scholarly journals Structural and Rheological Properties of Nonedible Vegetable Oil-Based Resin

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2490
Author(s):  
Nurul Huda Mudri ◽  
Luqman Chuah Abdullah ◽  
Min Min Aung ◽  
Dayang Radiah Awang Biak ◽  
Rida Tajau
Keyword(s):  
Shear Rate ◽  
Elevated Temperatures ◽  
Ultra Violet ◽  
Shear Thinning ◽  
Toluene Diisocyanate ◽  
Side Reactions ◽  
Self Healing ◽  
Jatropha Oil ◽  
Encapsulation Process ◽  
Fluid Behaviour

Jatropha oil-based polyol (JOL) was prepared from crude Jatropha oil via an epoxidation and hydroxylation reaction. During the isocyanation step, two different types of diisocyanates; 2,4-toluene diisocyanate (2,4-TDI) and isophorone diisocyanate (IPDI), were introduced to produce Jatropha oil-based polyurethane acrylates (JPUA). The products were named JPUA-TDI and JPUA-IPDI, respectively. The success of the stepwise reactions of the resins was confirmed using 1H nuclear magnetic resonance (NMR) spectroscopy to support the Fourier-transform infrared (FTIR) spectroscopy analysis that was reported in the previous study. For JPUA-TDI, the presence of a signal at 7.94 ppm evidenced the possible side reactions between urethane linkages with secondary amine that resulted in an aryl-urea group (Ar-NH-COO-). Meanwhile, the peak of 2.89 ppm was assigned to the α-position of methylene to the carbamate (-CH2NHCOO) group in the JPUA-IPDI. From the rheological study, JO and JPUA-IPDI in pure form were classified as Newtonian fluids, while JPUA-TDI showed non-Newtonian behaviour with pseudoplastic or shear thinning behaviour at room temperature. At elevated temperatures, the JO, JPUA-IPDI mixture and JPUA-TDI mixture exhibited reductions in viscosity and shear stress as the shear rate increased. The JO and JPUA-IPDI mixture maintained Newtonian fluid behaviour at all temperature ranges. Meanwhile, the JPUA-TDI mixture showed shear thickening at 25 °C and shear thinning at 40 °C, 60 °C and 80 °C. The master curve graph based on the shear rate for the JO, JPUA-TDI mixture and JPUA-IPDI mixture at 25 °C, 40 °C, 60 °C and 80 °C was developed as a fluid behaviour reference for future storage and processing conditions during the encapsulation process. The encapsulation process can be conducted to fabricate a self-healing coating based on a microcapsule triggered either by air or ultra-violet (UV) radiation.

Investigation on the Rheological Behavior of Polyamide6/Montmorillonite Nanocomposites by Reactive Extrusion

2011 ◽  
Vol 233-235 ◽  
pp. 1998-2001 ◽  
Author(s):  
Ming Zhao ◽  
Xiao Zhong Lu ◽  
Kai Gu ◽  
Xiao Min Sun ◽  
Chang Qing Ji
Keyword(s):  
Activation Energy ◽  
Shear Stress ◽  
Shear Rate ◽  
Rheological Behavior ◽  
Reactive Extrusion ◽  
Shear Thinning ◽  
Experimental Results ◽  
Montmorillonite Nanocomposites

The rheological behavior of PA6/montmorillonite(MMT) by reactive extrusion was investigated using cone-and-plate rheometer. The experimental results indicated that PA6/MMT exhibited shear-thinning behavior. The shear stress of both neat PA6 and PA6/MMT increased with the increase in the shear rate. The reduction of the viscous activation energy with the increase of shear stress reflected PA6/MMT can be processed over a wider temperature.

Granular effect on debris flow rheology

2021 ◽  
Author(s):  
Taiqiang Yang
Keyword(s):  
Shear Rate ◽  
Debris Flow ◽  
Debris Flows ◽  
Shear Thinning ◽  
Dynamical Equations ◽  
Real Rate ◽  
The Real ◽  
Jiangjia Gully ◽  
Material Sources ◽  
Surge Phenomena

<p>Debris flow is characterized by the multi-disperse grain composition and intergranular collision and friction, but the granular effects on rheology are often reduced to the volumetric concentration of solid (C<sub>v</sub>), almost ignoring the specific grain size distribution (GSD). In this study, small debris flows occurring in a tributary of Jiangjia Gully were taken as the material sources for rheology experiments. From the real flows we selected slurries with different C<sub>v</sub> and maximum grain sizes (D<sub>m</sub>) for rheological tests under shearing rate up to 40 (s<sup>-</sup><sup>1</sup>), which is usually the real rate for debris flows in natural conditions. The results indicate that the flows follow the Herschel-Bulkley (HB) rheology, with randomly changing consistency coefficient and relatively constant exponent of 0.45 on average. Only at high shear rate will the flow exhibit Bingham behavior. The HB rheology also reveals shear thinning behavior in surge phenomena observed in the field. Shear-thinning behavior is revealed by the viscosity-shear rate relationship: η<sub>a</sub>=pγ<sup>q</sup>, with the exponent (thinning index) dependent on shear rate. This greatly concerns the surge phenomena observed in field. Moreover, both the yield stress and the effective viscosity are found to be perfectly related to the scaling GSD parameters in power-law and exponential form, with nearly constant exponents independent of the shear rate(Figure 1). The rheology properties can be calculated from their relationships to GSD parameters (μ, D<sub>c</sub>), which in turn can be used to infer the HB rheology for the concerned flows and then build the dynamical equations(Figure 2). This implies the presence of some interlock between the fine and coarse grains. Finally the rheology model (general in HB form) can be completely determined by the GSD parameters. This study has for the first time proposed quantitative formulas for rheology incorporating GSD parameters, which is helpful for more accurate dynamic analysis of debris flow.</p>

Abstract 17133: A Novel, Shear-Thinning and Rapidly Self-Healing Polymer Nanoparticle Hydrogel Diminishes Post-Operative Adhesions in Rodent and Ovine Models of Cardiac Adhesion Formation

Circulation ◽  
2018 ◽  
Vol 138 (Suppl_1) ◽  
Author(s):  
Lyndsay M Stapleton ◽  
Amanda N Steele ◽  
Hanjay N Wang ◽  
Michael J Paulsen ◽  
Hector L Hernandez ◽  
...  
Keyword(s):  
Inflammatory Responses ◽  
Heart Function ◽  
Adhesion Formation ◽  
Shear Thinning ◽  
Adhesion Prevention ◽  
Large Animal ◽  
Self Healing ◽  
Adhesion Barrier ◽  
Polymer Nanoparticle ◽  
Large Animal Models

Objective: Adhesions develop after 95% of operations, represent a major clinical challenge, and cost the U.S healthcare system $2.5B annually. In cardiac surgery, adhesions are problematic during re-operations, increasing operative times and posing risks of hemorrhage and injury to the heart and lungs during sternal reentry and cardiac dissection. We hypothesized that shear-thinning, self-healing polymer nanoparticle hydrogels (PNP) would provide a viscoelastic barrier, effectively preventing adhesion formation (Fig 1A). Methods: Multiple PNP formulations underwent rheologic characterization. Male Sprague Dawley rats (n=52) underwent permanent ligation of the LAD to induce robust postinfarct adhesions, followed by epicardial application of PNP (200L), Seprafilm®(1cm 2 ), or no treatment. Male Dorset sheep (n=8) underwent an anterolateral epicardial abrasion followed by application of PNP (25mL), Seprafilm® (12 cm 2 ), or no treatment. Degree of adhesion formation, standardized dissection time, heart function, and immune response were assessed 4-weeks following surgery. Results: PNP exhibited formulation-dependent mechanical properties indicating the effect of hydrogel stiffness on adhesion barrier efficacy (Fig 1B). Infarct size and heart function were controlled to ensure similar inflammatory responses contributing to adhesion formation across treatment groups. Treatment with certain PNP formulations significantly reduced the development of adhesions compared to controls (Fig 1C). Ovine hearts treated with the PNP 1:10 revealed a pristine epicardial surface (Fig 1D, 1E, and 1F) and resulted in a shorter dissection time relative to the controls (Fig 1G). Conclusion: Administration of a shear-thinning, self-healing hydrogel reduces the extent of adhesion formation in the thoracic cavity following surgery in small and large animal models. PNP provides an easily delivered, scalable solution for post-operative adhesion prevention.

scholarly journals Synthesis of mechanically strong waterborne poly(urethane-urea)s capable of self-healing at elevated temperatures

2019 ◽  
Vol 112 ◽  
pp. 411-422 ◽  
Author(s):  
Sil Nevejans ◽  
Nicholas Ballard ◽  
Iván Rivilla ◽  
Mercedes Fernández ◽  
Antxon Santamaria ◽  
...  
Keyword(s):  
Elevated Temperatures ◽  
Self Healing

The Simulation of Aggregated Colloids Under Flow

1992 ◽  
Vol 289 ◽  
Author(s):  
John R. Melrose
Keyword(s):  
Shear Rate ◽  
Large Scale ◽  
Shear Thinning ◽  
High Shear ◽  
Shear Rates ◽  
Rouse Model ◽  
High Shear Rates ◽  
Structural Breakdown ◽  
Large Scale Simulations ◽  
Low Shear

AbstractAn overview is given of theories of aggregates under flow. These generally assume some sort of structural breakdown as the shear rate is increased. Models vary with both the rigidity of the bonding and the level of treatment of hydrodynamics. Results are presented for simulations of a Rouse model of non-rigid, (i.e. central force) weakly bonded aggregates. In large scale simulations different structures are observed at low and high shear rates. The change from one structure to another is associated with a change in the rate of shear thinning. The model captures low shear rate features of real systems absent in previous models: this feature is ascribed to agglomerate deformations. Quantitatively, the model is two orders of magnitude out from experiment but some scaling is possible.

Stability of a Shear-Thinning Film on a Porous Substrate

2010 ◽  
Author(s):  
R. Usha ◽  
S. Millet ◽  
H. BenHadid ◽  
F. Rousset
Keyword(s):  
Thin Film ◽  
Free Surface ◽  
Shear Rate ◽  
Film Flow ◽  
Shear Thinning ◽  
Free Surface Flows ◽  
Significant Feature ◽  
Porous Substrate ◽  
Carreau Model ◽  
Porous Substrates

A significant feature of gravity-driven film flows of Newtonian and rheologically complex fluids down an inclined/vertical substrate is the instability of the free surface which manifests as surface waves having wavelengths much larger than the film thickness. There are a number of applications which can be modeled as thin film flow systems on porous substrates. Pascal [1] investigated the stability of a falling power-law film on an inclined porous substrate. This model for the fluid predicts a viscosity that goes to infinity as the shear rate approaches zero. There is a need to employ a more appropriate model to examine the effects of non-Newtonian rheology on the dynamics and stability of thin film free surface flows down inclined or vertical rigid/porous substrates. The four-parameter Carreau model predicts a viscosity that remains finite as the shear rate approaches zero and is given by η−η∞η0−η∞=[1+(δγ)˙2]n−12.(1) Weinstein [2] and Rousset et al. [3] have considered the Carreau model and have examined the temporal stability of a film flow down an impermeable rigid inclined substrate. The authors show that a shear-thinning Carreau fluid film on a rigid impermeable substrate is more unstable than a Newtonian film. This calls for an analysis that includes both the effects of Carreau non-Newtonian rheology and bottom permeability and the present study reports such an investigation of a Carreau non-Newtonian film on a porous inclined substrate.

scholarly journals Shear-Thinning Effect of the Spinning Disc Mixer on Starch Nanoparticle Precipitation

Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1622
Author(s):  
Sahr Sana ◽  
Vladimir Zivkovic ◽  
Kamelia Boodhoo
Keyword(s):  
Shear Rate ◽  
Shear Thinning ◽  
Solute Concentration ◽  
Liquid Films ◽  
High Shear ◽  
Shear Rates ◽  
Disc Surface ◽  
Particle Characteristics ◽  
Thinning Effect ◽  
Spinning Disc

Spinning disc technology is capable of achieving intensified micromixing within thin liquid films created through large shear rates, typically of the order of 103 s−1, generated by means of fast disc surface rotation. In this study the effect of the high shear on solvent–antisolvent mixing and starch nanoparticle precipitation is reported. Rheological studies of starch solutions at 2% w/v and 4% w/v have demonstrated their shear-thinning behaviour at the large shear rates experienced on the spinning disc surface. The effect of such high shear rate on starch nanoparticle precipitation is investigated alongside solute concentration and several other operating parameters such as flow rate, disc rotational speed, and solvent/antisolvent ratio. A reduction in nanoparticle size has been observed with an increase in starch concentration, although agglomeration was found to be more prevalent amongst these smaller particles particularly at larger flow rates and disc rotational speeds. Micromixing time, estimated on the basis of an engulfment mechanism, has been correlated against shear rate. With fast micromixing of the order of 1 ms observed at higher shear rates, and which are practically unaffected by the starch concentrations used, micromixing is not thought to be influential in determining the particle characteristics highlighted in this work.

Rheological Behavior of Seed Gum from Cassia fistula

2019 ◽  
Vol 818 ◽  
pp. 16-20
Author(s):  
Wancheng Sittikijyothin ◽  
Khanaphit Khumduang ◽  
Keonakhone Khounvilay ◽  
Rattanaphol Mongkholrattanasit
Keyword(s):  
Shear Rate ◽  
Flow Behavior ◽  
Critical Concentration ◽  
Shear Thinning ◽  
Zero Shear Viscosity ◽  
Specific Viscosity ◽  
Cross Model ◽  
Linear Slope ◽  
Mechanical Spectra ◽  
Seed Gum

The C. fistula gums in aqueous solutions clearly exhibited shear-thinning flow behavior at high shear rate, however, at higher concentrations, pronounced shear thinning was observed. The value of zero shear viscosity [h0] was predicted by fitting Cross model. A plotting of specific viscosity at zero shear rate (hsp0) against coil overlap parameter (C[h]) was shown the linear slope of dilute and simi-dilute as 1.43 and 4.10, respectively, which found the critical concentration (C*) about 7.08/[h]. While, the mechanical spectra in the linear viscoelastic region of gum solutions showed the typical shape for macromolecular solutions.

Fully Developed Flow of Power-Law Fluid Through a Cylindrical Microfluidic Pipe: Pressure Drop and Electroviscous Effects

2008 ◽  
Author(s):  
Ram P. Bharti ◽  
Dalton J. E. Harvie ◽  
Malcolm R. Davidson
Keyword(s):  
Pressure Drop ◽  
Field Strength ◽  
Charge Density ◽  
Power Law ◽  
Maximum Velocity ◽  
Shear Thickening ◽  
Shear Thinning ◽  
Electrical Field ◽  
Electrical Field Strength ◽  
Fluid Behaviour

Pressure drop and electroviscous effects in the axisymmetric, steady, fully developed, pressure-driven flow of incompressible power-law fluids through a cylindrical microchannel at low Reynolds number (Re = 0.01) have been investigated. The Poisson-Boltzmann equation (describing the electrical potential) and the momentum equations in conjunction with electrical force and power-law fluid rheology have been solved numerically using the finite difference method. The pipe wall is considered to have uniform surface charge density (S = 4) and the liquid is assumed to be a symmetric electrolyte solution. In particular, the influence of the dimensionless inverse Debye length (K = 2, 20) and power-law flow behaviour index (n = 0.2, 1, 1.8) on the EDL potential, ion concentrations and charge density profiles, induced electrical field strength, velocity and viscosity profiles and pressure drop have been studied. As expected, the local EDL potential, local charge density and electrical field strength increases with decreasing K and/or increasing S. The velocity profiles cross-over away from the charged pipe wall with increasing K and/or decreasing n. The maximum velocity at the center of the pipe increases with increasing n and/or increasing S and/or decreasing K. The shear-thinning fluid viscosity is strongly dependent on K and S, whereas the shear-thickening viscosity is very weakly dependent on K and S. For fixed K, as the fluid behaviour changes from Newtonian (n = 1) to shear-thinning (n < 1), the induced electrical field strength increases and maximum velocity reduces. On the other hand, the change in fluid behaviour from Newtonian (n = 1) to shear-thickening (n > 1) decreases the electrical field strength and increases the maximum velocity. The non-Newtonian effects on maximum velocity and pressure drop are stronger in shear-thinning fluids at small K and large S, the shear-thickening fluids show opposite influence. Electroviscous effects enhance with decreasing K and/or increasing S. The electroviscous effects show complex dependence on the non-Newtonian tendency of the fluids. The shear-thickening (n > 1) fluids and/or smaller K show stronger influence on the pressure drop and thus, enhance the electroviscous effects than that in shear-thinning (n < 1) fluids and/or large K where EDL is very thin.

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