scholarly journals Thermo-Responsive and Biocompatible Diblock Copolymers Prepared via Reversible Addition-Fragmentation Chain Transfer (RAFT) Radical Polymerization

Polymers ◽  
2014 ◽  
Vol 6 (3) ◽  
pp. 846-859 ◽  
Author(s):  
Kenichi Fukuda ◽  
Ryusuke Enomoto ◽  
Kazuhiko Ishihara ◽  
Yotaro Morishima ◽  
Shin-ichi Yusa
2005 ◽  
Vol 37 (7) ◽  
pp. 480-488 ◽  
Author(s):  
Shin-ichi Yusa ◽  
Yoshitane Konishi ◽  
Yoshiro Mitsukami ◽  
Tohei Yamamoto ◽  
Yotaro Morishima

1998 ◽  
Vol 31 (16) ◽  
pp. 5559-5562 ◽  
Author(s):  
John Chiefari ◽  
Y. K. (Bill) Chong ◽  
Frances Ercole ◽  
Julia Krstina ◽  
Justine Jeffery ◽  
...  

1999 ◽  
Vol 32 (21) ◽  
pp. 6977-6980 ◽  
Author(s):  
Roshan T. A. Mayadunne ◽  
Ezio Rizzardo ◽  
John Chiefari ◽  
Yen Kwong Chong ◽  
Graeme Moad ◽  
...  

2004 ◽  
Vol 58 (11) ◽  
pp. 514-520
Author(s):  
Milena Avramovic ◽  
Lynne Katsikas ◽  
Branko Dunjic ◽  
Ivanka Popovic

The fundamentals of controlled radical polymerization are presented in this review. The paper focuses on reversible addition fragmentation chain transfer (RAFT) polymerization. The mechanism and specifics of this type of polymerization are discussed, as are the possibilities of synthesizing complex macro-molecular structures. The synthesis and properties of RAFT agents, of the general structure Z-C(=S)-S-R, are presented.


Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1543-1551 ◽  
Author(s):  
Mao Chen ◽  
Honghong Gong ◽  
Yu Gu

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties.1 Introduction2 Atom Transfer Radical Polymerization3 Reversible Addition-Fragmentation Chain Transfer Polymerization4 Nitroxide-Mediated Radical Polymerization5 Photo-CRP Mediated with Metal Complexes6 Metal-free Photo-CRP7 Conclusion


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