scholarly journals Arsenic Removal from Mining Effluents Using Plant-Mediated, Green-Synthesized Iron Nanoparticles

Processes ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 759 ◽  
Author(s):  
Karimi ◽  
Javanshir ◽  
Sayadi ◽  
Arabyarmohammadi
Keyword(s):  
Iron Nanoparticles ◽  
Arsenic Removal ◽  
Surface Characteristics ◽  
Isotherm Models ◽  
Aqueous Environment ◽  
Temperature Sensitive ◽  
Agitation Rate ◽  
Arsenic Adsorption ◽  
Microscopy Imaging ◽  
Teucrium Polium

Arsenic contamination in industrial and mining effluents has always been a serious concern. Recently, nano-sized iron particles have been proven effective in sorptive removal of arsenic, because of their unique surface characteristics. In this study, green synthesis of iron nanoparticles was performed using a mixed extract of two plant species, namely Prangos ferulacea and Teucrium polium, for the specific purpose of arsenic (III) removal from the aqueous environment. Results of UV-visible spectrometry, X-ray powder diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR) analyses confirmed the formation of iron nanoparticles from Prangos ferulacea (Pf) and Teucrium polium (Tp) extracts. The synthesized Fe nanoparticles morphology was studied via microscopy imaging. The particle size was 42 nm, as assessed by dynamic light scattering (DLS) analysis. Adsorption experiments were also designed and performed, which indicated 93.8% arsenic removal from the aqueous solution at 200 rpm agitation rate, 20 min agitation time, pH 6, initial concentration of 0.1 g/L, and adsorbent dosage of 2 g/L. Adsorption isotherm models were investigated, and the maximum uptake capacity was determined to be about 61.7 mg/g. The kinetic data were best represented by the pseudo-second kinetic model (R2 = 0.99). The negative value of Gibbs free energy, the enthalpy (−7.20 kJ/mol), and the entropy (−57 J/mol.K) revealed the spontaneous and exothermic nature of the adsorption process. Moreover, the small quantity of the activation energy confirmed the physical mechanism of arsenic adsorption onto iron nanoparticles and that the process is not temperature sensitive.

Effect of Quartz Sand Coated with Water-Treatment Residuals as Arsenic Adsorbent

2013 ◽  
Vol 663 ◽  
pp. 1064-1069 ◽  
Author(s):  
Chi Chuan Kan ◽  
Meng Wei Wan ◽  
Hui Ling Yang ◽  
Chih Chao Wu
Keyword(s):  
Water Treatment ◽  
Quartz Sand ◽  
Arsenic Concentration ◽  
Surface Characteristics ◽  
Isotherm Models ◽  
Water Treatment Residuals ◽  
Arsenic Adsorption ◽  
Average Pore ◽  
Before And After ◽  
Iron Manganese

In this study, quartz sand coated with water-treatment residuals was tested for its effectiveness as an arsenic adsorbent. The surface characteristics of the quartz sand before and after modification were analyzed. Different amounts of modified quartz sand were then tested for their adsorption capacity, using raw water with an arsenic concentration of 500 ppb. Analysis showed that the surface area and average pore diameter of the quartz sand had increased significantly after modification, as did the amounts of iron, manganese, and aluminum found as surface elements. Using both Freundlich and Langmuir isotherm models to measure the effectiveness of arsenic adsorption by the modified quartz sand, it was found that the latter model, for monolayer adsorption, was more appropriate.

scholarly journals Study on the modification of Phu Yen diatomite by mixed Fe-Mn oxide and the use of the modified material as an arsenic removal adsorbent in water environment

2021 ◽  
Vol 10 (1) ◽  
pp. 13-20
Author(s):  
Thien Tran Vinh ◽  
Tu Nguyen Thi Thanh ◽  
Son Bui Hai Dang
Keyword(s):  
Adsorption Capacity ◽  
Arsenic Removal ◽  
Water Environment ◽  
Surface Characteristics ◽  
Reduction Reaction ◽  
Arsenic Adsorption ◽  
Solution Ph ◽  
Mn Oxide ◽  
Oxidation Reduction ◽  
Modified Diatomite

The paper presents the modification of Phu Yen diatomite by oxidation-reduction reaction between Fe (II) and KMnO4 salts in solution pH = 6 on the diatomite surface. Characteristics of modified materials and the influence of research factors on these characteristics were investigated using techniques XRD, EDX, XPS, SEM, TEM, BET. Arsenic adsorption capacity of modified materials, the influence of environmental factors on the adsorption capacity were also investigated and evaluated. The results showed that mixed oxide-modified diatomite has higher arsenic adsorption capacity than natural diatomite and modified diatomite by individual oxides.

scholarly journals Arsenic Removal from Aqueous Solutions bySalvadora persicaStem Ash

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Ferdos Kord Mostafapour ◽  
Edris Bazrafshan ◽  
Mahdi Farzadkia ◽  
Samira Amini
Keyword(s):  
Aqueous Solutions ◽  
Contact Time ◽  
Arsenic Removal ◽  
Arsenic Concentration ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Aqueous Environment ◽  
Salvadora Persica ◽  
Naturally Occurring ◽  
Maximum Removal

Arsenic is a naturally occurring metalloid, which is widely distributed in nature and is regarded as the largest mass poisoning in history. In the present study, the adsorption potential ofSalvadora persica(S. persica) stem ash in a batch system for the removal of As(V) from aqueous solutions was investigated. Isotherm studies were carried out to evaluate the effect of contact time (20–240 min), pH (2–11), initial arsenic concentration (50–500 μg/L), and adsorbent dose on sorption efficiency. Maximum removal efficiency of 98.33% and 99.32% was obtained at pH 6, adsorbent dosage 3.5 g/L, initial As(V) concentration 500 μg/L, and contact time 80 and 60 min forS. persicastem ash at 300 °C and 500 °C, respectively. Also, the adsorption equilibriums were analyzed by the Langmuir and Freundlich isotherm models. Such equilibriums showed that the adsorption data was well fitted with the Freundlich isotherm model forS. persicastem ash at both 300 °C and 500 °C (R2=0.8983and 0.9274, resp.). According to achieved results, it was defined thatS. persicastem ash can be used effectively for As(V) removal from the aqueous environment.

scholarly journals Testing of Chemically Activated Cellulose Fibers as Adsorbents for Treatment of Arsenic Contaminated Water

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3731
Author(s):  
Mihaela Ciopec ◽  
Gabriela Biliuta ◽  
Adina Negrea ◽  
Narcis Duțeanu ◽  
Sergiu Coseri ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Vital Role ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Arsenic Adsorption ◽  
Good Efficiency ◽  
Initial Concentration ◽  
Viscose Fibers ◽  
Contaminated Food ◽  
Removal Technologies

Exposure to different arsenic concentrations (higher than 10 μg/L), either due to the direct consumption of contaminated drinking water or indirectly by using contaminated food is harmful for human health. Therefore, it is important to remove arsenic from aqueous solutions. Among many arsenic removal technologies, adsorption offers a promising solution with a good efficiency, however the material used as adsorbent play a very vital role. The present investigation evaluated the behavior of two cellulose-based adsorbent materials, i.e., viscose fibers (V) and its TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) derivative, obtained by using the well-established TEMPO-mediated protocol (VF). Due to the known arsenic affinity for Fe ions the two materials were later doped with it. This was done after a preliminary functionalization with di-2-ethylhexyl phosphoric acid (DEHPA), to obtain two materials: V-DEHPA-Fe and VF-DEHPA-Fe. Arsenic adsorption is known to be pH dependent (between 6 and 8); therefore, the optimal pH range for As(V) adsorption has been established. In order to evaluate the adsorption mechanism for both the synthesized materials, the influence of contact time, temperature and initial concentration was evaluated. Langmuir, Freundlich and Sips equilibrium isotherm models were used in order to determine the ability of the model to describe As(V) adsorption process. The maximum adsorption capacity of the material V-DEHPA-Fe was 247.5 µg As(V)/g with an As(V) initial concentration of 5 mg/L and for the material VF-DEHPA-Fe it was 171.2 µg As(V)/g with initial concentration of 5 mg/L.

scholarly journals Study on arsenic removal process from water

2014 ◽  
Vol 12 ◽  
pp. 53-55
Author(s):  
B Bayarmaa ◽  
E Selenge ◽  
Yang Min
Keyword(s):  
Magnetic Properties ◽  
Iron Oxide ◽  
Adsorption Capacity ◽  
Ferric Oxide ◽  
Arsenic Removal ◽  
Ph Dependence ◽  
Surface Characteristics ◽  
Arsenic Adsorption ◽  
Ferric Oxides ◽  
The Relationship

In this study a novel adsorbent, iron oxide, is used for As (V) or As (III) removal. Some ferric oxides have been reported to be effective for arsenic removal. Ferric oxides powder is a good adsorbent material since it’s has magnetic properties and a good adsorption capacity. The main purpose of this study has been focused on to study the relationship between adsorption capacity (ability, performance) and the surface characteristics of the ferric oxide. Prepared sample’s capacity was evaluated. The value was 26.1-67.4 mg/g for As (V) and 20.5-47.8 mg/g for As (III). pH dependence was evaluated and when pH increasing, adsorption capacity was decreased. The kinetic was evaluated and about 12 hours reached equilibrium and a capacity of 49 mg/g for As (V) and 42 mg/g for As(III) was gained. The kinetic constants for arsenic adsorption on the ferrihydrite adsorbent’s were fitted.DOI: http://dx.doi.org/10.5564/mjc.v12i0.172 Mongolian Journal of Chemistry Vol.12 2011: 53-55

As(III) Removal by Dynamic Adsorption onto Amberlite XAD7 Functionalized with Crown Ether and Doped with Fe(III) Ions

2019 ◽  
Vol 70 (7) ◽  
pp. 2330-2334
Author(s):  
Mihaela Ciopec ◽  
Adina Negrea ◽  
Narcis Duteanu ◽  
Corneliu Mircea Davidescu ◽  
Iosif Hulka ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Arsenic Removal ◽  
Arsenic Concentration ◽  
Fixed Bed ◽  
World Health ◽  
Arsenic Content ◽  
Arsenic Adsorption ◽  
Stage Of Development ◽  
Wide Range ◽  
Health Organization

Arsenic content in groundwater�s present a wide range of concentration, ranging from hundreds of micrograms to thousands of micrograms of arsenic per litter, while the maximum permitted arsenic concentration established by World Health Organization (WHO) is 10 mg L-1. According to the WHO all people, regardless of their stage of development and their social economic condition, have the right to have access to adequate drinking water. The most efficient and economic technique used for arsenic removal is represented by adsorption. In order to make this remediation technique more affordable and environmentally friendly is important to new materials with advance adsorbent properties. Novelty of present paper is represented by the usage of a new adsorbent material obtained by physical - chemical modification of Amberlite XAD polymers using crown ethers followed by iron doping, due to well-known affinity of arsenic for iron ions. Present paper aims to test the obtained modified Amberlite polymer for arsenic removal from real groundwater by using adsorption in a fixed bed column, establishing in this way a mechanism for the adsorption process. During experimental work was studied the influence of competing ions from real water into the arsenic adsorption process.

scholarly journals Evaluation of Fe-Mg Binary Oxide for As (III) Adsorption—Synthesis, Characterization and Kinetic Modelling

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 805
Author(s):  
Saif Ullah Khan ◽  
Rumman Zaidi ◽  
Feroz Shaik ◽  
Izharul Haq Farooqi ◽  
Ameer Azam ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Kinetic Modelling ◽  
Arsenic Concentration ◽  
Experimental Studies ◽  
Precipitation Method ◽  
Arsenic Adsorption ◽  
Adsorbent Dosage ◽  
X Ray ◽  
Co Precipitation ◽  
Contaminated Waters

Nanotechnology has received much attention in treating contaminated waters. In the present study, a facile co-precipitation method was employed to synthesize a novel iron and magnesium based binary metal oxide using a stoichiometrically fixed amount of FeNO3.9H2O and MgNO3.6H2O in a proportion of molar concentration 1:1 and was later evaluated in removing As (III) from contaminated waters. Characterization of the prepared nanomaterial was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX) and ultraviolet–visible spectrophotometry (UV-VIS). Experimental studies on batch scale were carried out, examining the effect of varying initial concentrations of metal, adsorbent dosage, application time and initial pH on removal efficiency. Arsenic removal increased on increasing adsorbent dosage (0.1–1 g/L) but trend reversed on increasing initial arsenic concentration attaining qmax of 263.20 mg/g. Adsorption was quite efficient in pH range 4–8. Freundlich fitted better for adsorption isotherm along with following Pseudo-2nd order kinetics. The reusability and effect of co-existing ions on arsenic adsorption, namely SO42−, CO32− and PO43− were also explored with reusability in 1st and 2nd cycles attained adsorptive removal up to 77% and 64% respectively. The prepared nano-adsorbent showed promising results in terms of high arsenic uptake (qmax of 263.20 mg/g) along with facile and cost-effective synthesis. Thus, the co-precipitation technique used in this work is a simple one step procedure without any use of any precursor as compared to most of the other procedures used for synthesis.

scholarly journals Cadmium Removal by using Pumice Modified with Iron Nanoparticles from Aqueous Solutions

2016 ◽  
Vol 18 (2) ◽  
pp. 426-436 ◽  
Keyword(s):  
Contact Time ◽  
Iron Nanoparticles ◽  
Cadmium Concentration ◽  
Synthetic Wastewater ◽  
Isotherm Models ◽  
Cadmium Removal ◽  
Pumice Stone ◽  
Practical Applications ◽  
Equilibrium Data ◽  
Adsorbent Dose

<p>In this study, the removal of cadmium by using pumice coated with iron nanoparticles (INPs) from synthetic wastewater was investigated. The effects of parameters influencing adsorption: contact time (10-20 min), pH (3-9), initial cadmium concentration (25-125 mg l<sup>-1</sup>) and adsorbent dose (2-10 g l<sup>-1</sup>) were studied. The pumice stone used in this research was, first, crashed and then sieved with 20 mesh standard sieves (0.85 mm); finally, it was coated with INPs. An atomic absorption spectrophotometer was used to measure cadmium contents and isotherm models and adsorption kinetics were studied. The results showed the adsorption process of cadmium reached equilibrium at contact time of 80 min. With increasing pH solution, the efficiency enhanced which peaked at pH 7-8. Cadmium concentration increase resulted in a decrease in efficiency, whereas adsorbent dose increase improved it. Equilibrium data of adsorption followed isotherms models: Langmuir and Freundlich. The highest removal efficiency and adsorption capacity were, respectively, 83% and 17.27 mg g<sup>-1</sup>. Furthermore, absorption kinetics is better described by the pseudo second-order model. According to the results obtained, pumice coated with INPs is an effective adsorbent and can be introduced as a suitable option in practical applications</p>

scholarly journals Arsenic Removal from Water by Green Synthesized Magnetic Nanoparticles

Water ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2520
Author(s):  
Jasmina Nikić ◽  
Aleksandra Tubić ◽  
Malcolm Watson ◽  
Snežana Maletić ◽  
Marko Šolić ◽  
...  
Keyword(s):  
Magnetite Nanoparticles ◽  
Arsenic Removal ◽  
Low Cost ◽  
High Capacity ◽  
Bet Surface Area ◽  
Arsenic Adsorption ◽  
Promising Alternative ◽  
Antioxidant Power ◽  
Corn Silk ◽  
Onion Peel

Magnetite nanoparticles were synthesized by a simple and ecofriendly method using onion peel (MNp-OP) and corn silk extract (MNp-CS), in order to develop new low-cost adsorbents for arsenic removal from groundwater. As a point of comparison, magnetite nanoparticles were also synthesized with a conventional chemical process (MNp-CO). The antioxidant potential of onion peel and corn silk extracts was determined using ferric reducing antioxidant power (FRAP) and free radical (DPPH) scavenging assays, including the total phenolics, flavonoids and tannins contents. The synthesized magnetite nanoparticles were characterised using different techniques (Scanning electron microscope/Energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) surface area analyzer). The adsorption capacity of MNp-OP and MNp-CS and the arsenic removal mechanism of these novel adsorbents was investigated through kinetic and equilibrium experiments and their corresponding mathematical models. Characterisation of MNp-OP and MNp-CS shows high BET specific surface areas of 243 m2/g and 261 m2/g, respectively. XRD and FTIR analysis confirmed the formation and presence of magnetite nanoparticles. The arsenic adsorption mechanism on MNp-OP, MNp-CS and MNp-CO involves chemisorption, intraparticle and external diffusion. Maximal adsorption capacities of MNp-OP, MNp-CS and MNp-CO were 1.86, 2.79, and 1.30 mg/g respectively. The green synthesis applied using onion peel and corn silk extracts was cost effective and environmentally friendly, and results in adsorbents with a high capacity for arsenic and magnetic properties, making them a very promising alternative approach in the treatment of arsenic contaminated groundwater.

scholarly journals Alginate-based biotechnology: a review on the arsenic removal technologies and future possibilities

2019 ◽  
Vol 68 (6) ◽  
pp. 369-389 ◽  
Author(s):  
Shakhawat Chowdhury ◽  
Imran Rahman Chowdhury ◽  
Fayzul Kabir ◽  
Mohammad Abu Jafar Mazumder ◽  
Md. Hasan Zahir ◽  
...  
Keyword(s):  
Drinking Water ◽  
Arsenic Removal ◽  
Alginate Bead ◽  
Alginate Beads ◽  
Industrial Applications ◽  
Mass Scale ◽  
Future Research ◽  
Large Area ◽  
Arsenic Adsorption ◽  
Wide Range

Abstract The alginate-based adsorption technologies have emerged as potential methods for arsenic removal from drinking water. The adsorbents (iron oxide, hydroxide, nano zero valent iron (nZVI), industrial waste, minerals, magnetite, goethite, zirconium oxide, etc.) are impregnated into alginate beads to produce the media. The biocompatibility, rough surface with large area, and amorphous and high water permeable bead structure improve arsenic adsorption efficiency while the regeneration process is simpler than the conventional adsorbents. In recent years, studies have reported laboratory-scale applications of alginate beads, encapsulated and impregnated with adsorbents, for arsenic removal from drinking water. The arsenic removal efficiencies were reported to be over 95% with a wide range of concentrations (10–1,000 parts per billion) and pH (3.0–7.5). However, commercial- and/or mass-scale applications have not been reported yet, due possibly to overall cost, complexity, reusability, and arsenic waste-laden sludge management. In this paper, research achievement on arsenic removal using alginate-based adsorbents has been reviewed. The review was performed in context to alginate bead development, adsorbent encapsulation and impregnation, application, performance, and regeneration. The advantages and limitations of the methods were analyzed and the scopes of future research were identified for mass scale domestic and industrial applications.

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