scholarly journals Thermodynamic, Economic and Environmental Analyses of Ammonia-Based Mixed Refrigerant for Liquefied Natural Gas Pre-Cooling Cycle

Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1298
Author(s):  
Ray Soujoudi ◽  
Randall Manteufel

Analyzing the entire liquefaction cycle, using a large temperature span with many degrees of freedom, may not always result in a practical solution. The objective of this paper is to investigate the feasibility of using an environmentally friendly refrigerant compound, ammonia, in the mixed refrigerant (MR) for the liquefied natural gas (LNG) pre-cooling cycle through thermodynamic performance, economic analyses and environmental impact. Fifteen cases studies within three major mixed refrigerants groups of MR-1, MR-2 and MR-3 were developed by adding ammonia to various molar compositions of lighter and heavier hydrocarbons. The thermodynamic analysis shows increasing ammonia’s concentrations in the mixed refrigerant by 10% had the largest enhancement on coefficient of performance (COP) of MR-1 by 0.67 and decreased the specific energy consumption of the pre-cooling cycle by 128 kJ/kg compared to the base case. Economic analyses revealed that the mixed refrigerant MR-1, with ammonia, methane, ethane and propane, benefited the most from higher concentration of ammonia in the mixed refrigerant, which resulted in both lower annual capital and operational costs by $2.52 MM and $3.67 MM, respectively. Lastly, reducing the methane concentration in MR and replacing it with ammonia, decreased the amount of refrigerant leakage through compressor’s seals and reduced the global warming potential index (GWPI) of mixed refrigerant up to 24.3%.

2010 ◽  
Vol 297-301 ◽  
pp. 1146-1151 ◽  
Author(s):  
Ho Saeng Lee ◽  
S.T. Oh ◽  
Jung In Yoon ◽  
S.G. Lee ◽  
K.H. Choi

This paper presents the comparison of performance characteristics for the several natural gas liquefaction cycles. The liquefaction cycle with the staged compression was designed and simulated for improving the cycle efficiency using HYSYS software. This includes a cascade cycle with a two-stage intercooler which is consisted of a Propane, Ethylene and Methane cycle. In addition, these cycles are compared with a modified staged compression process. The key parameters of the above cascade cycles were compared and analyzed. The COP (Coefficient of Performance) of the cascade cycle with a two-stage intercooler and a modified staged compression process is 13.7% and 29.7% higher than that of basic cycle. Also, the yield efficiency of LNG (Liquefied Natural Gas) improved compared with the basic cycle by 28.5%.


Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7267
Author(s):  
Andrea Liberale Rispoli ◽  
Giacomo Rispoli ◽  
Nicola Verdone ◽  
Annarita Salladini ◽  
Emanuela Agostini ◽  
...  

The aim of this study is to analyze the exergetic, environmental, and economic impact of the electrification of a bio-refinery plant, considering the application of Mechanical Vapor Compression (MVC) to a conventional water–ethanol distillation column in the context of bioethanol production. The process was implemented in AspenPlus® and Aspen Exchange Design and Rating (EDR) simulation environments, where a sensitivity analysis was also carried out, considering four scenarios characterized by different compressions’ operative conditions, and including a Coefficient of Performance (CoP) analysis of the proposed solution with MVC. Exergetic and economic analyses were performed, and the relevant impacts on Operative Expenditure (OpEx) and Capital Expenditure (CapEx) were analyzed. Comparing the base case scenario with the proposed solution, a reduction of operative costs of around 63% was achieved. Finally, an environmental analysis was carried out, showing a remarkable reduction in the carbon footprint of the unit, with a carbon dioxide emission reduction of almost 80% for the MVC solution, in line with RED target requirements.


Author(s):  
Erwan Auburtin ◽  
Eric Morilhat ◽  
Stéphane Paquet ◽  
Abdeslam Raissi ◽  
Ewoud van Haaften ◽  
...  

Abstract Prelude Floating Liquefied Natural Gas (FLNG) facility reached a significant milestone in June 2018 when gas was introduced onboard for the first time as part of the facility startup process, loaded from an LNG carrier moored in side-by-side (SBS) configuration. This first offshore LNG SBS operation allowed Prelude’s utilities to switch from running on diesel to running on gas. SBS mooring is the base case configuration for of floading both LNG and Liquefied Petroleum Gas (LPG) into product carriers using Marine Loading Arms (MLA) once the Prelude FLNG facility is fully operational. These complex and weather sensitive operations are expected to take place on a weekly basis. This means critical decisions about weather-window and timing should be supported as much as possible by predictive analysis and modelling of environment forecasts to reduce the risks. Prelude Floating Liquefied Natural Gas (FLNG) is designed to offload Liquefied Natural Gas (LNG) and Liquefied Petroleum Gas (LPG) to carrier vessels moored in a side-by-side (SBS) configuration, using Marine Loading Arms (MLA) technology. For onshore terminals or small/medium FLNG, the traditional design of MLA (Double Counterweight Marine Arm – DCMA), featuring a vertical riser, can be used. However due to the exceptional freeboard of Prelude a new type of MLA was designed, namely the Offshore Loading Arm Footless (OLAF), without vertical riser in order to reach the LNG or LPG manifolds located as far as about 16 meters below the MLA base. Thanks to the OLAF design, the length and weight of the articulated MLA sections is reduced in comparison with conventional DCMA, and so are the dynamic loads applied by the MLA on the vessel manifold, which was mandatory to remain below the acceptable stress limit of standard LNG/LPG carrier manifolds. OLAF employs the field proven targeting system (TS) allowing the connection and disconnection of the MLA to the vessel manifold in dynamic conditions. This paper describes the assumptions and process to design and validate this new system — in terms of overall geometry and structural design, while verifying project feasibility, aiming at a reliable design of all components and minimizing the risks during operations. The key challenges and lessons learnt are also discussed. This innovative type of MLA had to be thoroughly designed and tested before being manufactured and assembled on the FLNG. The innovation management was also coupled with the additional challenge imposed by the expected highly dynamic conditions of relative motion between vessels that were never encountered for such systems in the past. MLA were designed with the objective to cover the operable envelope induced by berthing, mooring and relative motion criteria, so that it should not become an additional criterion in general. Since such an envelope is larger for this offshore application compared to sheltered terminals, this objective was particularly challenging but could be met thanks to the OLAF design. The SBS hydrodynamic numerical model is based on potential theory and includes multi-body coupling, non-linear mooring characteristics and coupling with sloshing. This model was calibrated using wave basin tests with a good agreement, and was used to determine the maximum operable environments and associated MLA envelope, using a 39-year hindcast for various LNG carriers and considering a scenario with different criteria and loading conditions. More than 100,000 time-domain simulations were required to evaluate non-linear quantities on a reduced set of environment ‘bins’. The new OLAF-type MLA was developed using these hydrodynamic simulations. Specific processes — based on spectral screening and selection using relevant criteria — were used to identify and select, in a systematic way, the designing load cases for connecting, connected, and emergency disconnection cases, while complying with the maximum allowable loads of conventional LNG and LPG carrier manifolds. An instrumented 1:4 OLAF scale model was built and tested with 6 degrees of freedom hexapods reproducing the motions on both sides of the OLAF which enabled us to confirm a 10% accuracy of the numerical studies results. The actual OLAF were dynamically tested with a full scale motion simulator before shipment to the yard for installation. The successful first operations were performed safely and confirmed the validity of the design. Measurements are now collected onboard Prelude to verify the design and when possible improve the accuracy of numerical modelling.


Processes ◽  
2018 ◽  
Vol 6 (10) ◽  
pp. 193 ◽  
Author(s):  
Matias Vikse ◽  
Harry Watson ◽  
Truls Gundersen ◽  
Paul Barton

Natural gas liquefaction is an energy intensive process where the feed is cooled from ambient temperature down to cryogenic temperatures. Different liquefaction cycles exist depending on the application, with dual mixed refrigerant processes normally considered for the large-scale production of Liquefied Natural Gas (LNG). Large temperature spans and small temperature differences in the heat exchangers make the liquefaction processes difficult to analyze. Exergetic losses from irreversible heat transfer increase exponentially with a decreasing temperature at subambient conditions. Consequently, an accurate and robust simulation tool is paramount to allow designers to make correct design decisions. However, conventional process simulators, such as Aspen Plus, suffer from significant drawbacks when modeling multistream heat exchangers. In particular, no rigorous checks exist to prevent temperature crossovers. Limited degrees of freedom and the inability to solve for stream variables other than outlet temperatures also makes such tools inflexible to use, often requiring the user to resort to a manual iterative procedure to obtain a feasible solution. In this article, a nonsmooth, multistream heat exchanger model is used to develop a simulation tool for two different dual mixed refrigerant processes. Case studies are presented for which Aspen Plus fails to obtain thermodynamically feasible solutions.


Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 272
Author(s):  
Sanghyun Che ◽  
Juwon Kim ◽  
Daejun Chang

Liquid air can be employed as a carrier of cold energy obtained from liquefied natural gas (LNG) and surplus electricity. This study evaluates the potential of liquid air as a distributed source with a supply chain for a cold storage system using liquid air. Energy storing and distributing processes are conceptually designed and evaluated considering both the thermodynamic and economic aspects. Further, the proposed supply chain is compared with a conventional NH3/CO2 cascade refrigeration system. The thermodynamic analysis demonstrates that the exergy efficiency and the coefficient of performance of the proposed supply chain are 22% and 0.56, respectively. Economic analysis is based on a life cycle cost (LCC) evaluation. From the economic analysis, the liquid air production cost and the LCC of a liquid air cold storage system (LACS) are estimated to be 40.4 USD/ton and 34.2 MMUSD, respectively. The LCC is reduced by 19% in the LACS compared with the conventional refrigeration system. The proposed supply chain is economically feasible, although its thermodynamic performances are lower than those of the conventional system. The sensitivity analysis indicates that LNG mass flow rate in the air liquefaction system and the cold storage operating time are dominant parameters affecting the economic performance.


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