scholarly journals Preparation and Characterization of Intrinsic Low-κ Polyimide Films

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4174
Author(s):  
Yu Sun ◽  
Tao Li ◽  
Haiyang Dai ◽  
Manman Wang ◽  
Renzhong Xue ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dielectric Properties ◽  
Free Volume ◽  
Energy Gap ◽  
Volume Fraction ◽  
Tensile Modulus ◽  
Chain Structure ◽  
Dielectric Constants ◽  
Fluorinated Polyimide ◽  
Dielectric And Mechanical Properties

Three fluorinated polyimide (PI-FP, PI-FO and PI-FH) films with low dielectric constants and excellent comprehensive properties were successfully prepared using a polycondensation reaction method by incorporating p-phenylenediamine (PDA), 4-4′-diaminodiphenyl ether (ODA) and 4,4′-(Hexafluoroisopropylidene) bis (p-phenyleneoxy) dianiline (HFPBDA) into 4,4′-(Hexafluoroisopropylidene) diphthalic anhydride (6FDA), respectively. The effects of the diamine monomer structure on optical, dielectric and mechanical properties were investigated. Compared with PDA and ODA, HFPBDA can effectively improve the optical and dielectric properties of PI due to due to its special chain structure. Among the three PI films, PI-FH film presents the best optic transmission (highest transmittance = 90.2%) and highest energy gap (2.69 eV). The dielectric properties of PI-FH film improve the most. The dielectric constant and loss at 104 Hz are reduced to 2.05 and 0.0034 at 104 Hz, respectively, and remain stable up to 250 °C. The mechanical properties decrease in turn for PI-FP, PI-FO and PI-FH films due to the increase in free volume fraction. Nevertheless, PI-FH film still exhibits good mechanical properties with a tensile strength of 88.4 Mpa, a tensile modulus of 2.11 GPa and an elongation at break of 4.1%. The correlation between the dielectric and mechanical properties of PI films and their free volume characteristics is well explained with the help of positron annihilation spectroscopy.

Microstructure, Mechanical and Dielectric Properties of Si3N4-BN Composites with Different Porosities

2015 ◽  
Vol 816 ◽  
pp. 40-47
Author(s):  
Kun Liu ◽  
Chang Rui Zhang ◽  
Bin Li ◽  
Si Qing Wang ◽  
Feng Cao
Keyword(s):  
Mechanical Properties ◽  
Elastic Modulus ◽  
Dielectric Properties ◽  
Flexural Strength ◽  
Dielectric Constants ◽  
Liquid Precursor ◽  
Die Pressing ◽  
Dielectric And Mechanical Properties

Si3N4-BN composites were prepared by die-pressing and precursor infiltration and pyrolysis (PIP) route using borazine as the precursor. The composition, microstructure, mechanical, and dielectric properties of the composites with different porosities were investigated. With the adoption of starch as pore forming substance, drawn the Si3N4preform from the liquid precursor borazine and decrease the pressure during curing, the porosity of the Si3N4-BN composites were effectively increased. Along with the increase of the porosity of the composites, the mechanical properties were decreased and the dielectric properties were improved. With 20 wt.% starch and drawn Si3N4preform from borazine before curing, the density, porosity, flexural strength and elastic modulus of the composites were 1.70 g·cm-3, 29.78%, 48.05MPa and 32.45GPa, respectively. The dielectric constants and loss tangents were 4.20~4.44 and 0.48~3.42×10-3at the frequency 7~ 18GHz. Composites with various dielectric and mechanical properties can be designed and prepared according to the application needs.

scholarly journals Characterization of Mechanical and Dielectric Properties of Silicone Rubber

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1831
Author(s):  
Eunyoung Cho ◽  
Loraine L. Y. Chiu ◽  
Mitchell Lee ◽  
Doshina Naila ◽  
Siddharth Sadanand ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dielectric Properties ◽  
Silicone Rubber ◽  
Material Properties ◽  
Dielectric Constants ◽  
Shear Moduli ◽  
Unique Material ◽  
Silicone Rubbers ◽  
Dielectric And Mechanical Properties

Silicone rubber’s silicone-oxygen backbones give unique material properties which are applicable in various biomedical devices. Due to the diversity of potential silicone rubber compositions, the material properties can vary widely. This paper characterizes the dielectric and mechanical properties of two different silicone rubbers, each with a different cure system, and in combination with silicone additives. A tactile mutator (Slacker™) and/or silicone thickener (Thi-vex™) were mixed with platinum-cured and condensation-cured silicone rubber in various concentrations. The dielectric constants, conductivities, and compressive and shear moduli were measured for each sample. Our study contributes novel information about the dielectric and mechanical properties of these two types of silicone rubber and how they change with the addition of two common silicone additives.

Mechanical and microstructural properties of polystyrene based composites: positron lifetime spectroscopic and DSC studies

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Abdullah Mohammed Ali Mohammed Altaweel ◽  
Jaya Madhu Raj ◽  
Malalvalli Nagarajaiah Chandrashekara ◽  
Puttegowda Ramya ◽  
Parthasarathy Sampathkumaran ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Free Volume ◽  
Positron Lifetime ◽  
Tensile Modulus ◽  
Silica Content ◽  
Scanning Calorimetry ◽  
Dsc Studies ◽  
Microstructural Property ◽  
Calcium Aluminosilicate

Abstract Polystyrene (PS) based composites respectively with cenosphere (CS) and calcium aluminosilicate (CAS) as fillers were studied using the positron lifetime technique to reveal the correlation between free volume, a microstructural property, and mechanical properties of the composites (tensile strength and tensile modulus). The thermal stability of the composites was determined using differential scanning calorimetry. The results showed that addition of CAS filler lead to a significant improvement in the mechanical properties of the composite, whereas addition of CS resulted in improvement in tensile modulus only. Both PS/CAS and PS/CS composites showed enhancement in thermal stability compared with that of the pure PS matrix. The positron results showed that the average free volume size for the PS/CAS composite (at 40 phr CAS) was reduced significantly compared with that of the pure PS. These results are understood in terms of the influence of silica content, filler-matrix interaction, and particle size.

scholarly journals Mechanical Properties of Oil Palm Shell Composites

2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
J. Sahari ◽  
M. A. Maleque
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Oil Palm ◽  
Volume Fraction ◽  
Unsaturated Polyester ◽  
Tensile Modulus ◽  
Sem Analysis ◽  
Palm Shell ◽  
Pull Out ◽  
Oil Palm Shell

The mechanical properties of oil palm shell (OPS) composites were investigated with different volume fraction of OPS such as 0%, 10%, 20%, and 30% using unsaturated polyester (UPE) as a matrix. The results presented that the tensile strength and tensile modulus of the UPE/OPS composites increased as the OPS loading increased. The highest tensile modulus of UPE/OPS was obtained at 30 vol% of OPS with the value of 8.50 GPa. The tensile strength of the composites was 1.15, 1.17, and 1.18 times higher than the pure UPE matrix for 10, 20, and 30 vol% of OPS, respectively. The FTIR spectra showed the change of functional group of composites with different volume fractions of OPS. SEM analysis shows the filler pull-out present in the composites which proved the poor filler-matrix interfacial bonding.

Preparation, Morphology and Dielectric Properties of Polyamide-6/Poly(Vinylidene Fluoride) Blends

2012 ◽  
Vol 496 ◽  
pp. 263-267
Author(s):  
Rui Li ◽  
Jian Zhong Pei ◽  
Yan Wei Li ◽  
Xin Shi ◽  
Qun Le Du
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Flexible Electronics ◽  
High Dielectric Constant ◽  
Vinylidene Fluoride ◽  
Volume Fraction ◽  
Polyamide 6 ◽  
Dielectric Constants ◽  
Poly Vinylidene Fluoride ◽  
High Dielectric

A novel all-polymeric material with high dielectric constant (k) has been developed by blending poly (vinylidene fluoride) (PVDF) with polyamide-6 (PA6). The dependence of the dielectric properties on frequency and polymer volume fraction was investigated. When the volume fraction of PA6 is 20%, the dielectric property is better than others. The SEM investigations suggest that the enhanced dielectric behavior originates from significant interfacial interactions of polymer-polymer. The XRD demonstrate that the PA6 and PVDF affect the crystalline behavior of each component. Furthermore, the stable dielectric constants of the blends could be tuned by adjusting the content of the polymers. The created high-k all-polymeric blends represent a novel type of material that are simple technology and easy to process, and is of relatively high dielectric constant, applications as flexible electronics.

Preparation and Dielectric Property of Ag/PVDF Composite Film

2014 ◽  
Vol 989-994 ◽  
pp. 242-245 ◽  
Author(s):  
Ya Jun Wang ◽  
Jian Wen Zhai ◽  
Fang Fang Wang ◽  
Chang Gen Feng
Keyword(s):  
Dielectric Properties ◽  
Dielectric Property ◽  
Composite Film ◽  
Volume Fraction ◽  
Composite Films ◽  
Dielectric Constants ◽  
Pvdf Film ◽  
Conductive Particle ◽  
Sem Images ◽  
Nanosilver Particles

Conductive particle fillers could improve the dielectric properties of the polymer matrix. By solvent casting method, different volume fraction of nanosilver particles were added into the PVDF film to prepare Ag/PVDF composite film so as to increase the dielectric properties of the materials. SEM was used to analyze the microstructure of the films. SEM images show that nanoAg filler particles were uniformly distributed throughout the whole matrix of the composite films. Dielectric property tests show that with the increase of nanoAg content, the dielectric constants of the composites increase first and decrease later while the dielectric losses decrease first and increase later. In the case of the optimal 17vol% Ag content, the dielectric constant of the composite film is the highest (14.5 at 100 Hz) with lower dielectric loss, and the energy storage density is relatively high (0.340 J·cm−3).

Microwave properties of saturated reservoirs

Geophysics ◽  
1983 ◽  
Vol 48 (3) ◽  
pp. 367-375 ◽  
Author(s):  
James N. Lange
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Surface Area ◽  
Oil And Gas ◽  
Volume Fraction ◽  
Empirical Relationship ◽  
Dielectric Constants ◽  
Solid Matrix ◽  
Detailed Model

Dielectric properties of saturated, porous geologic materials reflect the large difference in dielectric constant ε of typical saturating fluids such as water (ε = 78) or oil and gas (ε = 1–3). The deconvolution of in‐situ dielectric properties of saturated porous materials into the component parts requires a detailed model of the composite material. Defining aspects of this model in the microwave frequency regime is the primary purpose of this investigation. A model is examined in which the dielectric constant of the composite is equal to the sum of the dielectric constants of the components weighted by the volume fraction occupied by each. That model is compared to measurements at microwave frequencies made on systems consisting of glass beads, quartz, or sand saturated with chlorobenzene, 1,2‐dichloroethane, methanol, or air, and find satisfactory agreement. When water is the saturant an interaction between water and the solid matrix has an important effect on the composite dielectric constant. This interaction is observed to be particularly large for quartz and water and suppresses the composite dielectric constant quite considerably. This interaction is dependent upon the relative surface area per unit volume. An empirical relationship between the surface area and composite dielectric constant is obtained for clean, saturated, unconsolidated reservoirs. The inverse process of determining surface area from in‐situ measurements of the composite dielectric constant may be possible for clean reservoirs of known lithology. In sandstones from cores the dielectric constant is also below the volume fraction model and corrections are needed to evaluate water content.

Preparation and Dielectric Properties of Cu/PVDF Composite Films

2014 ◽  
Vol 1035 ◽  
pp. 417-421 ◽  
Author(s):  
Jian Wen Zhai ◽  
Ya Jun Wang ◽  
Jian Lou Deng ◽  
Chang Gen Feng
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Room Temperature ◽  
Volume Fraction ◽  
Composite Films ◽  
Interfacial Polarization ◽  
Dielectric Constants ◽  
Pvdf Film ◽  
Continuous Increase ◽  
Better Than

nanoand micro size Cu were employed separately and investigated comparatively. Different volume fraction of Cu was added into PVDF film in order to investigate the content of filler effect on the dielectric properties of polymer composites. XRD and SEM were used to analyze the crystalline phase and microstructure of the films. The results show that two sizes of Cu have the same peak features, and with the continuous increase of the content of Cu, it disperse better in PVDF. The dielectric constant (ε) of the composite containing 16 vol% micro-CCTO filler is 16 at 100 Hz and room temperature, and its dielectric loss (tanδ) is only 0.15, which is substantially better than others. Besides, for 18 vol% nanoCu/PVDF composite tanδis 0.25 andεis 18 at 100 Hz. Moreover,εand tanδof nanoCu/PVDF composite are both higher than those of micro-Cu/PVDF. Analysis shows that the composites with nanoCu have higher dielectric constants, which is mainly from the interfacial polarization.

The Effect of Additives on the Microstructure and Properties of BaTiO3 Ceramics

2013 ◽  
Vol 787 ◽  
pp. 152-156
Author(s):  
A. Lara ◽  
P. Yuan ◽  
F. Ghezzo ◽  
X. Miao ◽  
Z. Zhao
Keyword(s):  
Mechanical Properties ◽  
Dielectric Properties ◽  
Relative Density ◽  
Slip Casting ◽  
Holding Time ◽  
Theoretical Density ◽  
Microstructure And Properties ◽  
Conventional Furnace ◽  
Effect Of Additives ◽  
Dielectric And Mechanical Properties

Doped BaTiO3 powders were sintered by slip casting. Sintering was performed at the temperature of 1300oC, for 180 min holding time, in a conventional furnace. Additives were varied to study their effect on the densification and both dielectric and mechanical properties. The relative density of the obtained material was high, up to 96.5 0.6 % the theoretical density for the BaTiO3-Al2O3 composition. For these samples, their mechanical and dielectric properties have been studied.

Effective Medium Calculations of the Electromagnetic Behavior of Single Walled Carbon Nanotube Composites

2002 ◽  
Vol 739 ◽  
Author(s):  
John W. Schultz ◽  
Rick L. Moore
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Dielectric Properties ◽  
Volume Fraction ◽  
Metal Layer ◽  
Effective Permittivity ◽  
Effective Medium ◽  
Dielectric Constants ◽  
Single Walled Carbon Nanotube ◽  
Single Walled Carbon

ABSTRACTDielectric properties of single walled carbon nanotube assemblies were calculated with an effective medium approximation at frequencies from 200 MHz to 200 GHz. The model treats the carbon nanotubes as layered cylinders, each with a core, a graphene layer and an outer layer, to investigate the dielectric properties of coated and filled nanotubes. The graphene and metal layer properties were modeled with a Drude approximation based on literature data. A generalized Bruggeman model was then used to determine the macroscopic behavior of the modified carbon nanotubes in a composite structure as a function of volume fraction, frequency, and aspect ratio. The depolarization factors in this model were scaled by the normalized effective permittivity to better account for percolation behavior. The model showed a wide variety of frequency dependent dielectric properties. Uncoated tubes were calculated to form highly conductive materials at volume fractions of just a few percent and metal-coated tubes enhanced the conductivity by an order of magnitude. Calculations of nanotubes with insulating coatings showed that high dielectric constants with moderate to low dielectric loss were possible.

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