scholarly journals Capture and Reuse of Carbon Dioxide (CO2) for a Plastics Circular Economy: A Review

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 759
Author(s):  
Laura Pires da Mata Costa ◽  
Débora Micheline Vaz de Miranda ◽  
Ana Carolina Couto de Oliveira ◽  
Luiz Falcon ◽  
Marina Stella Silva Pimenta ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gas ◽  
Circular Economy ◽  
Carbon Capture ◽  
Chemical Transformations ◽  
Patent Literature ◽  
Bibliometric Review ◽  
Production Stages ◽  
The Many ◽  
Carbon Dioxide Co2

Plastic production has been increasing at enormous rates. Particularly, the socioenvironmental problems resulting from the linear economy model have been widely discussed, especially regarding plastic pieces intended for single use and disposed improperly in the environment. Nonetheless, greenhouse gas emissions caused by inappropriate disposal or recycling and by the many production stages have not been discussed thoroughly. Regarding the manufacturing processes, carbon dioxide is produced mainly through heating of process streams and intrinsic chemical transformations, explaining why first-generation petrochemical industries are among the top five most greenhouse gas (GHG)-polluting businesses. Consequently, the plastics market must pursue full integration with the circular economy approach, promoting the simultaneous recycling of plastic wastes and sequestration and reuse of CO2 through carbon capture and utilization (CCU) strategies, which can be employed for the manufacture of olefins (among other process streams) and reduction of fossil-fuel demands and environmental impacts. Considering the previous remarks, the present manuscript’s purpose is to provide a review regarding CO2 emissions, capture, and utilization in the plastics industry. A detailed bibliometric review of both the scientific and the patent literature available is presented, including the description of key players and critical discussions and suggestions about the main technologies. As shown throughout the text, the number of documents has grown steadily, illustrating the increasing importance of CCU strategies in the field of plastics manufacture.

A Laboratory Investigation of the Effect of Ethanol-Treated Carbon Dioxide Injection on Oil Recovery and Carbon Dioxide Storage

SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Molar Fraction ◽  
Co2 Injection ◽  
Carbon Dioxide Injection ◽  
Treated Carbon ◽  
Carbon Dioxide Co2 ◽  
And Storage ◽  
Experimental Runs

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.

Farming Facts

Eating Earth ◽  
2014 ◽  
Author(s):  
Lisa Kemmerer
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Carbon Dioxide Emissions ◽  
Gas Emissions ◽  
Animal Products ◽  
Plant Foods ◽  
Dietary Choice ◽  
Ocean Environment ◽  
Carbon Dioxide Co2

Cheap meat, dairy, and eggs are an illusion—we pay for each with depleted forests, polluted freshwater, soil degradation, and climate change. Diet is the most critical decision we make with regard to our environmental footprint—and what we eat is a choice that most of us make every day, several times a day. Dietary choice contributes powerfully to greenhouse gas emissions (GHGE) and water pollution. Animal agriculture is responsible for an unnerving quantity of greenhouse gas emissions. Eating animal products—yogurt, ice cream, bacon, chicken salad, beef stroganoff, or cheese omelets—greatly increases an individual’s contribution to carbon dioxide, methane, and nitrous oxide emissions. Collectively, dietary choice contributes to a classic “tragedy of the commons.” Much of the atmosphere’s carbon dioxide (CO2) is absorbed by the earth’s oceans and plants, but a large proportion lingers in the atmosphere—unable to be absorbed by plants or oceans (“Effects”). Plants are not harmed by this process, but the current overabundance of carbon dioxide in the atmosphere causes acidification of the earth’s oceans. As a result of anthropogenic carbon dioxide emissions, the “acidity of the world’s ocean may increase by around 170% by the end of the century,” altering ocean ecosystems, and likely creating an ocean environment that is inhospitable for many life forms (“Expert Assessment”). Burning petroleum also leads to wars that devastate human communities and annihilate landscapes and wildlife—including endangered species and their vital habitats. Additionally, our consumption of petroleum is linked with oil spills that ravage landscapes, shorelines, and ocean habitat. Oil pipelines run through remote, fragile areas—every oil tanker represents not just the possibility but the probability of an oil spill. As reserves diminish, our quest for fossil fuels is increasingly environmentally devastating: Canada’s vast reserves of tar sands oil—though extracted, transported, and burned only with enormous costs to the environment—are next in line for extraction. Consuming animal products creates ten times more fossil fuel emission per calorie than does consuming plant foods directly (Oppenlander 18). (This is the most remarkable given that plant foods are not generally as calorically dense as animal foods.) Ranching is the greatest GHGE offender.

scholarly journals Enabling Large-Scale Carbon Capture, Utilisation, and Storage (CCUS) Using Offshore Carbon Dioxide (CO2) Infrastructure Developments—A Review

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1945 ◽  
Author(s):  
Lars Ingolf Eide ◽  
Melissa Batum ◽  
Tim Dixon ◽  
Zabia Elamin ◽  
Arne Graue ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Large Scale ◽  
Business Models ◽  
Reservoir Performance ◽  
High Investment ◽  
Co2 Eor ◽  
Carbon Dioxide Co2 ◽  
And Storage

Presently, the only offshore project for enhanced oil recovery using carbon dioxide, known as CO2-EOR, is in Brazil. Several desk studies have been undertaken, without any projects being implemented. The objective of this review is to investigate barriers to the implementation of large-scale offshore CO2-EOR projects, to identify recent technology developments, and to suggest non-technological incentives that may enable implementation. We examine differences between onshore and offshore CO2-EOR, emerging technologies that could enable projects, as well as approaches and regulatory requirements that may help overcome barriers. Our review shows that there are few, if any, technical barriers to offshore CO2-EOR. However, there are many other barriers to the implementation of offshore CO2-EOR, including: High investment and operation costs, uncertainties about reservoir performance, limited access of CO2 supply, lack of business models, and uncertainties about regulations. This review describes recent technology developments that may remove such barriers and concludes with recommendations for overcoming non-technical barriers. The review is based on a report by the Carbon Sequestration Leadership Forum (CSLF).

scholarly journals Critical Analysis and Evaluation of the Technology Pathways for Carbon Capture and Utilization

2020 ◽  
Vol 2 (4) ◽  
pp. 492-512
Author(s):  
Simon P. Philbin
Keyword(s):  
Climate Change ◽  
Carbon Dioxide ◽  
Circular Economy ◽  
Critical Analysis ◽  
Carbon Capture ◽  
Research Study ◽  
Carbon Dioxide Emission ◽  
Analysis And Evaluation ◽  
Carbon Capture And Utilization ◽  
The Impact

Carbon capture and utilization (CCU) is the process of capturing unwanted carbon dioxide (CO2) and utilizing for further use. CCU offers significant potential as part of a sustainable circular economy solution to help mitigate the impact of climate change resulting from the burning of hydrocarbons and alongside adoption of other renewable energy technologies. However, implementation of CCU technologies faces a number of challenges, including identifying optimal pathways, technology maturity, economic viability, environmental considerations as well as regulatory and public perception issues. Consequently, this research study provides a critical analysis and evaluation of the technology pathways for CCU in order to explore the potential from a circular economy perspective of this emerging area of clean technology. This includes a bibliographic study on CCU, evaluation of carbon utilization processes, trend estimation of CO2 usage as well as evaluation of methane and methanol production. A value chain analysis is provided to support the development of CCU technologies. The research study aims to inform policy-makers engaged in developing strategies to mitigate climate change through reduced carbon dioxide emission levels and improve our understanding of the circular economy considerations of CCU in regard to production of alternative products. The study will also be of use to researchers concerned with pursuing empirical investigations of this important area of sustainability.

Greener Solvent Selection and Solvent Recycling for Carbon Dioxide Capture

2012 ◽  
Vol 5 (1) ◽  
Author(s):  
G. Hachem ◽  
J. Salazar ◽  
U. Dixekar
Keyword(s):  
Carbon Dioxide ◽  
Simulated Annealing ◽  
Carbon Capture ◽  
Power Plants ◽  
Carbon Dioxide Capture ◽  
Carbon Capture And Storage ◽  
Aspen Plus ◽  
Solvent Selection ◽  
Carbon Dioxide Co2 ◽  
And Storage

Carbon capture and storage (CCS) constitutes an extremely important technology that is constantly being improved to minimize the amounts of carbon dioxide (CO2) entering the atmosphere. According to the Global CCS Institute, there are more than 320 worldwide CCS projects at different phases of progress. However, current CCS processes are accompanied with a large energy and efficiency penalty. This paper models and simulates a post-combustion carbon capture system, that uses absorption as a method of separation, in Aspen Plus V7.2. Moreover, the CAPE-OPEN Simulated Annealing (SA) Capability is implemented to minimize the energy consumed by this system, and allow coal-fired power plants to use similar carbon capture systems without losing 20 to 40 % of the plant's output.

scholarly journals National Greenhouse Gas Emissions Inventory – Romania

2010 ◽  
Vol 67 (2) ◽  
Author(s):  
Marian PROOROCU ◽  
Sorin DEACONU ◽  
Mihaela SMARANDACHE
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gas ◽  
Kyoto Protocol ◽  
Fossil Fuels ◽  
Ghg Emissions ◽  
Great Probability ◽  
Emissions Inventory ◽  
National Inventory ◽  
Commitment Period ◽  
Carbon Dioxide Co2

As a Party to the United Nations Framework Convention on Climate Change (UNFCCC), and its Kyoto Protocol, Romania is required to elaborate, regularly update and submit the national GHG Inventory. In compliance with the reporting requirements, Romania submitted in 2010 its ninth version of the National Inventory Report (NIR) covering the national inventories of GHG emissions/removals for the period 1989-2008. The inventories cover all sectors: Energy, Industrial Processes, Solvent and other product use, Agriculture, LULUCF and Waste. The direct GHGs included in the national inventory are: Carbon dioxide (CO2); Methane (CH4); Nitrous oxide (N2O); Hydrofluorocarbons (HFCs); Perfluorocarbons (PFCs); Sulphur hexafluoride (SF6). The emissions trend over the 1989-2008 period reflects the changes characterized by a process of transition to a market economy. With the entire economy in transition, some energy intensive industries reduced their activities and this is reflected in the GHG emissions reduction. Energy represents the most important sector in Romania, accounting for about 69% of the total national GHG emissions in 2008. The most significant anthropogenic greenhouse gas is the carbon dioxide. The decrease of CO2 emissions is caused by the decline of the amount of fossil fuels burnt in the energy sector, as a consequence of activity decline. According to the figures, there is a great probability for Romania to meet the Kyoto Protocol commitments on the limitation of the GHG emissions in the 2008-2012 commitment period.

scholarly journals Synthesis of Sustainable Carbon Negative Eco-Industrial Parks

2021 ◽  
Vol 9 ◽  
Author(s):  
Elizabeth J. Abraham ◽  
Farah Ramadan ◽  
Dhabia M. Al-Mohannadi
Keyword(s):  
Carbon Dioxide ◽  
Circular Economy ◽  
Carbon Dioxide Emissions ◽  
Carbon Capture ◽  
Carbon Dioxide Emission ◽  
Value Added ◽  
Mixed Integer ◽  
Industrial Parks ◽  
And Storage

Growing climate change concerns in recent years have led to an increased need for carbon dioxide emission reduction. This can be achieved by implementing the concept of circular economy, which promotes the practice of resource conservation, emission minimization, and the maintenance of sustainable revenue streams. A considerable amount of carbon dioxide emissions is a consequence of stationary sources from industrial processes. These emissions can be reduced using carbon capture utilization and storage (CCUS) or reduced at source by using emission free renewable resources. The method developed within this work uses mixed integer linear programming (MILP) to design sustainable clusters that convert seawater (including waste brine), air, and waste carbon dioxide emissions to value-added products with sunlight as the main energy source. In this way, circular economy is employed to minimize fresh resource consumption and maximize material reuse. The potential of this work is demonstrated through a case study, which shows that an industrial park may be profitable while adhering to strict emission and material constraints.

scholarly journals Analysis of Hydrogen Sulfide (H2S) and Hydrocarbon Composition of Natural Gas from GMS (Gas Metering Station) in PT. Pupuk Sriwidjaja Palembang

2018 ◽  
Vol 4 (1) ◽  
pp. 17-23
Author(s):  
Rostyanesia Rostyanesia ◽  
Salmahaminati Salmahaminati ◽  
Putri Dwinanda Vidya
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
Hydrocarbon Composition ◽  
Blue Color ◽  
Steel Cylinder ◽  
The Many ◽  
Carbon Dioxide Co2 ◽  
Main Material

Natural gas of GMS (Gas Metering Station) is an important component that must be analyzed routinely in PT. Fertilizer Sriwidjaja because it is the main material used in addition to Carbon dioxide (CO2) and water vapor in the manufacture of ammonia. The quality of natural gas will affect the ammonia and urea fertilizer product. The purpose of this research is to know the composition of hydrocarbons and to know the level of H2S gas in natural gas which is contained in GMS pipes. Determination of H2S levels was performed to find out the many catalysts used in the manufacture of ammonia gas.In determining the hydrocarbon composition, the first gas sample is taken using Stainless Steel Cylinder Tube. After the gas filled tube it was analyzed using GC (Gas Chromatography) and  it will know the hydrocarbon composition of GMS. As for the determination of H2S level, the gas sample taken as much as 30 L through gas spreader and inserted into erlenmeyer with 10% Cd Acetate and NaOH. Subsequently, 1% PADAS (N, N-Dimethyl-p-phenylendiamine sulphate) and FeCl3 were added. After the solution changed to blue color then analyzed using UV-Vis Spectrophotometer in 660 nm wavelength.The results obtained are nitrogen-containing natural gas and various hydrocarbon components: methane, hexane, carbon dioxide, ethane, propane, i-butane, n-butane, i-pentane, and n-pentane with H2S 2,954 ppm with the largest composition of methane 85.89%. The results have been in accordance with the standards used in the Pusri Industry which apply the provision that the natural gas used should contain methane with concentrations greater than 70% 

scholarly journals Achieving Net Zero Emissions Requires the Knowledge and Skills of the Oil and Gas Industry

2020 ◽  
Vol 2 ◽  
Author(s):  
Astley Hastings ◽  
Pete Smith
Keyword(s):  
Carbon Dioxide ◽  
Energy Consumption ◽  
Greenhouse Gas ◽  
Carbon Capture ◽  
Oil And Gas ◽  
Ghg Emissions ◽  
Anthropogenic Activity ◽  
Low Carbon ◽  
Net Zero ◽  
Low Carbon Energy

The challenge facing society in the 21st century is to improve the quality of life for all citizens in an egalitarian way, providing sufficient food, shelter, energy, and other resources for a healthy meaningful life, while at the same time decarbonizing anthropogenic activity to provide a safe global climate, limiting temperature rise to well-below 2°C with the aim of limiting the temperature increase to no more than 1.5°C. To do this, the world must achieve net zero greenhouse gas (GHG) emissions by 2050. Currently spreading wealth and health across the globe is dependent on growing the GDP of all countries, driven by the use of energy, which until recently has mostly been derived from fossil fuel. Recently, some countries have decoupled their GDP growth and greenhouse gas emissions through a rapid increase in low carbon energy generation. Considering the current level of energy consumption and projected implementation rates of low carbon energy production, a considerable quantity of fossil fuels is projected to be used to fill the gap, and to avoid emissions of GHG and close the gap between the 1.5°C carbon budget and projected emissions, carbon capture and storage (CCS) on an industrial scale will be required. In addition, the IPCC estimate that large-scale GHG removal from the atmosphere is required to limit warming to below 2°C using technologies such as Bioenergy CCS and direct carbon capture with CCS to achieve climate safety. In this paper, we estimate the amount of carbon dioxide that will have to be captured and stored, the storage volume, technology, and infrastructure required to achieve the energy consumption projections with net zero GHG emissions by 2050. We conclude that the oil and gas production industry alone has the geological and engineering expertise and global reach to find the geological storage structures and build the facilities, pipelines, and wells required. Here, we consider why and how oil and gas companies will need to morph from hydrocarbon production enterprises into net zero emission energy and carbon dioxide storage enterprises, decommission facilities only after CCS, and thus be economically sustainable businesses in the long term, by diversifying in and developing this new industry.

GREENHOUSE GAS EMISSION FROM COMBUSTION OF ASSOCIATED PETROLEUM GAS IN RUSSIA

2021 ◽  
pp. 54-61
Author(s):  
N. V. Popov ◽  
◽  
I. L. Govor ◽  
M. L. Gitarskii ◽  
◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
Component Composition ◽  
Emission Factors ◽  
Gas Emission ◽  
Associated Petroleum Gas ◽  
Carbon Dioxide Co2

The average weighted long-term component composition of associated petroleum gas burned at the fields in Russia is obtained, where the volume fractions of carbon dioxide (CO2) and methane (CH4) make up 0.8 and 66.4%, respectively. Based on it, the national emission factors of greenhouse gases from the flaring of associated petroleum gas are developed: the values are equal to 2.76 103 t CO2 and 0.0155 103 t CH4 per 1 106 m3 of the gas burnt. The calculations based on the emission factors led to the 37% increase in total equivalent emission of CO2 and CH4 as compared to the calculations based on the IPCC emission factors. The use of the national emission factors increases the reliability of the estimates of greenhouse gas emissions and the evaluation of their impact on climate.

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