scholarly journals Self-Assembled Behavior of Ultralightweight Aerogel from a Mixture of CNC/CNF from Oil Palm Empty Fruit Bunches

Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2649
Author(s):  
Dian Burhani ◽  
Athanasia Amanda Septevani ◽  
Ruby Setiawan ◽  
Luthfia Miftahul Djannah ◽  
Muhammad Andrew Putra ◽  
...  

This study aims to explore the use of cellulose nanocrystals (CNC) and cellulose nanofiber (CNF), obtained from unbleached fiber of oil palm empty fruit bunches (EFB), as raw materials in fabricating aerogel, using the facile technique without solvent displacement. The CNC was isolated from sulfuric acid hydrolysis, and the CNF was fibrillated using Ultra Turrax. The CNC and CNF were mixed by ultrasonication in different ratios to produce aerogel using slow freezing (−20 °C), followed by freeze-drying. The obtained aerogel was characterized as ultralightweight and highly porous material, at the density range of 0.0227 to 0.0364 g/cm3 and porosity of 98.027 to 98.667%. Interestingly, the ratio of CNC and CNF significantly affected the characteristics of the obtained aerogel. The mixed aerogel exhibited a higher specific surface area than pure CNC or CNF, with the highest value of 202.72 m2/g for the ratio of 1:3 (CNC/CNF). In addition, the crystallinity degree of obtained aerogel showed a higher value in the range of 76.49 to 69.02%, with the highest value being obtained for higher CNC content. This study is expected to provide insight into nanocellulose-based aerogel, with a promising potential for various applications.

2016 ◽  
Vol 82 (2) ◽  
Author(s):  
. ALHIDAYATULLAH ◽  
Lisdar I SUDIRMAN1 ◽  
Okky Setyawati DHARMAPUTRA

Abstract  Oil palm empty fruit bunches (OPEFB) are the ligno-cellulosic wastes from palm oil processing. They can be used to produce raw materials for value-added products. The purpose of this study was to determine the degradation capacity of JPA wood rot fungi and Trichoderma sp. S2-2 on OPEFB. The 500 g of substrates consisted of 81% of OPEFB, 15% bran, 1.5% lime and 1.5% gypsum were used for growing. The substrates were inoculated with five treatments i.e without isolate (K); with JPA isolate (JPA); with Trichoderma sp. S2-2 (T); with the two isolates (JPA + T); and with JPA isolate and after four weeks of incubation inoculated with Trichoderma sp. S2-2 [(JPA)+T]. All treatments were incubated for eight weeks. The results showed that JPA+T was the best treatment which the two isolates must be inoculated simultaneously for degradation of OPEFB. Lignin and cellulose content on JPA+T treatment respectively were 20.83% and 33.77%. C/N ratio of OPEFB degraded with JPA+T was lower than the C/N ratio of TKKS degraded with Trichoderma harzianum and TKKS degraded with EM4 in previous study. AbstrakTandan kosong kelapa sawit (TKKS) merupakan limbah lignoselulosa dari pengolahan minyak kelapa sawit. TKKS dapat dimanfaatkan untuk memperoleh bahan baku untuk produk bernilai tambah. Tujuan penelitian ini adalah untuk mengetahui kemampuan degradasi jamur pelapuk kayu isolat JPA dan Trichoderma sp. S2-2 pada TKKS. Sebanyak 500 g substrat terdiri dari 81% TKKS, 15% dedak, 1,5% kapur, dan 1,5% gypsum digunakan untuk per-tumbuhan. Substrat diinokulasi dengan lima perlakuan yaitu tanpa isolat (K); dengan isolat JPA (JPA); dengan Trichoderma sp. S2-2 (T); dengan isolat JPA dan setelah empat minggu inkubasi, diinokulasi dengan Trichoderma sp. S2-2 [(JPA+T)]. Semua perlakuan diinkubasi selama delapan minggu. Hasil percobaan menunjukkan bahwa perlakuan JPA+T adalah perlakuan terbaik yaitu kedua isolat tesebut harus diinokulasi secara bersamaan untuk mendegradasi TKKS. Kandungan lignin dan selulosa TKKS dengan  perlakuan  JPA+T   masing-masing  adalah  20,83% dan 33,77%. Rasio C/N TKKS hasil degradasi dengan JPA+T lebih  rendah  daripada  rasio C/N pada TKKS yang didegradasi dengan Trichoderma harzianum dan TKKS yang didegradasi dengan EM4 pada penelitian sebelumnya.


2019 ◽  
Vol 40 (04) ◽  
Author(s):  
Rebeca Vidal Vidal ◽  
Ramón Vidal García ◽  
Antonio Flores Martínez ◽  
Fco. José De los Santos Estébanez

Activated carbon is a highly porous material that is gaining interest nowadays in different sectors due to its strong adsorption capacity. Although it can be manufactured from very diverse feedstock, vegetable carbon and coal have been the most widely used raw materials. The increasing market demand and the encouragement of practices for the transition to the circular economy have promoted the use of wastes for the manufacturing of activated carbon. A significant part of the activated carbon currently in the market is produced from coconut shells, but wastes from a variety of sources are the subject of intense research. The number and variety of agricultural wastes tested as precursors of activated carbon is enormous, especially due to their high lignocellulose content. This review is focused on the use of almond shells as feedstock for the production of high-quality activated carbon.


2019 ◽  
Vol 2 (1) ◽  
pp. 65-68
Author(s):  
Rahman Farhan Aditya

Oil Palm growths in Indonesia are getting higher every year. Oil palm plantationproduced various waste, including oil palm empty fruit bunches (OP-EFB). 95 % Indonesia energy demand still provided by the fossil fuel and only 5 % provided by renewable energy, which provide opportunity of OP-EFB biomass pellets to be utilized as alternative resource. The research of biomass still low, especially research of OP-EFB biomass pellets. Therefore, the research objectives were to determine the production process of OP-EFB and to define the most effective binder and binder ratio for the biomass pellets. This research experiments  consist of shredding, chopping, drying, grinding, and sieving as raw material pretreatment. Also, varying the binder and binder concentration of the mixture between raw materials was the part of this thesis research. The binders used in this thesis research are PVAC paste and tapioca based paste with 4 variations of concentration. The analyses of the biomass pellets characteristic are density,compressive strength, proximate analysis (moisture, ash, volatile matter, and fixed carbon), calorific value, combustion rate, and gas chromatographic & mass spectroscopy (GCMS). The result shows that OP-EFB biomass pellets are qualified to be considered as biomass pellets. The most effective OP-EFB biomass pellets is biomass pellets with 10% tapioca binder concentration.


2016 ◽  
Vol 8 (1) ◽  
pp. 9
Author(s):  
I Dewa Gede Putra Prabawa

Oil palm empty fruit bunches and water hyacinth have not been widely used, especially in South Kalimantan. These materials were known containing macro elements that are needed by plants. This research was conducted to study potential of oil palm empty fruit bunches and water hyacinth as raw material for organic fertilizer. The effect of ashing temperature variations (500°C; 750°C; 1000°C) on the macro nutrients content (N, P2O5, and K2O) have been studied. The result showed that the characterization of empty fruit bunches and water hyacinth have the highest P2O5 and K2O content, whereas the content of nitrogen was still lowest. The treatment of ashing temperature was effect on improve total content of N, P2O5 and K2O. The highest nitrogen contents in empty fruit bunches and water hyacinth obtained on ashing temperature 500oC. The highest P2O5 contents in empty fruit bunches obtained on ashing temperature 1000oC and water hyacinth obtained on ashing temperature 750oC. The highest K2O contents in empty fruit bunches obtained on ashing temperature 750oC and water hyacinth obtained on ashing temperature 500oC. Ash of oil palm empty fruit bunches and water hyacinth was potentially as a source of nutrients P2O5 and K2O for organic fertilizer, but less potential as a source of nitrogen.Keywords: oil palm empty fruit bunches, water hyacinth, raw material, organic fertilizer


2016 ◽  
Vol 82 (2) ◽  
Author(s):  
. ALHIDAYATULLAH ◽  
Lisdar I SUDIRMAN1 ◽  
Okky Setyawati DHARMAPUTRA

Abstract  Oil palm empty fruit bunches (OPEFB) are the ligno-cellulosic wastes from palm oil processing. They can be used to produce raw materials for value-added products. The purpose of this study was to determine the degradation capacity of JPA wood rot fungi and Trichoderma sp. S2-2 on OPEFB. The 500 g of substrates consisted of 81% of OPEFB, 15% bran, 1.5% lime and 1.5% gypsum were used for growing. The substrates were inoculated with five treatments i.e without isolate (K); with JPA isolate (JPA); with Trichoderma sp. S2-2 (T); with the two isolates (JPA + T); and with JPA isolate and after four weeks of incubation inoculated with Trichoderma sp. S2-2 [(JPA)+T]. All treatments were incubated for eight weeks. The results showed that JPA+T was the best treatment which the two isolates must be inoculated simultaneously for degradation of OPEFB. Lignin and cellulose content on JPA+T treatment respectively were 20.83% and 33.77%. C/N ratio of OPEFB degraded with JPA+T was lower than the C/N ratio of TKKS degraded with Trichoderma harzianum and TKKS degraded with EM4 in previous study. AbstrakTandan kosong kelapa sawit (TKKS) merupakan limbah lignoselulosa dari pengolahan minyak kelapa sawit. TKKS dapat dimanfaatkan untuk memperoleh bahan baku untuk produk bernilai tambah. Tujuan penelitian ini adalah untuk mengetahui kemampuan degradasi jamur pelapuk kayu isolat JPA dan Trichoderma sp. S2-2 pada TKKS. Sebanyak 500 g substrat terdiri dari 81% TKKS, 15% dedak, 1,5% kapur, dan 1,5% gypsum digunakan untuk per-tumbuhan. Substrat diinokulasi dengan lima perlakuan yaitu tanpa isolat (K); dengan isolat JPA (JPA); dengan Trichoderma sp. S2-2 (T); dengan isolat JPA dan setelah empat minggu inkubasi, diinokulasi dengan Trichoderma sp. S2-2 [(JPA+T)]. Semua perlakuan diinkubasi selama delapan minggu. Hasil percobaan menunjukkan bahwa perlakuan JPA+T adalah perlakuan terbaik yaitu kedua isolat tesebut harus diinokulasi secara bersamaan untuk mendegradasi TKKS. Kandungan lignin dan selulosa TKKS dengan  perlakuan  JPA+T   masing-masing  adalah  20,83% dan 33,77%. Rasio C/N TKKS hasil degradasi dengan JPA+T lebih  rendah  daripada  rasio C/N pada TKKS yang didegradasi dengan Trichoderma harzianum dan TKKS yang didegradasi dengan EM4 pada penelitian sebelumnya.


2019 ◽  
Vol 1230 ◽  
pp. 012052
Author(s):  
M S Rahmi ◽  
B N Taufiq ◽  
R Indah ◽  
K Syahputri ◽  
M T Mangara ◽  
...  

2021 ◽  
Vol 7 (1) ◽  
pp. 37-41
Author(s):  
K. Y. Teo ◽  
S. Ghazali ◽  
S. Abd Rahim

Non-renewable resources such as fossil fuels could be combusted for energy and electricity to human kind. The demand of fossil fuel energy had reached an exponential growth which caused disasters and catastrophic damages on the environment; thus, renewable resources should be implemented to protect the environment. One of the natural resources was biomass waste. In this study, spent activated carbon (AC) was co-pelletized with biomass waste, oil palm empty fruit bunches (EFB). The effect of EFB, AC and adhesive (tapioca) mixing ratio in the pellet was evaluate through physical and thermal properties. The raw materials were grinded and mixed together at different AC/EFB/tapioca ratio. The mixed raw materials were compressed at 130°C and 7 MPa for 10 minutes. The densified products were characterized by using Thermogravimetric Analysis (TGA). For the thermal characteristics, sample with 0% waste AC, 90% EFB and 10% starch had the highest mass loss rate (570 µg/min) followed by sample with 10% of waste AC, 60% of EFB and 30% of starch which was 420 µg/min. Besides, sample with 0% waste AC, 90% EFB and 10% had the highest burn out temperature (802.6 °C) followed by sample with 30% of waste AC, 60% of EFB and 10% of starch which was 792.85 °C. In conclusion, sample with 0% waste AC, 90% EFB and 10% starch had an easiest ignition and longest combustion period since it had the highest mass loss rate and burn out temperature.


2016 ◽  
Vol 10 (3) ◽  
pp. 325-328 ◽  
Author(s):  
Bemgba Nyakuma ◽  
◽  
Arshad Ahmad ◽  
Anwar Johari ◽  
Tuan Abdullah ◽  
...  

The study is aimed at investigating the thermal behavior and decomposition kinetics of torrefied oil palm empty fruit bunches (OPEFB) briquettes using a thermogravimetric (TG) analysis and the Coats-Redfern model. The results revealed that thermal decomposition kinetics of OPEFB and torrefied OPEFB briquettes is significantly influenced by the severity of torrefaction temperature. Furthermore, the temperature profile characteristics; Tonset, Tpeak, and Tend increased consistently due to the thermal lag observed during TG analysis. In addition, the torrefied OPEFB briquettes were observed to possess superior thermal and kinetic properties over the untorrefied OPEFB briquettes. It can be inferred that torrefaction improves the fuel properties of pelletized OPEFB for potential utilization in bioenergy conversion systems.


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