scholarly journals A Modification of Palm Waste Lignocellulosic Materials into Biographite Using Iron and Nickel Catalyst

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1079
Author(s):  
Noor Hafidzah Jabarullah ◽  
Afiqah Samsul Kamal ◽  
Rapidah Othman
Keyword(s):  
Thermal Treatment ◽  
Waste Management ◽  
Control Sample ◽  
Palm Kernel ◽  
Lignocellulosic Materials ◽  
Graphite Material ◽  
Simple Method ◽  
Graphitic Structure ◽  
Iron Nickel ◽  
Palm Waste

This paper presents an alternative way to maximize the utilization of palm waste by implementing a green approach to modify lignocellulosic materials into a highly crystalline biographite. A bio-graphite structure was successfully synthesized by converting lignocellulosic materials via a simple method using palm kernel shell (PKS) as a carbon precursor. This involved the direct impregnation of a catalyst into raw material followed by a thermal treatment. The structural transformation of the carbon was observed to be significantly altered by employing different types of catalysts and varying thermal treatment temperatures. Both XRD and Raman spectroscopy confirmed that the microstructural alteration occurred in the carbon structure of the sample prepared at 800 and 1000 °C using iron, nickel or the hybrid of iron-nickel catalysts. The XRD pattern revealed a high degree of graphitization for the sample prepared at 1000 °C, and it was evident that iron was the most active graphitization catalyst. The presence of an intensified peak was observed at 2θ = 26.5°, reflecting the formation of a highly ordered graphitic structure as a result of the interaction between the iron catalyst and the thermal treatment process at 1000 °C. The XRD observation was further supported by the Raman spectrum in which PKS-Fe1000 showed a lower defect structure associated with the presence of a significant amount of graphitic structure, as a low value of (Id/Ig) ratio was reported. An HRTEM image showed a well-defined lattice fringe seen on the structure for PKS-Fe1000; meanwhile, a disordered microstructure was observed for the control sample, indicating that successful structural modification was achieved with the aid of the catalyst. Further analysis from BET found that the PKS-Fe1000 developed a surface area of 202.932 m2/g with a pore volume of 0.208 cm3/g. An overall successful modification from palm waste into graphitic material was achieved. Thus, this study will help those involved in waste management to evaluate the possibility of a sustainable process for the generation of graphite material from palm waste. It can be concluded that palm waste is a potential source of production for graphite material through the adoption of the proposed waste management process.

scholarly journals Poland’s Proposal for a Safe Solution of Waste Treatment during the COVID-19 Pandemic and Circular Economy Connection

2021 ◽  
Vol 11 (9) ◽  
pp. 3939
Author(s):  
Krzysztof Pikoń ◽  
Nikolina Poranek ◽  
Adrian Czajkowski ◽  
Beata Łaźniewska-Piekarczyk
Keyword(s):  
Thermal Treatment ◽  
Waste Management ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Economic Impact ◽  
Circular Economy ◽  
Waste Treatment ◽  
Management Systems ◽  
Waste Streams

The purpose of the study presented in this text is to show the influence of COVID-19 on waste management systems and circular economy stream, and their impact on circular economy, particularly the economic impact of the pandemic on the waste management sector, impact on circular economy objectives’ implementation as well as additional challenges like the need for hygienization of waste streams during different implementation efforts, such as changes in the municipal solid waste market and different waste processes of their disposal. Additionally, some methods—such as thermal treatment—which seemed to be not fully aligned with the circular economy approach have advantages not taken into account before. Incineration of higher volume of waste affects the waste structure and will change some of the circular economy objectives. The analysis was carried out on the example of the Polish market.

Palm Kernel Shell as Partial Coarse Aggregate Replacement in Asphalt Mixture: Optimum Binder Content and Volumetric Properties Investigation

2021 ◽  
Vol 1047 ◽  
pp. 179-185
Author(s):  
Siti Zubaidah Mohd Asri ◽  
Faridah Hanim Khairuddin ◽  
Choy Peng Ng ◽  
Noor Aina Misnon ◽  
Nur Izzi Md Yusoff ◽  
...  
Keyword(s):  
Coarse Aggregate ◽  
Asphalt Mixture ◽  
Control Sample ◽  
Palm Kernel ◽  
Binder Content ◽  
Partial Replacement ◽  
Volumetric Properties ◽  
Aggregate Gradation ◽  
Palm Kernel Shell ◽  
Mixture Samples

Pavement failures such as fatigue, rutting, cracking, bleeding, and stripping are typical pavement deterioration. Researchers have been experimenting with pavement modification to overcome these problems. This study determines the optimum binder content (OBC) for modifying an asphalt mixture with a partial replacement of coarse aggregate (5mm-14mm sieve size) with palm kernel shell (PKS). A 60/70 penetration grade bitumen was mixed with 10, 20 and 30% PKS at selected aggregate gradation following the Public Work Department of Malaysia (JKR/SPJ/2008-S4) specification. The preparation of 60 samples of unmodified and modified asphalt mixture employed the Marshall Method compacted with 75 blows. The OBC was determined based on five volumetric properties of asphalt mixture namely stability, flow, bulk density, void filled with asphalt, and void in total mix. The OBC and volumetric properties of the modified PKS asphalt mixture samples were compared with unmodified asphalt mixture samples in accordance to the specification. Results showed that the OBC sample with 30% aggregate replacement produced the highest OBC value of 5.53% relative to the control sample with 5.40% OBC. The trend for OBC with PKS replacement begins with 10% PKS with 5.30% OBC, 20% PKS with 5.32% OBC and 30% PKS. All volumetric properties of the PKS samples are within the specification limit. Thus, PKS has a promising potential as a coarse aggregate replacement in asphalt mixture.

Life Cycle Comparison of Two Options for MSW Management in Puerto Rico: Thermal Treatment vs. Modern Landfilling

2008 ◽  
Author(s):  
Giselle Balaguer-Da´tiz ◽  
Nikhil Krishnan
Keyword(s):  
Puerto Rico ◽  
Life Cycle ◽  
Thermal Treatment ◽  
Waste Management ◽  
Life Cycle Inventory ◽  
Landfill Gas ◽  
The Body ◽  
Waste To Energy ◽  
Msw Management ◽  
Wide Range

The management of municipal solid wastes (MSW) in Puerto Rico is becoming increasingly challenging. In recent years, several of the older landfills have closed due to lack of compliance with federal landfill requirements. Puerto Rico is an island community and there is limited space for construction of new landfills. Furthermore, Puerto Rico residents generate more waste per capita than people living on the continental US. Thermal treatment, or waste to energy (WTE) technologies are therefore a promising option for MSW management. It is critical to consider environmental impacts when making decisions related to MSW management. In this paper we quantify and compare the environmental implications of thermal treatment of MSW with modern landfilling for Puerto Rico from a life cycle perspective. The Caguas municipality is currently considering developing a thermal treatment plant. We compare this to an expansion of a landfill site in the Humacao municipality, which currently receives waste from Caguas. The scope of our analysis includes a broad suite of activities associated with management of MSW. We include: (i) the transportation of MSW; (ii) the impacts of managing waste (e.g., landfill gas emissions and potential aqueous run-off with landfills; air emissions of metals, dioxins and greenhouse gases) and (iii) the implications of energy and materials offsets from the waste management process (e.g., conversion of landfill gas to electricity, electricity produced in thermal treatment, and materials recovered from thermal treatment ash). We developed life cycle inventory models for different waste management processes, incorporating information from a wide range of sources — including peer reviewed life cycle inventory databases, the body of literature on environmental impact of waste management, and site-specific factors for Puerto Rico (e.g. waste composition, rainfall patterns, electricity mix). We managed uncertainty in data and models by constructing different scenarios for both technologies based on realistic ranges of emission factors. The results show that thermal treatment of the unrecyclable part of the waste stream is the preferred option for waste management when compared to modern landfilling. Furthermore, Eco-indicator 99 method is used to investigate the human health, ecosystem quality and resource use impact categories.

Integrated Refinery Waste Management

1992 ◽  
Vol 25 (3) ◽  
pp. 273-275
Author(s):  
Y.-S. Shieh ◽  
W. J. Sheehan
Keyword(s):  
Phase Separation ◽  
Liquid Phase ◽  
Thermal Treatment ◽  
Waste Management ◽  
Resource Recovery ◽  
Volume Reduction ◽  
Waste Minimization ◽  
Oil Refining ◽  
Cement Kiln ◽  
Refinery Waste

In response to the RCRA land ban regulations and TC rule promulgated by the U.S. Federal Environmental Protection Agency (EPA) in 1988-1990, an Integrated Refinery Waste Management (IRWM) program has been developed to provide cost-effective solutions to petroleum industry customers. The goal of IRWM is to provide technology based remediation treatment services to manage sludges and wastewaters generated from the oil refining processes, soils contaminated with petroleum distillates and groundwater contaminated with fuels. Resource recovery, volume reduction and waste minimization are the primary choices to mitigate environmental problems. Oil recovery has been performed through phase separation (such as centrifugation and filtration) and heating of heavy oils. Volume reduction is achieved by dewatering systems such as centrifuges and filter presses, and low temperature thermal treatment. Waste minimization can be accomplished by bioremediation and resource recovery through a cement kiln. In-situ vapor extraction has been applied to remove volatile organic compounds from the vadose zone in contaminated sites. Stabilization has been effective for soils contaminated with heavy metals and nonvolatile substances. For the listed hazardous wastes generated from the refining process, a combination of liquid/solids separation and thermal treatment has been successfully applied. The sludge from the on-site ponds or continuous operations is pumped to a surge tank before heating, phase separation and volume reduction by a two-stage centrifuge system. The first stage horizontal centrifuge has effectively separated the solids from the liquid phase containing oil and water. The oil in the liquid phase is separated from the water in the second stage vertical centrifuge and is recycled back to the refinery for re-use. The water will be sent back to the wastewater treatment system for further treatment. Pretreatment of the wastewater may be required.

scholarly journals Feeding and Cooling and Time of Thermal Treatment of a Massive Bush Made of the Complex Aluminum Bronze Cast by the Lost Foam

2014 ◽  
Vol 14 (4) ◽  
pp. 39-44
Author(s):  
P. Just ◽  
B.P. Pisarek
Keyword(s):  
Thermal Treatment ◽  
Adhesive Wear ◽  
Structure Stability ◽  
Aluminum Bronze ◽  
Aluminium Bronze ◽  
The Matrix ◽  
Iron Nickel ◽  
Lost Foam ◽  
Selection Of ◽  
Eps Pattern

Abstract Small additions of Cr, Mo and W to aluminium-iron-nickel bronze are mostly located in phases κi (i=II; III; IV),and next in phase α (in the matrix) and phase γ2. They raise the temperature of the phase transformations in aluminium bronzes as well as the casts’ abrasive and adhesive wear resistance. The paper presents a selection of feeding elements and thermal treatment times which guarantees structure stability, for a cast of a massive bush working at an elevated temperature (650-750°C) made by means of the lost foam technology out of composite aluminium bronze. So far, there have been no analyses of the phenomena characteristic to the examined bronze which accompany the process of its solidification during gasification of the EPS pattern. There are also no guidelines for designing risers and steel internal chill for casts made of this bronze. The work identifies the type and location of the existing defects in the mould’s cast. It also proposes a solution to the manner of its feeding and cooling which compensates the significant volume contraction of bronze and effectively removes the formed gases from the area of mould solidification. Another important aspect of the performed research was establishing the duration time of bronze annealing at the temperature of 750°C which guarantees stabilization of the changes in the bronze microstructure - stabilization of the changes in the bronze HB hardness.

scholarly journals Improvement of ASTM A53 Steel Durability Using Agrowastes as Carburizing Agent

2021 ◽  
Vol 13 (6) ◽  
Author(s):  
S. A. Afolalu ◽  
◽  
O. M. Ikumapayi ◽  
M.E. Emetere ◽  
T.S. Ogedengbe ◽  
...  
Keyword(s):  
Carbon Content ◽  
Control Sample ◽  
Palm Kernel ◽  
Low Carbon Steel ◽  
Grain Structure ◽  
Past Century ◽  
Low Carbon ◽  
Environment Impact ◽  
The Past ◽  
Carburized Steel

The importance of steel in manufacturing and construction over the past century cannot be over-emphasized and easy accessibility couple with excellent mechanical properties make it preferable over others. However, the problem of durability has posed a serious concern as majority of steel application are meant for long term use. Several attempts have been made to improve the durability of steel in the past and increase of carbon content in low carbon steel was found to be a suitable agent. Although getting carbon is not the challenge rather obtaining it from a sustainable source that has zero environment impact. This research identified two separate agrowaste that has high carbon content the issue of sustainability brought about the development of carburizing agent from agrowaste that are easily accessible namely palm kernel and eggshell which is employed in this research. The use of agrowaste was found to be effective as there was notable increase in grain structure of the carburized steel when compared to the control sample without carburized agent in it.

Waste Management Practice in Malaysia and Future Challenges

2020 ◽  
pp. 531-549
Author(s):  
Huang Shen Chua ◽  
Mohammed J. K. Bashir
Keyword(s):  
Thermal Treatment ◽  
Waste Management ◽  
Management Practice ◽  
Treatment Plant ◽  
Waste To Energy ◽  
Heating Value ◽  
High Heating Value ◽  
Bio Oil ◽  
Future Challenges ◽  
Combustible Gases

Malaysia current waste management systems are not able to solve the disposal rates. The reduction of waste through 3Rs programme (reduce, reuse, and recycle) is in precontemplation stage. The municipal solid waste (MSW) condition is mixed and wet. The landfill and Thermal Treatment Plant (incineration) are the current practices for the MSW disposal. Landfill created leachate while incineration released unhealthy gases. Incineration failed due to the improper management and high cost of the operation. Torrefaction is needed before it goes to the incineration to improve the high heating value (HHV). The MSW pyrolysis and gasification are able to convert into valuable products (bio-oil, biochar, combustible gases). Combustible gases can be used to feedback into the incinerator. The heat of the incinerator can be performed waste to energy (WTE), which is able to convert into electricity as a Feed-in-Tariff (FiT).

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