scholarly journals Biodiesel Dry Purification Using Unconventional Bioadsorbents

Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 194
Author(s):  
Emilio Arenas ◽  
Stephanie M. Villafán-Cáceres ◽  
Yetzin Rodríguez-Mejía ◽  
Jonathan A. García-Loyola ◽  
Omar Masera ◽  
...  

The dry washing method is an alternative to replace water washing, thereby reducing the negative impacts of contamination. However, commercial adsorbents come from industrial processes that, due to their composition, may not be such a sustainable resource in the global biodiesel production process. In this study, the use of organic residues, such as sawdust, coconut fiber, nutshell, rice husk, and water hyacinth fiber, were proposed as bioadsorbents for the purification of biodiesel from waste cooking oil. Quality parameters such as the acid number, water content, and free and total glycerin content were evaluated and compared with those after purification with commercial adsorbents (Magnesol and Amberlite BD10DRY). Promising results were obtained using sawdust in the purification process, achieving a reduction in the acid number value of 31.3% respect to the unpurified biodiesel. Indeed, the reduction with sawdust was more efficient than with Amberlite BD10DRY (that increased the acid number). In addition, sawdust reduced free glycerin by 54.8%, again more efficient than Amberlite BD10DRY. The total glycerin values were similar between commercial adsorbents and sawdust. Water content after purification with sawdust was similar to the obtained with Amberlite BD10DRY and better than with Magnesol (399, 417, and 663 mg/kg respectively). These results show that sawdust can be used as an alternative bioadsorbent in a dry purification method for biodiesel, generating less environmental impact.

Author(s):  
Emilio Arenas ◽  
Stephanie Michelle Villafan ◽  
Yetzin Rodríguez Mejía ◽  
Jonathan Alejandro García Loyola ◽  
Omar Masera ◽  
...  

The dry washing method is an alternative to replace water washing, thereby reducing the negative impacts of contamination. However, commercial adsorbents come from industrial processes that, due to their composition, may not be such a sustainable resource in the global biodiesel production process. In this study, the use of organic residues, such as sawdust, coconut fiber, nutshell, rice husk and water hyacinth fiber, were proposed as bioadsorbents for the purification of biodiesel from waste cooking oil (WCO). Quality parameters such as the acid value, water content, and free and total glycerin content were evaluated and compared with those of commercial resins such as Magnesol® and Amberlite™. Promising results were obtained using sawdust during the purification process, achieving a 31.6% reduction in the acid value compared to that of unpurified biodiesel, the reduction was 31.3% more efficient than Amberlite™. Sawdust adsorbed free glycerin at 55.8%, being more efficient than Amberlite™. The total glycerin values were similar between commercial resins and sawdust. A water content values were similar than Amberlite™ and better than that with Magnesol®, at 4.3% and 39.81%, respectively. These results show that sawdust can be used as an alternative bioadsorbent in a dry purification method for biodiesel being a residue with less environmental impact.


2019 ◽  
Vol 96 (12) ◽  
pp. 1379-1388
Author(s):  
Larissa Braga Bueno‐Borges ◽  
Grasiela Cristina Pereira dos Santos ◽  
Severino Matias Alencar ◽  
Marisa Aparecida Bismara Regitano‐d'Arce

Separations ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 22 ◽  
Author(s):  
Aleksandra Sander ◽  
Ana Petračić ◽  
Jelena Parlov Vuković ◽  
Lana Husinec

Over three billion cups of coffee are consumed daily, making waste coffee grounds readily available throughout the world. Containing approximately 10–15 wt% of oil, they have great potential for biodiesel production. The goal of this work was to produce high quality biodiesel from waste coffee grounds. One fresh and four different types of waste coffee grounds were collected. Oil was extracted by the Soxhlet method with n-hexane and then purified via extractive deacidification with a potassium carbonate-based deep eutectic solvent. Biodiesels were synthesized by means of alkali catalyzed transesterification at different catalyst:methanol:oil mass ratios and reaction times. Impurities present in crude biodiesels were extracted with a choline chloride-based deep eutectic solvent. All batch extraction experiments were performed at room conditions in a small scale extractor. Optimal conditions for synthesis and purification were defined in order to assure high quality of the produced biodiesel. Additionally, continuous column extraction with the choline chloride-based solvent was tested as a purification method for crude biodiesel. Stabilization time and optimal biodiesel to solvent mass ratio were determined. The potassium carbonate-based solvent efficiently reduced the total acid number of the feedstock (deacidification efficiency ranged from 86.18 to 94.15%), while the one based on choline chloride removed free glycerol and glycerides from crude biodiesels. After continuous purification, the purified biodiesel was of excellent quality with glycerol and glyceride contents below the EN 14214 limit.


REAKTOR ◽  
2018 ◽  
Vol 18 (03) ◽  
pp. 149 ◽  
Author(s):  
Luqman Buchori ◽  
Dinda Labibah Ubay ◽  
Khonsa Syahidah

Biodiesel is one of diesel fuel alternative made from renewable resources such as vegetable oils and animal fats. One of the natural ingredients that can be used as a material in the production of biodiesel is waste cooking oil (WCO). Biodiesel from WCO can be made through a transesterification reaction using a CaO catalyst. Free fatty acid (FFA) content in WCO needs to be reduced by activated charcoal adsorption. This research aims to determine the optimum time of adsorption by activated charcoal that made from salak peel and to determine the effect of transesterification temperature on biodiesel yield. The results showed that the FFA content of WCO decrease from 6.16% to 0.224% with adsorption time is 80 minutes and 10 gram of activated charcoal. Biodiesel yield increase by increasing transesterification temperature. The appropriate temperature is 50oC with 86.40% of yield, 887.2 kg/m3of density, 5.174 mm2/s of kinematic viscosity and acid number 0.421 mg KOH/gram sample. The composition of alkyl ester was obtained 65.54% with a FAAE yield of 56.63%.


Konversi ◽  
2018 ◽  
Vol 5 (1) ◽  
pp. 8
Author(s):  
Muthia Elma ◽  
Satria Anugerah Suhendra ◽  
Wahyuddin Wahyuddin

Abstrak-Indonesia memiliki hasil produksi buah kelapa yang hanya dimanfaatkan untuk memasak. Minyak jelantah merupakan hasil dari sisa penggorengan rumah tangga yang setelah penggunaanya menjadi limbah dan dapat mencemari lingkungan. Penelitian ini bertujuan untuk memproduksi biodiesel dengan memanfaatkan campuran antara minyak kelapa dan minyak jelantah terhadap efek penambahan metanol dan waktu reaksi optimum dari pembuatan biodiesel. Proses produksi biodiesel dari campuran kedua bahan baku menggunakan proses dimana minyak kelapa dan minyak jelantah dicampurkan berdasarkan %-v/v dari 200 mL dengan perbandingan minyak jelantah (MJ) dan minyak kelapa (MK) yaitu 100MJ:0MK; 75MJ:25MK; 50MJ:50MK; 25MJ:75MK; dan 0MJ:100MK dengan komposisi metanol serta esterifikasi 38%; 30%; 28%; 19% serta untuk trasesterifikasi 19%; 20%; 21%; 25%. Pada reaksi esterifikasi menggunakan komposisi katalis H2SO4 0,5%, dan transesterifikasi menggunakan katalis KOH 0,9%. Yield yang dihasilkan dari penelitian ini adalah: 100MJ:0MK 92,15%; 93,65%, 75MJ:25MK (96,65%), 50MJ:50MK (95,11%), 25MJ:25MK (96,65%) dan 100MK:0MJ (82,65%). Analisa gliserol total yang didapat pada penelitian ini adalah 100MJ:0M (0,19%), 75MJ:25MK (0,21%), 50MJ:50MK (0,23%) 25MJ:25MK (0,22%) dan 100MK:0MJ (0,26%). Dari hasil analisa gliserol total tersebut didapat sampel yang terbaik yakni 50MJ:50MK dengan nilai glirserol total 0,23% dengan waktu 60 menit untuk esterifikasi dan 70 menit untuk transesterifikasi, dengan analisa angka asam yang didapatkan sebesar 0,2117, angka penyabunan 198,41; ester content  yang didapat sebesar 98,163% water content untuk sebesar 0,56 ppm. Keseluruhan dari hasil analisa biodiesel tersebut memenuhi standar EN 14214.  Kata kunci: minyak kelapa, minyak jelantah, biodiesel, FFA, trigliserida, gliserol total.  Abstract-Coconut oil is normally produced as cooking oil in some areas in Indonesia. However, palm oil mostly produced by industries as vegetable/cooking oil.Waste cooking oil from palm oil becomes a big problem in the environment, and creates pollution. This research aims to use waste cooking oil to produce biodiesel by mixing waste cooking oil and coconut oil. Those mixed oils become raw materials for this proces. The composition of the mixtures are  100MJ: 0MK; 75MJ: 25MK; 50MJ: 50MK; 25MJ: 75MK; and 0MJ: 100MK (% v / v of waste cooking oil (MJ) and coconut oil (MK)).The total of 200 mL oil mixtures was used for the esterification process with methanol composition were 38%; 30%; 28%; and trans-esterification were 19%; 20%; 21%; 23%. Esterification reaction was using the 0,5% H2SO4 as a catalyst, while transesterification was using 0.9% KOH as catalyst. The yield of biodiesel this reaserch were: 100MJ: 0MK (92.15%), 75MJ: 25MK (96.65%), 50MJ: 50MK (95.11%), 25MJ: 25MK (96.65%) and 100MK: 0MJ (82.65%). Furthermore, the total glycerol values were 100MJ:0MK (0.19%), 75MJ: 25MK (0.21%), 50MJ:50MK (0.23%) 25MJ: 25MK (0.22%) and 100MK: 0MJ (0.26%). EN14214 standard shows that the best composition of mixtured oils was 50MJ:50MK. Then, the total glycerol was 0.23% (60-70 minutes for the esterification and transesterification reaction). Acid number value was 0.2117, saponification number was 198.41; ester content was 98.163% and water content was 0.56 ppm.  Keywords: coconut oil, waste cooking oil, biodiesel, FFA, triglyceride, total glycerol.


Food Research ◽  
2020 ◽  
Vol 4 (S1) ◽  
pp. 220-226
Author(s):  
Widayat ◽  
Hadiyanto ◽  
D.A. Putra ◽  
Nursafitri I. ◽  
H. Satriadi ◽  
...  

The objective of this research was to produce biodiesel using waste cooking oil and various magnetite catalysts with the esterification-transesterification process. Magnetite catalysts tested were α- Fe2O3, α- Fe2O3/Al2O3, α- Fe2O3/ZSM-5 catalysts. Catalysts were prepared through chemical precipitation and calcination. The esterificationtransesterification process was carried out with the conditions WCO: methanol molar ratio of 15:1, catalyst (1% wt of oil), heated at 65℃ for 3 hrs. The results showed biodiesel production using α- Fe2O3-ZSM-5 catalyst obtained higher %FAME (83.28%), yield (91.915%) and monoglyceride content (16.72%) compared to others due to larger pore volume. Biodiesel produced passed the requirement of Indonesian National Standard (SNI) based on density, acid number and viscosity.


2018 ◽  
Vol 10 (2) ◽  
pp. 14-19
Author(s):  
Andesta Yulanda ◽  
Lisna Wahyuni ◽  
Rahmi Safitri ◽  
Abu Bakar ◽  
Muhammad Dani Supardan

ABSTRAK. Transesterifikasi merupakan salah satu proses dalam pembuatan biodiesel. Metode transesterifikasi secara konvesional tanpa penambahan adsorben memiliki kekurangan pada rendemen dan mutu biodiesel sehingga dikembangkan metode transesterifikasi menggunakan adsorben secara simultan. Penelitian ini bertujuan untuk pemanfaatan bentonit sebagai penyerap air untuk meningkatkan rendemen biodiesel pada proses transesterifikasi minyak jelantah. Pertama dilakukan pengecilan ukuran bentonit menjadi 100 hingga 120 mesh dan dilanjutkan dengan aktivasi bentonit menggunakan asam sulfat 98% pada suhu 80oC. Hasil analisis Scanning Electron Microscope menunjukkan bentonit aktivasi memiliki permukaan yang lebih halus dan bersih dibandingkan dengan bentonit tanpa aktivasi. Selanjutnya, bentonit digunakan pada proses transesterifikasi minyak jelantah dengan variasi massa adsorben (1, 2, 3 dan 4 %-berat minyak) dan kadar air minyak jelantah (2, 3, 5 dan 6 %-berat minyak). Hasil penelitian menunjukkan bahwa penggunaan bentonit teraktivasi menghasilkan rendemen yang lebih tinggi dibandingkan bentonit tanpa aktivasi dan proses tanpa menggunakan bentonit. Hasil penelitian terbaik diperoleh pada massa adsorben 3% dan kadar air 2% yaitu rendemen biodiesel sebesar 81%, massa jenis 865 kg/m3, viskositas 2,90 mm2/s, angka asam 0,1675 mg KOH/gram dan kadar air 0,70%.ABSTRACT.Transesterification is one of process in production of biodiesel. Conventional transterification method without adding adsorbent has deficiency in the yield and quality of biodiesel, therefore transesterification using adsorbent simultaneously is developed. The purpose of this research is to utilize bentonit as the adsorbent of water to increase yield of biodiesel in the waste cooking oil transesterication process. The first step to do in this research was bentonite crushing to the size of 100 to 120 mesh and then bentonite activation using sulfuric acid 98% at 80 oC. The result of SEM analysis showed that activated bentonite surface was smoother  and more clean than bentonite without activation. Bentonite is used to transesterification process by varying mass of adsorben (1, 2, 3 and 4 %-wt. of waste cooking oil) and water content (2, 3, 5 and 6 %-wt. of waste cooking oil). The result of this research showed that activated bentonite has better yield than without adsorbent and activation. The best result from this research is at adsorbent mass 3% and water content 2% with biodiesel yield 81%. The biodiesel produced have density of 865 kg/m3, viscosity of 2.90 mm2/s, acid number of 0.1675 mg KOH/gram and water content of 0.7%.


2016 ◽  
Vol 9 (1) ◽  
pp. 50-55
Author(s):  
Saibun Sitorus

The research about utilization ash of coconut husk as source of base catalyst in aplication for reaction of transesterification from Jatropha curcas oil has been researched. Content of base compound in coconut husk ash was analyzed by AAS and acidy alkalimetry. The base catalyst was extracted using methanol, for transesterification reaction of Jatropha curcas oil. This method of biodiesel production by transesterification process used coconut husk ash catalyst by weight variation as much as 2%, 4%, 6%, 8% and 10% (w/w). Analysis of the quality of biodiesel is done with quality parameters acid number, iodine number, density, viscosity and water content in accordance with SNI 04-7182-2006 standards. The result of the research showed that potassium concentration as carbonat salt in the ash of coconut husk was 17,4% (w/w) and the conversion of biodiesel obtained from each catalyst in a row is 43,62%; 78,45%; 76,22%; 75,69% and 63,27% (w/w). Biodiesel optimum results obtained with the addition of the catalyst are 4% with density values of 0.86 (g / mL), the viscosity value of 3.23 (cSt), the value of water content 0.0352%, 0.12 acid number (mg KOH / g) and iodine number of 8.23 (g I2 / 100 g).The research about utilization ash of coconut husk as source of base catalyst in aplication for reaction of transesterification from Jatropha curcas oil has been researched. Content of base compound in coconut husk ash was analyzed by AAS and acidy alkalimetry. The base catalyst was extracted using methanol, for transesterification reaction of Jatropha curcas oil. This method of biodiesel production by transesterification process used coconut husk ash catalyst by weight variation as much as 2%, 4%, 6%, 8% and 10% (w/w). Analysis of the quality of biodiesel is done with quality parameters acid number, iodine number, density, viscosity and water content in accordance with SNI 04-7182-2006 standards. The result of the research showed that potassium concentration as carbonat salt in the ash of coconut husk was 17,4% (w/w) and the conversion of biodiesel obtained from each catalyst in a row is 43,62%; 78,45%; 76,22%; 75,69% and 63,27% (w/w). Biodiesel optimum results obtained with the addition of the catalyst are 4% with density values of 0.86 (g / mL), the viscosity value of 3.23 (cSt), the value of water content 0.0352%, 0.12 acid number (mg KOH / g) and iodine number of 8.23 (g I2 / 100 g).ABSTRAKPenelitian tentang pemanfaatan abu sabut kelapa sebagai sumber katalis basa pada aplikasi reaksi transesterifikasi minyak biji jarak pagar (Jatropha curcas. L) telah dilakukan. Karakterisasi kadar basa dalam sabut kelapa dilakukan dengan AAS dan alkalinitas. Katalis basa diperoleh dengan pengadukan abu sabut kelapa dalam metanol dan selanjutnya digunakan untuk reaksi transesterifikasi minyak biji jarak pagar (Jatropha curcas. L). Metode pembuatan biodiesel ini dengan transesterifikasi menggunakan katalis abu sabut kelapa dengan variasi berat sebanyak 2%, 4%, 5%, 6%, 8% dan 10% (b/b). Analisis kualitas dari biodiesel dilakukan dengan parameter mutu bilangan asam, bilangan iod, densitas, viskositas dan kadar air sesuai dengan standar SNI 04-7182-2006. Hasil penelitian menunjukkan bahwa kadar kalium dalam bentuk kalium karbonat dalam abu sabut kelapa sebesar 17,4% (b/b) dan konversi biodiesel yang diperoleh dari masing masing katalis berturut-turut adalah 43,62%; 78,45%; 76,22%; 75,69% dan 63,27% (b/b). Hasil optimum biodiesel diperoleh dengan penambahan katalis 4% dengan nilai densitas 0,86 (g/mL), nilai viskositas 3,23 (cSt), nilai kadar air 0,0352%, bilangan asam 0,12 (mg KOH/g) dan bilangan iod sebesar 8,23 (g I2/100 g). Kata kunci :    Abu sabut kelapa, biodiesel, transesterifikasi, minyak biji jarak pagar(Jatropha curcas. L)


2020 ◽  
Vol 162 ◽  
pp. 1906-1918
Author(s):  
Nattawat Petchsoongsakul ◽  
Kanokwan Ngaosuwan ◽  
Worapon Kiatkittipong ◽  
Doonyapong Wongsawaeng ◽  
Suttichai Assabumrungrat

2017 ◽  
pp. 116-121 ◽  
Author(s):  
Salih Muharam ◽  
Lela Mukmilah Yuningsih ◽  
Iim Sulaeman Rohana

Penyulingan minyak nilam tradisional dilakukan dalam kapasitas kecil dan menggunakanmetode penyulingan sederhanaberdasarkan pada perbedaan titik didih yang jauh atau salah satu komponen bersifat volatil. Proses ini menghasilkan kualitas minyak nilam kurang baik seperti bilangan asam lebih dari 8, minyak berwarna gelap, patchouli alkohol kurang dari 30%, dan kadarair tinggi.Pada penelitian ini telah dilakukan penyulingan minyak dari tanaman nilammenggunakan kombinasi metode yaitu fermentasi-delignifikasi, destilasi dan pemurnian untuk meningkatkan kualitas minyak nilam. Hasil penelitian ini menunjukan bahwa kombinasi proses fermentasi-delignifikasi-destilasi-adsorpsi menghasilkan kualitas minyak nilam yang lebih baik dengan kualitas bilangan asam, kandungan patchouli alkohol,  kadar air dan bobot jenis berturut-turut adalah 7.48, 35.60%, 0.56%,0.0957. The traditional distillationof patchouli oil conducted in small capacity and using a simple distillation method based on differences of wide a boiling point or one component is volatile. This process results a poor quality of patchouli oils such as the acid numbers is more than 8, dark-colored oils, patchouli alcohols contentis less than 30%, and high water content. In this research has been done oil distillation from patchouli plants using a combination of methods i.e. fermentation-delignification, distillation and purification to improve of patchouli oil quality. The results show that the combination of the fermentation-delignification-distillation-adsorptionis better in quality of patchouli oil with the acid number, patchouli alcohol content, water content and density were 7.48, 35.60%, 0.56%, and 0.0957 respectively.


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