scholarly journals Engineering Porous Poly(lactic acid) Scaffolds with High Mechanical Performance via a Solid State Extrusion/Porogen Leaching Approach

Polymers ◽  
2016 ◽  
Vol 8 (6) ◽  
pp. 213 ◽  
Author(s):  
Hua-Mo Yin ◽  
Jing Qian ◽  
Jin Zhang ◽  
Zai-Fu Lin ◽  
Jian-Shu Li ◽  
...  
2019 ◽  
Vol 821 ◽  
pp. 89-95
Author(s):  
Wanasorn Somphol ◽  
Thipjak Na Lampang ◽  
Paweena Prapainainar ◽  
Pongdhorn Sae-Oui ◽  
Surapich Loykulnant ◽  
...  

Poly (lactic acid) or PLA was reinforced by nanocellulose and polyethylene glycol (PEG), which were introduced into PLA matrix from 0 to 3 wt.% to enhance compatibility and strength of the PLA. The nanocellulose was prepared by TEMPO-mediated oxidation from microcrystalline cellulose (MCC) powder and characterized by TEM, AFM, and XRD to reveal rod-like shaped nanocellulose with nanosized dimensions, high aspect ratio and high crystallinity. Films of nanocellulose/PEG/PLA nanocomposites were prepared by solvent casting method to evaluate the mechanical performance. It was found that the addition of PEG in nanocellulose-containing PLA films resulted in an increase in tensile modulus with only 1 wt% of PEG, where higher PEG concentrations negatively impacted the tensile strength. Furthermore, the tensile strength and modulus of nanocellulose/PEG/PLA nanocomposites were higher than the PLA/PEG composites due to the existence of nanocellulose chains. Visual traces of crazing were detailed to describe the deformation mechanism.


2018 ◽  
Vol 29 (12) ◽  
pp. 3065-3074 ◽  
Author(s):  
Shuhao Sun ◽  
Qian Li ◽  
Na Zhao ◽  
Jing Jiang ◽  
Kangkang Zhang ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4910 ◽  
Author(s):  
Alejandro Aragón-Gutierrez ◽  
Marina P. Arrieta ◽  
Mar López-González ◽  
Marta Fernández-García ◽  
Daniel López

Bionanocomposites based on poly (lactic acid) (PLA) and silica aerogel (SiA) were developed by means of melt extrusion process. PLA-SiA composite films were plasticized with 15 wt.% of acetyl (tributyl citrate) (ATBC) to facilitate the PLA processability as well as to attain flexible polymeric formulations for films for food packaging purposes. Meanwhile, SiA was added in four different proportions (0.5, 1, 3 and 5 wt.%) to evaluate the ability of SiA to improve the thermal, mechanical, and barrier performance of the bionanocomposites. The mechanical performance, thermal stability as well as the barrier properties against different gases (carbon dioxide, nitrogen, and oxygen) of the bionanocomposites were evaluated. It was observed that the addition of 3 wt.% of SiA to the plasticized PLA-ATBC matrix showed simultaneously an improvement on the thermal stability as well as the mechanical and barrier performance of films. Finally, PLA-SiA film formulations were disintegrated in compost at the lab-scale level. The combination of ATBC and SiA sped up the disintegration of PLA matrix. Thus, the bionanocomposites produced here show great potential as sustainable polymeric formulations with interest in the food packaging sector.


2014 ◽  
Vol 53 (9S) ◽  
pp. 09PC02 ◽  
Author(s):  
Mitsunobu Yoshida ◽  
Takayuki Onogi ◽  
Katsuki Onishi ◽  
Takuma Inagaki ◽  
Yoshiro Tajitsu

2013 ◽  
Vol 55 ◽  
pp. 234-239 ◽  
Author(s):  
Xinghou Gong ◽  
Chak Yin Tang ◽  
Ling Pan ◽  
Zhonghua Hao ◽  
Chi Pong Tsui ◽  
...  

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