scholarly journals Optimization of Methanol Synthesis under Forced Periodic Operation

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 872
Author(s):  
Carsten Seidel ◽  
Daliborka Nikolić ◽  
Matthias Felischak ◽  
Menka Petkovska ◽  
Andreas Seidel-Morgenstern ◽  
...  

Traditionally, methanol is produced in large amounts from synthesis gas with heterogeneous Cu/ZnO/Al2O3 catalysts under steady state conditions. In this paper, the potential of alternative forced periodic operation modes is studied using numerical optimization. The focus is a well-mixed isothermal reactor with two periodic inputs, namely, CO concentration in the feed and total feed flow rate. Exploiting a detailed kinetic model which also describes the dynamics of the catalyst, a sequential NLP optimization approach is applied to compare optimal steady state solutions with optimal periodic regimes. Periodic solutions are calculated using dynamic optimization with a periodicity constraint. The NLP optimization is embedded in a multi-objective optimization framework to optimize the process with respect to two objective functions and generate the corresponding Pareto fronts. The first objective is the methanol outlet flow rate. The second objective is the methanol yield based on the total carbon in the feed. Additional constraints arising from the complex methanol reaction and the practical limitations are introduced step by step. The results show that significant improvements for both objective functions are possible through periodic forcing of the two inputs considered here.

Author(s):  
Tomonari KAWAI ◽  
Katsuhiro ICHIYANAGI ◽  
Takuo KOYASU ◽  
Kazuto YUKITA ◽  
Yasuyuki GOTO

2018 ◽  
Vol 8 (9) ◽  
pp. 1670 ◽  
Author(s):  
Wei Zhong ◽  
Xiang Ji ◽  
Chong Li ◽  
Jiwen Fang ◽  
Fanghua Liu

Sintered metal porous media are widely used in a broad range of industrial equipment. Generally, the flow properties in porous media are represented by an incompressible Darcy‒Forchheimer regime. This study uses a modified Forchheimer equation to represent the flow rate characteristics, which are then experimentally and theoretically investigated using a few samples of sintered metal porous media. The traditional steady-state method has a long testing time and considerable air consumption. With this in mind, a discharge method based on an isothermal chamber filled with copper wires is proposed to simultaneously determine the permeability and inertial coefficient. The flow rate discharged from the isothermal chamber is calculated by differentiating the measured pressure, and a paired dataset of pressure difference and flow rate is available. The theoretical representations of pressure difference versus flow rate show good agreement with the steady-state results. Finally, the volume limit of the isothermal chamber is addressed to ensure sufficient accuracy.


Author(s):  
Xiaofeng Yang ◽  
Zhaohui Chen ◽  
Tang-Wei Kuo

Steady-state port flow simulations were carried out with a commercial three dimensional (3D) Computational Fluid Dynamics (CFD) code using Cartesian mesh with cut cells to study the prediction accuracy. The accuracy is assessed by comparing predicted and measured mass-flow rate and swirl and tumble torques at various valve lifts using different boundary condition setup and mesh topology relative to port orientation. The measured data is taken from standard steady-state flow bench tests of a production intake port. The predicted mass-flow rates agree to within 1% with the measured data between the intermediate and high valve lifts. At low valve lifts, slight over prediction in mass-flow rate can be observed. The predicted swirl and tumble torques are within 25% of the flow bench measurements. Several meshing parameters were examined in this study. These include: inlet plenum shape and outlet plenum/extension size, embedded sphere with varying minimum mesh size, finer meshes on port and valve surface, orientation of valve and port centerline relative to the mesh lines. For all model orientations examined, only the mesh topology with the valve axis aligned closely with the mesh lines can capture the mass-flow rate drop for very high valve lifts due to flow separation. This study further demonstrated that it is possible to perform 3D CFD flow analyses to adequately simulate steady-state flow bench tests.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
R. Chandra ◽  
V. K. Vijay ◽  
P. M. V. Subbarao

This paper presents the results of an automated water scrubbing system used for enrichment of methane content in the biogas, to produce vehicular grade biomethane fuel. Incorporation of automatic control systems for precisely regulating the water level and maintaining constant operating pressure in the packed bed absorption column of water scrubbing system resulted in steady-state operation of the scrubbing system and a consistent supply of methane-enriched biogas from the gas outlet. The improved automated water scrubbing system was found to enrich 97% methane at an operating column pressure of 1.0 MPa with 2.5 m3/h biogas in-flow rate and 2.0 m3/h water in-flow rate into the scrubbing column unit.


Author(s):  
Kevin Reid ◽  
John Denton ◽  
Graham Pullan ◽  
Eric Curtis ◽  
John Longley

An investigation into the effect of stator-rotor hub gap sealing flow on turbine performance is presented. Efficiency measurements and rotor exit area traverse data from a low speed research turbine are reported. Tests carried out over a range of sealing flow conditions show that the turbine efficiency decreases with increasing sealant flow rate but that this penalty is reduced by swirling the sealant flow. Results from time-accurate and steady-state simulations using a three-dimensional multi-block RANS solver are presented with particular emphasis paid to the mechanisms of loss production. The contributions toward entropy generation of the mixing of the sealant fluid with the mainstream flow and of the perturbed rotor secondary flows are assessed. The importance of unsteady stator wake/sealant flow interactions is also highlighted.


2018 ◽  
Vol 72 (2) ◽  
pp. 59-68
Author(s):  
Tijana Urosevic ◽  
Dragan Povrenovic ◽  
Predrag Vukosavljevic ◽  
Ivan Urosevic

In this paper, the influence of operating parameters (transmembrane pressure, temperature, the flow rate of retentate) on the cross - flow microfiltration of synthetic fruit juice and periodic backwashing with air was examined. In the experiments, the Kerasep W5 ceramic membrane with a separation limit of 0.2 ?m was used. The results of experiments in which different transmembrane pressures were used showed that stationary fluxes, at stationary conditions, after 60 minutes, have similar values. So, it can be concluded that the value of the driving force is irrelevant at steady state conditions. However, until the steady state conditions are established, a positive effect of the increase in the driving force is opposed to the negative effect of the increased polarization resistance, as a result of the driving force increase. Thus, the optimal transmembrane pressure was determined amounting to 2 bars. The optimum temperature of the process of clearing the fruit juices by microfiltration is reported as 55?C. Higher temperatures are not used due to a degrading effect on the chemical composition of the juice and a long microfiltration process. With an increase in the temperature of retentate from 22?C to 55?C, the permeate flux increased up to 60%. Increasing the flow rate of retentate reduces the thickness of the formed layer on the surface of the membrane. Due to limitations of the experimental setup and the large surface area of the membrane, the specific velocity of the retentate was low, so that the effects of cross-flow filtration were absent. The use of cross-flow filtration is one of the main requirements for increasing permeate flux, but in the present case it was in overall insufficient, so we have applied periodic air backwashing for improving fruit juice flux during membrane clarification. With this technique, the deposited layer on the membrane is lifted and the permeate flux is maintained at high levels preventing establishment of the steady state in the low flux zone. The time spent for the periodic backwashing was low as compared to the benefits of the increase in the collected permeate quantity. In all experiments with periodic backwashing with air, the collected permeate quantity is higher for up to 72.5 % as compared to experiments without backwashing. By increasing the backwashing duration, the flux increase is up to 5 %, which can be significant for microfiltration at industrial scale. Therefore, this technique is certainly recommended for microfiltration in the production of fruit juices.


2021 ◽  
Author(s):  
Matthew Davis

A HgCl₂ containing diffusion source was evaluated for its potential usefulness as a calibration source for gaseous oxidized mercury (GOM) measurements. Unlike previous calibration sources described in the literature, this source made use of a flow rate of at least 1 L min-¹, and was maintained at a temperature of as low as - 15oC. Under these conditions, the source was found to emit GOM at an environmentally relevant level of 0.0905 pg s-¹, with a GOM fraction of approximately 78%. The source was found to have a consistent response to temperature, a steady state emission level of Hg could be rapidly established and the source was temporally stable. Duplicate sources were compared with one another and found to emit similar levels of Hg under identical sampling conditions. Various methods of cleaning HgCl₂ contaminated items were tested, with the most successful method using a stannous chloride wash solution.


1963 ◽  
Vol 3 (01) ◽  
pp. 85-94 ◽  
Author(s):  
P.R. Paslay ◽  
J.B. Cheatham

Abstract Rock stresses and steady-state flow rates induced by the pressure gradient associated with the flow of formation fluid into a borehole have been analytically determined for a permeable, elastic material saturated with an incompressible fluid. In this analysis, the material properties and loading are considered to he symmetric about the axis of the borehole and independent of axial position. For Case I the material is assumed to have uniform permeability in the radial direction, whereas for Case II the permeability is assumed to have been reduced in a localized region adjacent to the hole by either normal well completion and production operations or deliberate plugging during air drilling.Results of a numerical example indicate that, in the absence of plugging, the rock shear strength must be approximately two-thirds the formation fluid pressure in order to prevent rock failure. The required rock strength is high for small radial zones of plugging and decreases as the region of reduced permeability becomes larger; however, a depth of plugging can be reached beyond which there is no real gain in strength, although the flow rate can be further reduced. Introduction During normal production of oil from a well, it is often desirable to increase the production rate of the formation fluid by increasing the pressure gradient through the formation adjacent to the borehole. Depending upon the magnitude of this pressure gradient and strength of the rock material, this production-rate increase can cause sloughing of the hole wall. In many cases, the production-rate increase can result in excessive sand production, increased wear of production equipment, lost production time and expensive workover jobs.In addition, the phenomenon of increased rock bit penetration rate with the use of a gaseous instead of a liquid drilling fluid has been observed in oilfield drilling operations and experimentally demonstrated by various investigators for several years. The improvement obtained by employing this technique can be quite significant and offers a promising method for reducing drilling costs. However, air drilling is currently limited to geographical locations where high-capacity water-bearing formations are not encountered. This limitation has prevented widespread adoption of air-drilling techniques, because the water influx into the borehole interferes with efficient removal of the drilling cuttings and usually results in a condition such that the bit becomes "balled-up" or stuck in the hole.In an attempt to remove the water-intrusion limitation from air drilling, various chemical and mechanical water shut-off methods have been proposed. Goodwin and Teplitz suggested one such proposal whereby the permeability of the water - bearing rock structure was reduced in the vicinity of the borehole. Although the development of a shut-off method based upon this approach would certainly be welcomed by the oil industry, it is conceivable that, under certain conditions of the pressure gradient, strength of the rock material and depth of the modified permeability zone, a stress field can be created that will result in an unstable hole.As part of their study, an analytical solution is given for stresses in an idealized model of a hole and the surrounding rock material. The purpose of the present study is to extend the analysis of Goodwin and Teplitz to gain more insight into the details and consequences of excessive production rates and formation water shut-off. In particular, simplified models of these problems have been analytically examined, which makes possible the evaluation of the type of stress fields that can be anticipated as a result of these production and drilling practices.Both problems solved concern the determination of the steady-state volume flow rate of the formation fluid and the resulting steady-state stress and displacement distribution in a hollow, cylindrical configuration. The cylinder of Case I, corresponding to the production-rate problem, consists of a material with a constant permeability from the inside surface to the outside surface; the cylinder of Case II, corresponding to the water shut-off problem, consists of a material with a constant permeability from the inside surface to an intermediate concentric cylindrical surface and a second constant permeability from the intermediate surface to the outside surface. SPEJ P. 85^


2021 ◽  
Author(s):  
Nicole Salvatori

<p>In natural environments plants are subjected to variable light conditions and therefore need an efficient regulatory system to regulate photosynthesis and the downstream metabolism. Most of the measurements available are taken at steady state and at leaf level but those may overestimate total carbon uptake in a more dynamic environment. Furthermore, some plants may be more adapted than others to deal with light fluctuations and therefore is difficult to draw general conclusions. We then grew a commercial soybean variety and a chlorophyll deficient mutant in a recently developed growth chamber system (DYNAMISM) which allowed to obtain instantaneous gas exchange data at canopy level for several weeks. By doing so we could investigate both short term responses and long term adaptations to light dynamic conditions of the two varieties. At steady state, chlorophyll deficient crops are thought to have a similar or even a higher photosynthetic rate compared to the green wildtypes, enhanced by a higher light transmittance throughout the canopy. But little is known about how they respond to fluctuations in light. The two varieties were grown either in fluctuating (F) or non-fluctuating (NF) light conditions to evaluate how variable light would affect biomass accumulation. Two different light treatments were applied, low light (LL) and high light (HL) with different light intensities and amplitude of fluctuations. The LL treatment did not entail any difference among F and NF in both varieties. The chlorophyll-deficient mutant was instead found to be susceptible to the fluctuations of light in the HL treatment, by accumulating less biomass. It is hypothesised that this might be due to its longer non‐photochemical quenching relaxation time  in light transitions, but other acclimatation mechanisms need to be investigated.</p>


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