scholarly journals Stimuli-Responsive Polyelectrolyte Brushes As a Matrix for the Attachment of Gold Nanoparticles: The Effect of Brush Thickness on Particle Distribution

Polymers ◽  
2014 ◽  
Vol 6 (7) ◽  
pp. 1877-1896 ◽  
Author(s):  
Stephanie Christau ◽  
Stefan Thurandt ◽  
Zuleyha Yenice ◽  
Regine von Klitzing
Keyword(s):  
Gold Nanoparticles ◽  
Particle Distribution ◽  
Stimuli Responsive ◽  
Polyelectrolyte Brushes

Thermoswitchable Janus Gold Nanoparticles with Stimuli-Responsive Hydrophilic Polymer Brushes

Langmuir ◽  
2016 ◽  
Vol 32 (17) ◽  
pp. 4297-4304 ◽  
Author(s):  
Xiaoqin Niu ◽  
Fen Ran ◽  
Limei Chen ◽  
Gabriella Jia-En Lu ◽  
Peiguang Hu ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Polymer Brushes ◽  
Hydrophilic Polymer ◽  
Stimuli Responsive

From multi-responsive tri- and diblock copolymers to diblock-copolymer-decorated gold nanoparticles: the effect of architecture on micellization behaviors in aqueous solutions

Soft Matter ◽  
2015 ◽  
Vol 11 (24) ◽  
pp. 4830-4839 ◽  
Author(s):  
Lichun Song ◽  
Hui Sun ◽  
Xiaolu Chen ◽  
Xia Han ◽  
Honglai Liu
Keyword(s):  
Gold Nanoparticles ◽  
Aqueous Solutions ◽  
Diblock Copolymer ◽  
Triblock Copolymer ◽  
Diblock Copolymers ◽  
Stimuli Responsive ◽  
Aba Triblock Copolymer

This work reports on the aqueous stimuli-responsive behaviors of an ABA triblock copolymer, a BAB triblock copolymer, an AB diblock copolymer and citrate-based gold nanoparticles decorated with AB diblock copolymers.

Mechanism of the Formation of Amorphous Gold Nanoparticles within Spherical Polyelectrolyte Brushes

2007 ◽  
Vol 208 (14) ◽  
pp. 1542-1547 ◽  
Author(s):  
Marc Schrinner ◽  
Frank Polzer ◽  
Yu Mei ◽  
Yan Lu ◽  
Björn Haupt ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Polyelectrolyte Brushes ◽  
Spherical Polyelectrolyte Brushes

scholarly journals Giant hollow fiber formation through self-assembly of oppositely charged polyelectrolyte brushes and gold nanoparticles

Soft Matter ◽  
2013 ◽  
Vol 9 (38) ◽  
pp. 9111 ◽  
Author(s):  
Jérôme J. Crassous ◽  
Pierre-Eric Millard ◽  
Adriana M. Mihut ◽  
Alexander Wittemann ◽  
Markus Drechsler ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Hollow Fiber ◽  
Self Assembly ◽  
Fiber Formation ◽  
Polyelectrolyte Brushes ◽  
Oppositely Charged

scholarly journals Radiolytic synthesis of gold nanoparticles in HEMA-based hydrogels: Potentialities for imaging nanocomposites

Nukleonika ◽  
2021 ◽  
Vol 66 (4) ◽  
pp. 165-177
Author(s):  
Katsiaryna Dziarabina ◽  
Uliana Pinaeva ◽  
Sławomir Kadłubowski ◽  
Piotr Ulański ◽  
Xavier Coqueret
Keyword(s):  
Gold Nanoparticles ◽  
Monomer Conversion ◽  
Thermomechanical Properties ◽  
Temperature Sensitive ◽  
Trimethylammonium Chloride ◽  
Stimuli Responsive ◽  
Monomer Composition ◽  
Swelling Characteristics ◽  
High Degree ◽  
Radiolytic Synthesis

Abstract This article reports on the radiolytic synthesis of nanocomposites containing gold nanoparticles (AuNPs) within two types of hydrogels based on 2-hydroxyethyl methacrylate (HEMA): (i) plain networks with various contents in ethylene glycol dimethacrylate (EGDMA), as a cross-linker and (ii) stimuli-responsive (SR) networks prepared from these monomers copolymerized with [2-(methacryloyloxy)ethyl]trimethylammonium chloride (MADQUAT) to confer pH-switchable swelling. Hydrogels were prepared by photopolymerization with well-defined composition and a high degree of monomer conversion using two experimental procedures, as xerogels or in aqueous solution. Besides MADQUAT, acrylic acid (AA) or N-isopropylacrylamide have been tested as copolymers, yielding pHor temperature-sensitive hydrogels, respectively. Isothermal swelling in water was affected by monomer composition. Electron beam (EB) irradiation at doses up to 100 kGy of poly(HEMA) xerogels and water-swollen networks prepared with 0.5 wt% of EGDMA had a moderate impact on swelling characteristics and thermomechanical properties of the plain materials, whereas small amounts of extractables were formed. Poly(HEMA)-based nanocomposites containing AuNPs were successfully obtained by EB irradiation of samples swollen by aqueous solutions of Au(III). The effects of dose and cross-linking density on the formation of AuNPs were monitored by UV-visible spectroscopy. Irradiation at well-defined temperatures of the Au(III)-loaded SR hydrogels induced the formation of nanoparticles with size-dependent features, whereas the efficiency of Au(III) reduction at 10 kGy was not significantly affected by the network structure. EB-induced reduction of Au(III) in poly(HEMA) hydrogels using a lead mask to generate well-defined patterns yielded coloured and long-lasting images in the zones where the nanocomposite was formed.

Stimuli-responsive nano- and microstructures based on gold nanoparticles

2016 ◽  
Author(s):  
K. G. Shevchenko ◽  
V. R. Cherkasov ◽  
I. L. Sokolov ◽  
M. P. Nikitin
Keyword(s):  
Gold Nanoparticles ◽  
Stimuli Responsive

Synthesis of gold nanoparticles inside polyelectrolyte brushes

2007 ◽  
Vol 17 (32) ◽  
pp. 3433 ◽  
Author(s):  
Omar Azzaroni ◽  
Andrew A. Brown ◽  
Nan Cheng ◽  
Alexander Wei ◽  
Alain M. Jonas ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Polyelectrolyte Brushes
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