scholarly journals Gasification Applicability of Korean Municipal Waste Derived Solid Fuel: A Comparative Study

Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1375
Author(s):  
Sang Yeop Lee ◽  
Md Tanvir Alam ◽  
Gun Ho Han ◽  
Dong Hyuk Choi ◽  
Se Won Park
Keyword(s):  
Solid Fuel ◽  
Fossil Fuels ◽  
Fixed Bed ◽  
Experimental Results ◽  
Municipal Waste ◽  
Fixed Bed Reactor ◽  
Renewable Energy Resources ◽  
Syngas Production ◽  
Cold Gas Efficiency ◽  
Gas Efficiency

Gaining energy independence by utilizing new and renewable energy resources has become imperative for Korea. Energy recovery from Korean municipal solid waste (MSW) could be a promising option to resolve the issue, as Korean MSW is highly recyclable due to its systematic separation, collection and volume-based waste disposal system. In this study, gasification experiments were conducted on Korean municipal waste-derived solid fuel (SRF) using a fixed bed reactor by varying the equivalence ratio (ER) to assess the viability of syngas production. Experiments were also conducted on coal and biomass under similar conditions to compare the experimental results, as the gasification applicability of coal and biomass are long-established. Experimental results showed that Korean SRF could be used to recover energy in form of syngas. In particular, 50.94% cold gas efficiency and 54.66% carbon conversion ratio with a lower heating value of 12.57 MJ/Nm3 can be achieved by gasifying the SRF at 0.4 ER and 900 °C. However, compared to coal and biomass, the syngas efficiency of Korean SRF was less, which can be resolved by operating the gasification processes at high temperatures. If proper research and development activities are conducted on Korean SRF, it could be a good substitute for fossil fuels in the future.

scholarly journals Syngas Characteristics From Catalytic Gasification of Polystyrene and Pinewood in CO2 Atmosphere

2021 ◽  
Vol 143 (5) ◽  
Author(s):  
Xuan Liu ◽  
Kiran Raj G. Burra ◽  
Zhiwei Wang ◽  
Jinhu Li ◽  
Defu Che ◽  
...  
Keyword(s):  
Mole Fraction ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Catalytic Gasification ◽  
Syngas Production ◽  
Cold Gas Efficiency ◽  
Gas Efficiency ◽  
Al2o3 Catalyst ◽  
Co2 Atmosphere ◽  
Cold Gas

Abstract Syngas production from catalytic gasification of polystyrene and pinewood in CO2 atmosphere was investigated over Ni-Mg/Al2O3 catalyst in a fixed-bed reactor at 900 °C. A quasi in situ method was adopted for catalytic gasification wherein the catalyst placed downstream of the feedstock in the same reactor was used for enhanced syngas production. The effect of catalyst on evolutionary behavior, cumulative syngas yield, syngas composition, and cold gas efficiency was systematically analyzed. The results showed that addition of catalyst for polystyrene gasification resulted in enhanced yields of 63% H2, 20% CO, 119% CH4, and 85% C2-C3 yields. Enhanced H2 and light hydrocarbon yields were mainly from enhanced cracking of pyrolytic vapors from polystyrene degradation, while the CO yield was attributed to CO2-assisted reforming of benzene derivatives from primary cracking and polycyclic aromatic hydrocarbons (PAHs) from secondary gas phase condensations. The yields of H2, CO, CH4, and C2-C3 from pinewood gasification in the presence of catalyst was also enhanced by 150%, 14%, 39%, and 16%, respectively, indicating that Ni-Mg/Al2O3 catalyst can efficiently enhance syngas production in CO2-assisted gasification. A comparison of syngas composition between non-catalytic and catalytic conditions revealed improved syngas quality in catalytic gasification with increased H2 mole fraction but decreased CO mole fraction. Furthermore, cold gas efficiency enhanced from 44% to 57% in catalytic polystyrene gasification, and from 75% to 94% in catalytic pinewood gasification. The results suggest that catalytic CO2 gasification offers a promising pathway for efficient energy production from wastes plastics and biomass while simultaneously using CO2.

Effects of operating parameters on co-gasification of coconut petioles and refuse-derived fuel

2021 ◽  
pp. 0734242X2110039
Author(s):  
Natvaree Chommontha ◽  
Awassada Phongphiphat ◽  
Komsilp Wangyao ◽  
Suthum Patumsawad ◽  
Sirintornthep Towprayoon
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Producer Gas ◽  
Treatment Technology ◽  
Flow Rates ◽  
Cold Gas Efficiency ◽  
Refuse Derived Fuel ◽  
Agent Flow ◽  
Gas Efficiency ◽  
Cold Gas

Coconut agro-industry in the western region of Thailand generates a large amount of residues. This study investigated the energy production potential of discarded coconut petioles, with a focus on co-gasification with refuse-derived fuel (RDF). Gasification tests involving petioles, RDFs and their mixtures (25%, 50%, 75% or 100% by weight) were conducted in a laboratory-scale fixed bed reactor. Fuel samples of 5 g were gasified at 700°C–900°C for 60 minutes, using simulated air (79% N2 to 21% O2, by volume) as a gasifying agent. Gasification of petioles generated producer gas with lower heating values, estimated at 0.43–0.75 MJ Nm−3, while RDF produced 0.92–1.39 MJ Nm−3. Adding greater quantities of RDF to the fuel mixture resulted in an increase in the heating value of the producer gas and cold gas efficiency. The operating temperatures and gasifying-agent flow rates affected the efficiency of process differently, depending on the fuel composition. However, the maximum cold gas efficiency from both fuels was detected in tests conducted at 800°C. In co-gasification and pure refuse-derived-fuel tests, higher temperatures and gasifying-agent flow rates led to outputs with higher energy yields. Our findings suggested that co-gasification of petiole is a viable alternative waste-treatment technology for this region.

scholarly journals Thermochemical Heat Storage in a Lab-Scale Indirectly Operated CaO/Ca(OH)2 Reactor—Numerical Modeling and Model Validation through Inverse Parameter Estimation

2021 ◽  
Vol 11 (2) ◽  
pp. 682
Author(s):  
Gabriele Seitz ◽  
Farid Mohammadi ◽  
Holger Class
Keyword(s):  
Numerical Model ◽  
Gas Flow ◽  
Reaction Rate ◽  
Heat Storage ◽  
Bulk Material ◽  
Fixed Bed ◽  
Experimental Results ◽  
Fixed Bed Reactor ◽  
Thermochemical Heat Storage ◽  
Speed Up

Calcium oxide/Calcium hydroxide can be utilized as a reaction system for thermochemical heat storage. It features a high storage capacity, is cheap, and does not involve major environmental concerns. Operationally, different fixed-bed reactor concepts can be distinguished; direct reactor are characterized by gas flow through the reactive bulk material, while in indirect reactors, the heat-carrying gas flow is separated from the bulk material. This study puts a focus on the indirectly operated fixed-bed reactor setup. The fluxes of the reaction fluid and the heat-carrying flow are decoupled in order to overcome limitations due to heat conduction in the reactive bulk material. The fixed bed represents a porous medium where Darcy-type flow conditions can be assumed. Here, a numerical model for such a reactor concept is presented, which has been implemented in the software DuMux. An attempt to calibrate and validate it with experimental results from the literature is discussed in detail. This allows for the identification of a deficient insulation of the experimental setup. Accordingly, heat-loss mechanisms are included in the model. However, it can be shown that heat losses alone are not sufficient to explain the experimental results. It is evident that another effect plays a role here. Using Bayesian inference, this effect is identified as the reaction rate decreasing with progressing conversion of reactive material. The calibrated model reveals that more heat is lost over the reactor surface than transported in the heat transfer channel, which causes a considerable speed-up of the discharge reaction. An observed deceleration of the reaction rate at progressed conversion is attributed to the presence of agglomerates of the bulk material in the fixed bed. This retardation is represented phenomenologically by mofifying the reaction kinetics. After the calibration, the model is validated with a second set of experimental results. To speed up the calculations for the calibration, the numerical model is replaced by a surrogate model based on Polynomial Chaos Expansion and Principal Component Analysis.

Application of Biofilm Kinetics to Anaerobic Fixed Bed Reactors

1991 ◽  
Vol 23 (7-9) ◽  
pp. 1319-1326 ◽  
Author(s):  
I. E. Gönenç ◽  
D. Orhon ◽  
B. Beler Baykal
Keyword(s):  
Removal Rate ◽  
Fixed Bed ◽  
Experimental Studies ◽  
Pilot Scale ◽  
Cod Removal ◽  
Experimental Results ◽  
Fixed Bed Reactor ◽  
Removal Mechanism ◽  
Term Operation ◽  
Fixed Bed Reactors

Two basic phenomena, reactor hydraulics and mass transport through biofilm coupled with kinetic expressions for substrate transformations were accounted for in order to describe the soluble COD removal mechanism in anaerobic fixed bed reactors. To provide necessary verification, experimental results from the long term operation of the pilot scale anaerobic reactor treating molasses wastewater were used. Theoretical evaluations verified by these experimental studies showed that a bulk zero-order removal rate expression modified by diffusional resistance leading to bulk half-order and first-order rates together with the particular hydraulic conditions could adequately define the overall soluble COD removal mechanism in an anaerobic fixed bed reactor. The experimental results were also used to determine the kinetic constants for practical application. In view of the complexity of the phenomena involved it is found remarkable that a simple simulation model based on biofilm kinetics is a powerful tool for design and operation of anaerobic fixed bed reactors.

scholarly journals ADSORPTION OF FLUORIDE FROM INDUSTRIAL WASTEWATER IN FIXED BED COLUMN USING JAVA PLUM (SYZYGIUM CUMINI)

2016 ◽  
Vol 9 (9) ◽  
pp. 320 ◽  
Author(s):  
Tej Pratap Singh ◽  
Sanjay Ghosh ◽  
Majumder Cb
Keyword(s):  
Residence Time ◽  
Industrial Wastewater ◽  
Fluoride Concentration ◽  
Fixed Bed ◽  
Experimental Results ◽  
Fixed Bed Reactor ◽  
Thomas Model ◽  
Fixed Bed Column ◽  
Empty Bed Residence Time

ABSTRACTObjective: The quality of drinking water is important for public safety and quality of life. Thus, providing every person on earth safe drinking waterseems to be the biggest challenge in front of mankind. For this purpose, here we have investigated the fluoride removal capacity of java plum.Methods: In this study, removal of fluoride from industrial wastewater using fixed-bed reactor adsorption techniques by java plum seed (Syzygiumcumini) was investigated. Fixed-bed column experiments were carried out for different bed depths, influent fluoride concentrations, and various flowrates. The Thomas model and bed depth service time model were applied to the experimental results. Both model predictions verify the experimentaldata for all the process parameters studied, indicating that the models were suitable for java plum (S. cumini) seeds (Biosorbent) fix-bed columndesign.Results: The empty bed residence time (EBRT) model optimizes the EBRT, and the Thomas model showed that the adsorption capacity is stronglydependent on the flow rate, initial fluoride concentration, and bed depth and is greater under conditions of a lower concentration of fluoride, lowerflow rate, and higher bed depth.Conclusion: The experimental results were encouraging and indicate that java plum (S. cumini) seed is a feasible option to use as a biosorbent toremove fluoride in a fixed bed adsorption process.Keywords: Adsorption, Column experiment, Thomas model, Empty bed residence time, Java plum.

Nitrogen-Bearing Emissions From Burning Corn Straw in a Fixed-Bed Reactor: Effects of Fuel Moisture, Torrefaction, and Air Flowrate

2019 ◽  
Vol 141 (8) ◽  
Author(s):  
Emad Rokni ◽  
Yu Liu ◽  
Xiaohan Ren ◽  
Yiannis A. Levendis
Keyword(s):  
Moisture Content ◽  
Hydrogen Cyanide ◽  
Fossil Fuels ◽  
Environmental Pollutants ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Fuel Moisture ◽  
Corn Straw ◽  
Renewable Biomass ◽  
Torrefied Biomass

Combustion-generated emissions of acid gases, such as nitrogen-bearing species, constitute environmental pollutants and some are subjected to environmental regulations. Assessment of such emissions is important to decide what systems need to be put in place for their control. This applies to both conventional fossil fuels and for alternative environmentally friendlier fuels, such as renewable biomass. This research investigated the emissions of nitrogen-bearing gases, which evolve from combustion of biomass (corn straw) in a fixed bed furnace, as a function of specific air flowrate (m˙air) through the bed and of moisture content of the fuel. The effect of torrefaction of corn straw on the combustion-generated nitrogen bearing emissions was also examined. The predominant nitrogen-bearing species in the combustion effluents were hydrogen cyanide (HCN), nitrogen oxide (NO), and ammonia (NH3). Increasing m˙air through the bed, to enhance the combustion rate, increased the emissions of HCN, NO, and NH3. As the m˙air through the bed increased by a factor of 5, the amounts of HCN, NO, and NH3 gases increased by factors of 3–4. As the moisture content of the biomass was reduced by drying, the combustion-generated emissions of NO increased mildly, whereas those of both NH3 and HCN decreased. Furthermore, the combustion-generated emissions of NO and NH3 from torrefied biomass were found to be higher than those from raw biomass. In contrast, the combustion-generated emissions of HCN from torrefied biomass were found to be lower than those generated from raw biomass.

Effect of atmosphere and temperature on syngas production during gasification of Zhundong lignite and water-washed Zhundong lignite in a fixed-bed reactor

2019 ◽  
Vol 74 (2) ◽  
pp. 555-569
Author(s):  
Xiuqi Shu ◽  
Jianbo Li ◽  
Jian Hao ◽  
Zhuo Liu ◽  
Quanhai Wang ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Syngas Production

Synthesis of CeO2 Supported BaCoO3 Perovskites for Chemical-Looping Methane Reforming to Syngas and Hydrogen

2017 ◽  
Author(s):  
Haoran Ding ◽  
Yongqing Xu ◽  
Linyi Xiang ◽  
Qiyao Wang ◽  
Cheng Shen ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Sol Gel ◽  
Fixed Bed ◽  
Gas Production ◽  
Fixed Bed Reactor ◽  
Methane Reforming ◽  
Chemical Looping ◽  
X Ray ◽  
Syngas Production ◽  
Fuel Reactor

In order to reduce the hotspots in partial oxidation of methane, CeO2 supported BaCoO3 perogvskite-type oxides were synthesized using a sol-gel method and applied in chemical-looping steam methane reforming (CL-SMR). The synthesized BaCoO3-CeO2 was characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). XRD and XPS results suggested that the obtained BaCoO3 was pure crystalline perovskite, its crystalline structure and lattice oxygen could regenerate after calcining. The reactivity of perovskite-type oxides in CL-SMR was evaluated using a fixed-bed reactor. Gas production rates and H2/CO ratios showed that the optimal reaction temperature was about 860 °C and the properly reaction time in fuel reactor was about 180s when Weight Hourly Space Velocity (WHSV) was 23.57 h−1. The syngas production in fuel reactor were 265.11 ml/g, hydrogen production in reforming reactor were 82.53 ml/g. (CSPE)

Effects of Zn on Steam Gasification Characteristics of Shenhua Lignite Char

2014 ◽  
Vol 1008-1009 ◽  
pp. 252-256
Author(s):  
Wipawan Sangsanga ◽  
Jin Xiao Dou ◽  
Zhe Lei Tong ◽  
Jiang Long Yu
Keyword(s):  
Gas Chromatography ◽  
Catalytic Activity ◽  
Fixed Bed ◽  
Steam Gasification ◽  
Experimental Results ◽  
Fixed Bed Reactor ◽  
Gas Composition ◽  
Gaseous Products ◽  
Lignite Char ◽  
Catalytic Effects

The catalytic effects of Zn on the yield of the gaseous products during steam gasification of lignite char were investigated by using a fixed-bed reactor. The gas composition was measured using a gas chromatography (GC). The experimental results show that Zn has catalytic effects on steam gasification and increased the yield of H2. There was an optimum content of Zn implanted into the coal above which zinc does not show further catalytic activity.

scholarly journals A Comprehensive Literature Review of Thermochemical Conversion of Biomass for Syngas Production and Associated Challenge

2019 ◽  
Vol 38 (2) ◽  
pp. 495-512
Author(s):  
Ghulamullah Maitlo ◽  
Rasool Bux Mahar ◽  
Zulfiqar Ali Bhatti ◽  
Imran Nazir
Keyword(s):  
Fossil Fuels ◽  
Fixed Bed ◽  
Biomass Gasification ◽  
Gaseous Product ◽  
Gas Production ◽  
Thermochemical Conversion ◽  
Producer Gas ◽  
Syngas Production ◽  
Gasification Process

The interest in the thermochemical conversion of biomass for producer gas production since last decade has increased because of the growing attention to the application of sustainable energy resources. Application of biomass resources is a valid alternative to fossil fuels as it is a renewable energy source. The valuable gaseous product obtained through thermochemical conversion of organic material is syngas, whereas the solid product obtained is char. This review deals with the state of the art of biomass gasification technologies and the quality of syngas gathered through the application of different gasifiers along with the effect of different operating parameters on the quality of producer gas. Main steps in gasification process including drying, oxidation, pyrolysis and reduction effects on syngas production and quality are presented in this review. An overview of various types of gasifiers used in lignocellulosic biomass gasification processes, fixed bed and fluidized bed and entrained flow gasifiers are discussed. The effects of various process parameters such as particle size, steam and biomass ratio, equivalence ratio, effects of temperature, pressure and gasifying agents are discussed. Depending on the priorities of several researchers, the optimum value of different anticipated productivities in the gasification process comprising better quality syngas production improved lower heating value, higher syngas production, improved cold gas efficiency, carbon conversion efficiency, production of char and tar have been reviewed.

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