions ◽  
Washing Process ◽  
The Impact

Tertiary recovery is directly dependent on the alteration in wettability and interfacial tension (IFT), hence releasing the trapped oil from rock pore spaces. Bio-surfactant water flooding to mobilise residual oil in reservoirs is a new and developing prospect that can be used more often in future due to its environmentally friendly nature and economic advantages. In this work, the impact of rhamnolipids as water soluble bio-surfactant solutions on the interfacial activities of saline water and the wettability of carbonate rock are studied at elevated temperature. The effectiveness of the bio-surfactant as a rock wettability modifier is analysed in the presence of different salinities, in particular SO42− ions. The reason for the focus on SO42− is its high affinity towards calcite surfaces, and hence its ability to intervene strongly on bio-surfactant performance. To achieve the objectives of this study, the oil-wet calcite samples at elevated temperature were put through a washing process that included bio-surfactant solutions in seawater at various concentrations of sodium sulphate ions, where the measurement of the contact angles of each sample after treatment and the IFT between the oil model and the washing solutions were taken. The obtained results illustrated that bio-surfactants (rhamnolipids) with incremental concentrations of SO42− ions in sea water (up to three times higher than the original ion concentration) can lower the IFT, and assessed changing the rocks towards greater water-wettability. This study reveals that the alteration of SO42− ions had a greater impact on the wettability alteration, whereas rhamnolipids were better at reducing the IFT between the oil phase and the aqueous phase. This study also looked at temperatures of 50 °C and 70 °C, which demonstrated undesired influences on the wettability and IFT. Bio-surfactants at high temperature showed less interfacial activity, thus indicating that rhamnolipids are not active at high temperatures, while the addition of SO42− shows a continuous decrease in the contact angle and IFT measurements at high temperature.

Shape stability of chosen thin wood based panels after heating

2019 ◽  
Vol 106 ◽  
pp. 85-89
Author(s):  
MACIEJ SYDOR ◽  
Bartosz Pałubicki
Keyword(s):  
High Temperature ◽  
Elevated Temperature ◽  
Thin Plate ◽  
Dimensional Stability ◽  
Power Supplies ◽  
Short Term ◽  
Shape Stability ◽  
Short Term Exposure ◽  
The Impact

Shape stability of chosen thin wood based panels after heating. Lignocellulose board materials are commonly used for furniture construction. Typically, these are particle boards, fibreboard or plywood with thicknesses from 10 to 20 mm, however, some furniture elements are made of thin boards with a thickness of 3-4 mm (back walls, bottoms of drawers and others). Modern furniture uses built-in components that are a source of heat, such as lamps, power supplies, ovens. Local high temperature may negatively affect the shape stability of thin lignocellulose plates. The aim of the research described in this article was to determine the impact of shortterm exposure to high temperature on the dimensional stability of selected thin plate furniture materials. Four different HDF boards with nominal thicknesses of 3 mm and four different plywood boards with nominal thicknesses of 2 to 4 mm were tested. The test samples were subjected to a short-term exposure to temperatures of up to 250°C. As a result of the tests, it was found that HDF boards are characterized by a much higher shape stability at elevated temperature than boards made of plywood.

scholarly journals Assessment of Changes in Microstructure and Hardness of Bearing Steel for Operation at a High Temperature Caused by Short-Term Overheating

2020 ◽  
Vol 50 (4) ◽  
pp. 89-110
Author(s):  
Krzysztof Łęczycki ◽  
Sebastian Gronek
Keyword(s):  
Electron Microscope ◽  
High Temperature ◽  
Elevated Temperature ◽  
Transmission Electron Microscope ◽  
Bearing Steel ◽  
Short Term ◽  
Turbine Engine ◽  
Bearing Ring ◽  
Transmission Electron ◽  
The Impact

AbstractThe paper presented research results of the impact of short-term overheating of samples collected from the outer bearing ring suitable for the operation at elevated temperature installed in the turbine engine on the microstructure and hardness of the material. The samples were annealed at the following temperatures: 500, 600, 700, 800, 900 and 1000°C; and then cooled in still air. Microstructure examinations were conducted under metallographic microscope and transmission electron microscope.

Influence of Triton X-100 and SDBS on the Sorption of Streptomycin Sulfate from Soil

2012 ◽  
Vol 610-613 ◽  
pp. 186-189
Author(s):  
Hong Mei Zhao ◽  
Yong Li Liang ◽  
Wen Yan Zhao
Keyword(s):  
Anionic Surfactant ◽  
Contaminated Soils ◽  
Soil Washing ◽  
Distribution Coefficients ◽  
Water Soluble ◽  
Streptomycin Sulfate ◽  
Surfactant Solutions ◽  
Remediation Efficiency ◽  
Triton X ◽  
The Impact

Although surfactants have been considered in surfactant-aided soil washing systems, there is little information on the adsorption of the impact of surfactant on the adsorption of antibiotic, and this may have significant implications for the soil. In this study, Triton X-100 and SDBS were selected to study its effect on the sorption of Streptomycin sulfate from soil under equilibrium sorption. The adsorption of Streptomycin sulfate on soils in surfactant free and surfactant solutions of different critical micelle concentrations (CMCs) has been studied .The applied surfactant concentrations (X) ranged from below the (nominal) CMC to 5 times the CMC. For relatively water-soluble Streptomycin sulfate, the distribution coefficients with anionic surfactant (Kd*) deceeded those without surfactant (Kd), while non-ionic (Kd*) all exceeded those without surfactant (Kd). The Kd*/Kd ratios were used to evaluate the efficiency of surfactants and it was found that anionic surfactant is a better choice for remediation of contaminated soils whereas non-ionic surfactants leads to poor remediation efficiency.

scholarly journals Influence of Surfactant Structure on the Stability of Water-in-Oil Emulsions under High-Temperature High-Salinity Conditions

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Abdelhalim I. A. Mohamed ◽  
Abdullah S. Sultan ◽  
Ibnelwaleed A. Hussein ◽  
Ghaithan A. Al-Muntasheri
Keyword(s):  
High Temperature ◽  
High Salinity ◽  
Water Soluble ◽  
Waste Oil ◽  
Water Control ◽  
Hydrophilic Lipophilic Balance ◽  
Emulsified Water ◽  
Oil Emulsions ◽  
The Stability ◽  
The Impact

Emulsified water-in-oil (W/O) systems are extensively used in the oil industry for water control and acid stimulation. Emulsifiers are commonly utilized to emulsify a water-soluble material to form W/O emulsion. The selection of a particular surfactant for such jobs is critical and certainly expensive. In this work, the impact of surfactant structure on the stability of W/O emulsions is investigated using the hydrophilic-lipophilic balance (HLB) of the surfactant. Different commercial surfactants were evaluated for use as emulsifiers for W/O systems at high-temperature (up to 120°C) high-salinity (221,673 ppm) HTHS conditions. Diverse surfactants were examined including ethoxylates, polyethylene glycols, fluorinated surfactants, and amides. Both commercial Diesel and waste oil are used for the oleic phase to prepare the emulsified system. Waste oil has shown higher stability (less separation) in comparison with Diesel. This work has successfully identified stable emulsified W/O systems that can tolerate HTHS environments using HLB approach. Amine Acetate family shows higher stability in comparison with Glycol Ether family and at even lower concentration. New insights into structure-surfactant stability relationship, beyond the HLB approach, are provided for surfactant selection.

scholarly journals Wettability in complex porous materials, the mixed-wet state, and its relationship to surface roughness

2018 ◽  
Vol 115 (36) ◽  
pp. 8901-8906 ◽  
Author(s):  
Ahmed AlRatrout ◽  
Martin J. Blunt ◽  
Branko Bijeljic
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Pore Space ◽  
Contact Angles ◽  
Wettability Alteration ◽  
Water Repellent ◽  
Local Degree ◽  
Wide Range ◽  
Mixed Wettability ◽  
The Impact

A quantitative in situ characterization of the impact of surface roughness on wettability in porous media is currently lacking. We use reservoir condition micrometer-resolution X-ray tomography combined with automated methods for the measurement of contact angle, interfacial curvature, and surface roughness to examine fluid/fluid and fluid/solid interfaces inside a porous material. We study oil and water in the pore space of limestone from a giant producing oilfield, acquiring millions of measurements of curvature and contact angle on three millimeter-sized samples. We identify a distinct wetting state with a broad distribution of contact angle at the submillimeter scale with a mix of water-wet and water-repellent regions. Importantly, this state allows both fluid phases to flow simultaneously over a wide range of saturation. We establish that, in media that are largely water wet, the interfacial curvature does not depend on solid surface roughness, quantified as the local deviation from a plane. However, where there has been a significant wettability alteration, rougher surfaces are associated with lower contact angles and higher interfacial curvature. The variation of both contact angle and interfacial curvature increases with the local degree of roughness. We hypothesize that this mixed wettability may also be seen in biological systems to facilitate the simultaneous flow of water and gases; furthermore, wettability-altering agents could be used in both geological systems and material science to design a mixed-wetting state with optimal process performance.

scholarly journals NEW AQUEOUS POLYMER FOR HIGH-TEMPERATURE RESERVOIRS

2018 ◽  
Vol 15 (30) ◽  
pp. 380-386
Author(s):  
Y. V. SAVINYKH ◽  
L. D. LANG
Keyword(s):  
High Temperature ◽  
Oil Recovery ◽  
High Salinity ◽  
Sea Water ◽  
Polymer Flooding ◽  
Water Soluble ◽  
Water Flooding ◽  
Polymer Gel ◽  
Sweep Efficiency ◽  
Water Soluble Polymer

Polymer flooding is technologically simple and highly effective method of enhanced oil recovery. The method is based on adding a small amount of polymer in conventional water flooding of oil reservoirs. The increase in viscosity and the reduction of the mobility of injected water are to equalize the displacement front by slowing the moving of water in the highly permeable zones and restricting the formation of water finger. These factors help to increase the sweep efficiency and oil-water displacement efficiency during flooding. Polymer flooding has been used successfully in clastic and carbonate reservoirs, as well as in low-permeability reservoirs such as a fractured basement. However, most of the current polymer gel used for control water flows are decayed by a high content of ions Ca2+ and Mg2+ in formation water or in injected water. Similarly, polymer gels lose their stability at high reservoir temperature (above 70°C). Developing water-soluble polymer, which does not change their rheological properties under high salinity and high temperature (over 100°C), is very important when producing offshore, where sea water is commonly used for flooding (high salinity of 30-40 g/L).

scholarly journals Performance Evaluation of STARPAM Polymer and Application in High Temperature and Salinity Reservoir

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Chengli Zhang ◽  
Peng Wang ◽  
Guoliang Song
Keyword(s):  
High Temperature ◽  
Salt Tolerance ◽  
Heat Resistance ◽  
Oil Recovery ◽  
Physical Simulation ◽  
Water Soluble ◽  
Water Flooding ◽  
Water Soluble Polymer ◽  
Oil Displacement ◽  
Star Shaped Polymer

Based on the properties of high temperature and salinity reservoir, the water-soluble polymer with good heat resistance and salt tolerance can be obtained through copolymerization between 2-acrylamide-2-methyl sulfonate monomer (AMPSN) and acrylamide monomer (AM) in water. The star shaped stable complexes (STARPAM) with the star nucleus of β-CD are prepared by living radical polymerization, which can improve the viscosity and change the percolation characteristics of the polymer in porous media. In the article, the performance of the STARPAM (star-shaped polymer) with heat resistance and salt tolerance was evaluated by comparing the viscosification property, heat and salt resistance, calcium and magnesium tolerance, and long-term thermal stability of STARPAM (star-shaped polymer) with those of HPAM (partially hydrolyzed polyacrylamide) and MO-4000 (linear polymer). The results of physical simulation experiment showed that the viscosity of the STARPAM is 3.3 times that of MO-4000 and 4 times that of HPAM under the conditions of mineralization degree of 20000 mg/L, concentration of 1500 mg/L, and 75°C, which indicated that heat resistance and salt tolerance of the STARPAM are excellent. Oil displacement experiments showed that STARPAM can enhance oil recovery by 20.53% after water flooding, and the effect of oil displacement is excellent. At present, 19 wells were effective with a ratio of 95.2%. Compared with before treatment, the daily liquid production increased by 136 m3, daily oil production increased by 44.6 t, water cut decreased by 4.67 percentage points, and flow pressure decreased by 1.15 MPa.

scholarly journals A microfluidic study of oil displacement in porous media at elevated temperature and pressure

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Marzieh Saadat ◽  
Nora Birgitte Vikse ◽  
Gisle Øye ◽  
Marcin Dudek
Keyword(s):  
Elevated Temperature ◽  
Oil Recovery ◽  
Good Control ◽  
Recovery Factor ◽  
Wettability Alteration ◽  
Crude Oils ◽  
Low Salinity ◽  
Surfactant Solutions ◽  
Temperature And Pressure ◽  
The Difference

AbstractMicrofluidics methods offer possibilities for visual observations of oil recovery processes. Good control over test parameters also provides the opportunity to conduct tests that simulate representative reservoir conditions. This paper presents a setup and procedure development for microfluidic oil recovery tests at elevated temperature and pressure. Oil recovery factors and displacement patterns were determined in single- or two-step recovery tests using two crude oils, high salinity salt solutions and low salinity surfactant solutions. Neither the displacement pattern nor the recovery factor was significantly affected by the pressure range tested here. Increasing temperature affected the recovery factor significantly, but with opposite trends for the two tested crude oils. The difference was justified by changes in wettability alteration, due to variations in the amounts and structure of the acidic and basic oil fractions. Low salinity surfactant solutions enhanced the oil recovery for both oils.

scholarly journals Wettability Alteration in High-Temperature and High-Salinity Carbonate Reservoirs

SPE Journal ◽  
2013 ◽  
Vol 18 (04) ◽  
pp. 646-655 ◽  
Author(s):  
Gaurav Sharma ◽  
Kishore K. Mohanty
Keyword(s):  
Contact Angle ◽  
High Temperature ◽  
Oil Recovery ◽  
Carbonate Rock ◽  
High Salinity ◽  
Spontaneous Imbibition ◽  
Wettability Alteration ◽  
Surfactant Systems ◽  
Original Oil In Place ◽  
Harsh Conditions

Summary The goal of this work was to change the wettability of a carbonate rock from mixed-wet toward water-wet at high temperature and high salinity. Three types of surfactants in dilute concentrations (<0.2 wt%) were used. Initial surfactant screening was performed on the basis of aqueous stability at these harsh conditions. Contact-angle experiments on aged calcite plates were conducted to narrow the list of surfactants, and spontaneous-imbibition experiments were conducted on field cores for promising surfactants. Secondary waterflooding was carried out in cores with and without the wettability-altering surfactants. It was observed that most but not all surfactants were aqueous-unstable by themselves at these harsh conditions. Dual-surfactant systems, mixtures of a nonionic and a cationic surfactant, increased the aqueous stability. Some of the dual-surfactant systems proved effective for wettability alteration and could recover could recover 70 to 80% OOIP (original oil in place) during spontaneous imbibition. Secondary waterflooding with the wettability-altering surfactant increased the oil recovery over the waterflooding without the surfactants (from 29 to 40% of OOIP).

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