scholarly journals The Brooks and Corey Capillary Pressure Model Revisited from Pore Network Simulations of Capillarity-Controlled Invasion Percolation Process

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1318
Author(s):  
Xiang Lu ◽  
Abdolreza Kharaghani ◽  
Hadi Adloo ◽  
Evangelos Tsotsas

Relating the macroscopic properties of porous media such as capillary pressure with saturation is an on-going problem in many fields, but examining their correlations with microstructural traits of the porous medium is a challenging task due to the heterogeneity of the solid matrix and the limitations of laboratory instruments. Considering a capillarity-controlled invasion percolation process, we examined the macroscopic properties as functions of matrix saturation and pore structure by applying the throat and pore network model. We obtained a relationship of the capillary pressure with the effective saturation from systematic pore network simulations. Then, we revisited and identified the microstructure parameters in the Brooks and Corey capillary pressure model. The wetting phase residual saturation is related to the ratio of standard deviation to the mean radius, the ratio of pore radius to the throat length, and pore connectivity. The size distribution index in the Brooks and Corey capillary pressure model should be more reasonably considered as a meniscus size distribution index rather than a pore size distribution index, relating this parameter with the invasion process and the structural properties. The size distribution index is associated with pore connectivity and the ratio of standard deviation to mean radius (σ0/r¯), increasing with the decline of σ0/r¯ but the same for networks with same σ0/r¯. The identified parameters of the Brooks and Corey model might be further utilized for correlations with other transport properties such as permeability.

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 362 ◽  
Author(s):  
Haashir Altaf ◽  
Nicole Vorhauer ◽  
Evangelos Tsotsas ◽  
Tanja Vidaković-Koch

Recently, pore network modelling has been attracting attention in the investigation of electrolysis. This study focuses on a 2D pore network model with the purpose to study the drainage of water by oxygen in anodic porous transport layers (PTL). The oxygen gas produced at the anode catalyst layer by the oxidation of water flows counter currently to the educt through the PTL. When it invades the water-filled pores of the PTL, the liquid is drained from the porous medium. For the pore network model presented here, we assume that this process occurs in distinct steps and applies classical rules of invasion percolation with quasi-static drainage. As the invasion occurs in the capillary-dominated regime, it is dictated by the pore structure and the pore size distribution. Viscous and liquid film flows are neglected and gravity forces are disregarded. The curvature of the two-phase interface within the pores, which essentially dictates the invasion process, is computed from the Young Laplace equation. We show and discuss results from Monte Carlo pore network simulations and compare them qualitatively to microfluidic experiments from literature. The invasion patterns of different types of PTLs, i.e., felt, foam, sintered, are compared with pore network simulations. In addition to this, we study the impact of pore size distribution on the phase patterns of oxygen and water inside the pore network. Based on these results, it can be recommended that pore network modeling is a valuable tool to study the correlation between kinetic losses of water electrolysis processes and current density.


Author(s):  
Sean Reilly ◽  
Ivan Catton

Biporous wicks are an effective means for facilitating evaporation in heat pipes used for electronics cooling. They facilitate boiling within the wick by having two distinct size distributions of pores; the smaller pores provide high capillary pressure to pump liquid to the surface while the larger pores maintain high vapor permeability. The wicks investigated in this study were sintered copper biporous material. The authors previously presented a validated statistical model, based on work by Kovalev, which could predict the performance of biporous wicks tested at UCLA with reasonable accuracy [1]. Using this model, the author was able to gain new insight into the effect that the numerical estimate of liquid saturation of the wick has on dry out. The pore size distribution allows the determination of the capillary pressure available inside the wick and the Kovalev model provides the required pressure drop to supply liquid water to the heater surface. This led to a method of predicting dry out by comparing the capillary pressure in the wick to the required pressure drop from the model to estimate when the wick was dried out. When the required pressure drop determined by code exceeds the peak effective capillary pressure provided by the wick, the large pores of the wick are considered to be dry. These values are correlated to the input heat flux to determine what at what input power the wick begins to dry out. While the wick will not fail in this mode, the overall heat transfer coefficient will have peaked. In this work, this method of determining dry out will be validated against wicks tested at UCLA by comparing the input powers at which this dry out phenomenon occurs. Accurate predictions of dry out and the role of the pore size distribution are critical in developing methods to delay dry out of biporous wicks. By comparing the relative dry out points of various wick geometries to each other, augmented wick geometries can be suggested for future work. This modeling tool can lay the foundation for future tailoring of biporous evaporator wicks to specific tasks.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Xiang Huang ◽  
Wei Zhou ◽  
Daxiang Deng

AbstractPore network modeling (PNM) has been widely investigated in the study of multiphase transport in porous media due to its high computational efficiency. The advantage of PNM is achieved in part at the cost of using simplified geometrical elements. Therefore, the validation of pore network modeling needs further verification. A Shan-Chen (SC) multiphase lattice Boltzmann model (LBM) was used to simulate the multiphase flow and provided as the benchmark. PNM using different definitions of throat radius was performed and compared. The results showed that the capillary pressure and saturation curves agreed well when throat radius was calculated using the area-equivalent radius. The discrepancy of predicted phase occupations from different methods was compared in slice images and the reason can be attributed to the capillary pressure gradients demonstrated in LBM. Finally, the relative permeability was also predicted using PNM and provided acceptable predictions when compared with the results using single-phase LBM.


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