scholarly journals Dye Adsorption Mechanism of Glass Fiber-Reinforced Plastic/Clay Ceramics and Influencing Factors

Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3172
Author(s):  
Hiroyuki Kinoshita ◽  
Koya Sasaki ◽  
Kentaro Yasui ◽  
Yuko Miyakawa ◽  
Toshifumi Yuji ◽  
...  

The effective reuse of waste glass fiber-reinforced plastic (GFRP) is desired. We previously produced porous ceramics by firing mixtures of crushed GFRP and clay in a reducing atmosphere and demonstrated their applicability as adsorbents for the removal of basic dyes from dyeing wastewater. However, the primary influencing factors and the dye adsorption mechanism have not been fully elucidated, and the adsorption of acidic and direct dyes has not been clarified. In this study, adsorption tests were conducted, and the effects of the firing atmosphere, specific surface area, type of dye, and individual components were comprehensively investigated. The results showed that reductively fired ceramics containing plastic carbide residue adsorbed basic dye very well but did not adsorb acidic dye well. The clay structure was the primary factor for the dye adsorption rather than the GFRP carbide. The mechanism for the basic dye adsorption appears to have been an increase in specific surface area due to the plastic carbide residue in the ceramic structure, which increased the ion exchange between the clay minerals and the dye. By adjusting the pH of the aqueous solution, the GFRP/clay ceramic also adsorbed considerable amounts of direct dye, so the mechanism was determined to be ion exchange with the calcium component of the glass fibers.

2019 ◽  
Vol 9 (8) ◽  
pp. 1574
Author(s):  
Kentaro Yasui ◽  
Koya Sasaki ◽  
Naoya Ikeda ◽  
Hiroyuki Kinoshita

We investigated the use of waste glass fiber-reinforced plastic (GFRP) to remove dye from industrial wastewater. The dye adsorbent material, based on GFRP/clay ceramics, was produced by mixing crushed GFRP with clay and firing the resulting mixture. Several types of ceramics were produced by adjusting the mixing ratio of clay, crushed 40% GF/GFRP, and firing atmosphere. Adsorption tests with methylene blue (MB) dye were performed by mixing the ceramics into an MB solution while controlling the stirring speed and measuring the decrease in MB dye concentration over time. These results showed that GFRP/clay ceramics reductively fired at 1073 K had a higher MB dye adsorption ability than that of the clay ceramic. The MB dye absorptivity of the reductively fired ceramics increased as we increased the mixing ratio of GFRP. We attribute this result to the high plastic carbide content in the ceramic, which has excellent dye absorbability. Furthermore, these particles had a comparatively high specific surface area and porosity.


1995 ◽  
Vol 117 (1) ◽  
pp. 133-138 ◽  
Author(s):  
G. Caprino ◽  
V. Tagliaferri ◽  
L. Covelli

A previously proposed micromechanical formula, aiming to predict the vaporization energy Qv of composite materials as a function of fiber and matrix properties and fiber volume ratio, was assessed. The experimental data, obtained on glass fiber reinforced plastic panels with different fiber contents cut by a medium power CO2 cw laser, were treated according to a procedure previously suggested, in order to evaluate Qv. An excellent agreement was found between experimental and theoretical Qv values. Theory was then used to predict the response to laser cutting of a composite material with a fiber content varying along the thickness. The theoretical predictions indicated that, in this case, the interpretation of the experimental results may be misleading, bringing to errors in the evaluation of the material thermal properties, or in the prediction of the kerf depth. Some experimental data were obtained, confirming the theoretical findings.


AIMS Energy ◽  
2018 ◽  
Vol 6 (6) ◽  
pp. 1032-1049 ◽  
Author(s):  
Yusuke Yasuda ◽  
◽  
Hayato Iwasaki ◽  
Kentaro Yasui ◽  
Ayako Tanaka ◽  
...  

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