scholarly journals The Kinetics Investigation of CO2 Absorption into TEA and DEEA Amine Solutions Containing Carbonic Anhydrase

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2140
Author(s):  
Bin Liu ◽  
Zhe Cui ◽  
Wende Tian
Keyword(s):  
Carbonic Anhydrase ◽  
Carbon Capture ◽  
Large Scale ◽  
Secondary Amines ◽  
Homogeneous Catalyst ◽  
Co2 Absorption ◽  
Tertiary Amines ◽  
Pseudo First Order Reaction ◽  
Amine Solution ◽  
Carbon Dioxide Co2

Tertiary amines have been used as alternative absorbents for traditional primary and secondary amines in the process of carbon capture. However, the carbon dioxide (CO2) absorption rates in these kinds of amine are relatively slow, which implies greater investment and construction costs and limits the large-scale application of carbon capture. Carbonic anhydrase (CA) is considered to be an ideal homogeneous catalyst for accelerating the rate of CO2 into aqueous amine solution. In this work, CO2 absorption combining CA with two single aqueous tertiary amines, namely triethanolamine (TEA) and 2-(diethylamino)ethanol (DEEA), was studied by use of the stopped-flow apparatus over temperature ranging from 293 to 313 K. The concentrations of selected aqueous amine solution and CA used in the experiment were ranging among 0.1–0.5 kmol/m3 and 0–50 g/m3 , respectively. Compared to the solution without the addition of CA, the pseudo first-order reaction rate in the presence of CA (k0,withCA) is significantly increased. The values of k0,withCA have been calculated by a new kinetics model. The results of experimental and calculated k0,amine and k0,withCA in CO2-amine-H2O solutions were also investigated,respectively.

scholarly journals Enabling Large-Scale Carbon Capture, Utilisation, and Storage (CCUS) Using Offshore Carbon Dioxide (CO2) Infrastructure Developments—A Review

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1945 ◽  
Author(s):  
Lars Ingolf Eide ◽  
Melissa Batum ◽  
Tim Dixon ◽  
Zabia Elamin ◽  
Arne Graue ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Large Scale ◽  
Business Models ◽  
Reservoir Performance ◽  
High Investment ◽  
Co2 Eor ◽  
Carbon Dioxide Co2 ◽  
And Storage

Presently, the only offshore project for enhanced oil recovery using carbon dioxide, known as CO2-EOR, is in Brazil. Several desk studies have been undertaken, without any projects being implemented. The objective of this review is to investigate barriers to the implementation of large-scale offshore CO2-EOR projects, to identify recent technology developments, and to suggest non-technological incentives that may enable implementation. We examine differences between onshore and offshore CO2-EOR, emerging technologies that could enable projects, as well as approaches and regulatory requirements that may help overcome barriers. Our review shows that there are few, if any, technical barriers to offshore CO2-EOR. However, there are many other barriers to the implementation of offshore CO2-EOR, including: High investment and operation costs, uncertainties about reservoir performance, limited access of CO2 supply, lack of business models, and uncertainties about regulations. This review describes recent technology developments that may remove such barriers and concludes with recommendations for overcoming non-technical barriers. The review is based on a report by the Carbon Sequestration Leadership Forum (CSLF).

scholarly journals A study on CO2 absorption using hybrid solvents in packed columns

2019 ◽  
Author(s):  
Ravinder Kumar ◽  
Mohammad Hossein Ahmadi ◽  
Dipen Kumar Rajak ◽  
Mohammad Alhuyi Nazari
Keyword(s):  
Carbon Dioxide ◽  
Co2 Capture ◽  
Power Plants ◽  
Large Scale ◽  
Carbon Dioxide Capture ◽  
Packed Column ◽  
Absorption Efficiency ◽  
Co2 Absorption ◽  
Process Industries ◽  
Carbon Dioxide Co2

Abstract Greenhouse gases emissions from large scale industries as well as gasoline based vehicles are mainly responsible for global warming since the 1980s. At present, it has triggered global efforts to reduce the level of GHG. The contribution of carbon dioxide (CO2) in polluting the environment is at a peak due to the excessive use of coal in power plants. So, serious attention is required to reduce the level of CO2 using advanced technologies. Carbon dioxide capture and storage may play an important role in this direction. In process industries, various carbon dioxide capture techniques can be used to reduce CO2 emissions. However, post-combustion carbon dioxide capture is on top priority. Nowadays the researcher is focusing their work on CO2 capture using hybrid solvent. This work highlights a review of carbon dioxide capture using various kind of hybrid solvent in a packed column. The various challenges for absorption efficiency enhancement and future direction are also discussed in the present work. It is concluded through the literature survey that hybrid solvent shows better efficiency in comparison to the aqueous solution used for CO2 capture.

scholarly journals Biocatalytic CO2 Absorption and Structural Studies of Carbonic Anhydrase under Industrially-Relevant Conditions

2020 ◽  
Vol 21 (8) ◽  
pp. 2918
Author(s):  
Aline M. de Castro ◽  
Elisabete Ferreira ◽  
Carla Portugal ◽  
Luisa A. Neves ◽  
João G. Crespo
Keyword(s):  
Carbonic Anhydrase ◽  
Co2 Capture ◽  
Large Scale ◽  
Rate Increase ◽  
Absorption Capacity ◽  
Co2 Absorption ◽  
Structural Studies ◽  
Kinetic Rate ◽  
Capture Process ◽  
Bovine Erythrocytes

The unprecedently high CO2 levels in the atmosphere evoke the urgent need for development of technologies for mitigation of its emissions. Among the alternatives, the biocatalytic route has been claimed as one of the most promising. In the present work, the carbonic anhydrase from bovine erythrocytes (BCA) was employed as a model enzyme for structural studies in an aqueous phase at alkaline pH, which is typical of large-scale absorption processes under operation. Circular dichroism (CD) analysis revealed a high enzymatic stability at pH 10 with a prominent decrease of the melting temperature above this value. The CO2 absorption capacity of the aqueous solutions were assessed by online monitoring of pressure decay in a stainless-steel cell, which indicated a better performance at pH 10 with a kinetic rate increase of up to 43%, as compared to non-biocatalytic conditions. Even low enzyme concentrations (0.2 mg g−1) proved to be sufficient to improve the overall CO2 capture process performance. The enzyme-enhanced approach of CO2 capture presents a high potential and should be further studied.

Carbonic anhydrase mimics for enhanced CO2 absorption in an amine-based capture solvent

2016 ◽  
Vol 45 (1) ◽  
pp. 324-333 ◽  
Author(s):  
Rachael A. Kelsey ◽  
David A. Miller ◽  
Sean R. Parkin ◽  
Kun Liu ◽  
Joe E. Remias ◽  
...  
Keyword(s):  
Carbonic Anhydrase ◽  
Small Molecule ◽  
Carbon Capture ◽  
Co2 Absorption ◽  
Physiological Conditions ◽  
Basic Amine

Carbonic anhydrase converts CO2 to HCO3− in physiological conditions, but in the highly basic amine-containing solutions used industrially for carbon capture, the enzyme does not function. Instead small molecule mimics can catalyze CO2 hydration.

Carbon Capture, Utilization, and Storage: An Update

SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2444-2455 ◽  
Author(s):  
Franklin M. Orr
Keyword(s):  
Oil Recovery ◽  
Carbon Capture ◽  
Large Scale ◽  
New Technologies ◽  
Research Effort ◽  
Pilot Scale ◽  
Project Finance ◽  
Separation Processes ◽  
Carbon Dioxide Co2 ◽  
And Storage

Summary Recent progress in carbon capture, utilization, and storage (CCUS) is reviewed. Considerable research effort has gone into carbon dioxide (CO2) capture, with many promising separation processes in various stages of development, but only a few have been tested at commercial scale, and considerable additional development will be required to determine competitiveness of new technologies. Processes for direct capture of CO2 from the air are also under development and are starting to be tested at pilot scale. Transportation of CO2 to storage sites by pipeline is well-established, though substantially more pipeline capacity will be required if CCUS is to be undertaken at a large scale. Considerable experience has now been built up in enhanced-oil-recovery (EOR) operations, which have been under way since the 1970s. Storage in deep saline aquifers has also been achieved at scale. Recent large-scale projects that capture and store CO2 are described, as are current and potential future markets for CO2. Potential effects of changes in the US tax code Section 45Q on those markets are summarized. Future deployment of CCUS will depend more on cost reductions for CO2 separations, development of new markets for CO2, and the complexities of project finance than on technical issues associated with storage of CO2 in the subsurface.

scholarly journals Global Warming and Technologies for Carbon Capture and Storage

2020 ◽  
Vol 24 (9) ◽  
pp. 1671-1686
Author(s):  
O.S. Bull ◽  
I. Bull ◽  
G.K. Amadi
Keyword(s):  
Global Warming ◽  
Carbon Capture ◽  
Large Scale ◽  
Fossil Fuels ◽  
Anthropogenic Activities ◽  
Carbon Capture And Storage ◽  
Ice Caps ◽  
Metal Organic ◽  
Carbon Dioxide Co2 ◽  
And Storage

Global concern about climate change caused by anthropogenic activities, such as the large scale use of fossil fuels as major energy sources for domestic and industrial application, which on combustion give off carbon dioxide (CO2) into the atmosphere. Deforestation is also reducing one of the natural sinks for CO2. These anthropogenic activities have led to an increase in the concentration of CO2 in the atmosphere and have thus resulted in the warming of the earth’s surface (Global Warming), droughts, melting of ice caps, and loss of coral reefs. Carbon capture and storage (CCS) and other variety of emerging technologies and methods have been developed. These technologies and methods are reviewed in this article. Keywords: Global warming, carbon capture and storage, amine-based absorbents, Metal-Organic Frameworks

scholarly journals Reviews and synthesis: Carbon capture and storage monitoring – an integrated biological, biophysical and chemical approach

2015 ◽  
Vol 12 (12) ◽  
pp. 8909-8937
Author(s):  
N. Hicks ◽  
U. Vik ◽  
P. Taylor ◽  
E. Ladoukakis ◽  
J. Park ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Large Scale ◽  
Multidisciplinary Approach ◽  
Current Knowledge ◽  
Carbon Capture And Storage ◽  
Co2 Production ◽  
Geological Time ◽  
Carbon Dioxide Co2 ◽  
The Impact ◽  
And Storage

Abstract. Carbon capture and storage (CCS) is a developing technology that seeks to mitigate against the impact of increasing anthropogenic carbon dioxide (CO2) production by capturing CO2 from large point source emitters. After capture the CO2 is compressed and transported to a reservoir where it is stored for geological time scales. Potential leakages from CCS projects, where stored CO2 migrates through the overlaying sediments, are likely to have severe implications on benthic and marine ecosystems. Nonetheless, prokaryotic response to elevated CO2 concentrations has been suggested as one of the first detectable warnings if a CO2 leakage should occur. Applying properties of prokaryotic communities (i.e. community composition and metabolic status) as a novel CO2 monitoring application is highly reliable within a multidisciplinary framework, where deviations from the baseline can easily be identified. In this paper we review current knowledge about the impact of CO2 leakages on marine sediments from a multidisciplinary-based monitoring perspective. We focus on aspects from the fields of biology, geophysics, and chemistry, and discuss a case study example. We argue the importance of an integrative multidisciplinary approach, incorporating biogeochemistry, geophysics, microbial ecology and modelling, with a particular emphasis on metagenomic techniques and novel bioinformatics, for future CCS monitoring. Within this framework, we consider that an effective CCS monitoring programme will ensure that large-scale leakages with potentially devastating effects for the overlaying ecosystem are avoided. Furthermore, the multidisciplinary approach suggested here for CCS monitoring is generic, and can be adapted to other systems of interest.

scholarly journals Attitudes on Carbon Capture and Storage (CCS) as a Mitigation Technology within the UNFCCC

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 629
Author(s):  
Katherine Romanak ◽  
Mathias Fridahl ◽  
Tim Dixon
Keyword(s):  
Carbon Capture ◽  
Large Scale ◽  
Fossil Fuels ◽  
Co2 Storage ◽  
Carbon Capture And Storage ◽  
Developed Countries ◽  
Primary Role ◽  
Positive Attitudes ◽  
Carbon Dioxide Co2 ◽  
And Storage

Carbon Capture and Storage (CCS) is a technology for mitigating emissions from large point-source industries. In addition to the primary role of reducing carbon dioxide (CO2) in the atmosphere, CCS forms the basis for two large-scale negative emissions technologies by coupling geologic CO2 storage with bioenergy (BECCS) and direct air carbon capture (DACCS). Despite its inclusion within the United Nations Framework Convention on Climate Change (UNFCCC), CCS has been largely unsupported by UNFCCC delegates because of its association with fossil fuels. We evaluate data from surveys given since 2015 to UNFCCC delegates at the Conference of the Parties (COPs) to ascertain how attitudes about bioenergy, BECCS, and CCS may be changing within the UNFCCC. The results show a positive change in attitudes over time for both fossil CCS and BECCS. Using a unique data analysis method, we ascertain that, in some instances, popularity of BECCS increased due to an increased acceptance of CCS despite lower opinions of bioenergy. Business and research NGOs have the most positive views of CCS, and environmental NGOs the most negative views. Delegates that attend CCS side-events have more positive attitudes towards CCS than non-attendees. Developing countries have a larger need and a greater appetite for information on BECCS than developed countries, but a need for information exists in both.

Reaction of arylmethylenemalonaldehydes with some nucleophiles

1987 ◽  
Vol 52 (11) ◽  
pp. 2699-2709 ◽  
Author(s):  
Dalimil Dvořák ◽  
Zdeněk Arnold
Keyword(s):  
Inorganic Anions ◽  
Secondary Amines ◽  
Tertiary Amines ◽  
Primary And Secondary Amines ◽  
Dipolar Structure

Reaction of arylmethylenemalonaldehydes with tributylphosphine and tertiary amines affords compounds of dipolar structure whereas reaction with primary and secondary amines leads to 1,4-addition products. Salts of nucleophilic inorganic anions add to arylmethylenemalonaldehydes under formation of salts of substituted malonaldehydes.

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