scholarly journals Polymer Composites Based on Polycarbonate (PC) Applied to Additive Manufacturing Using Melted and Extruded Manufacturing (MEM) Technology

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2455
Author(s):  
Katarzyna Bulanda ◽  
Mariusz Oleksy ◽  
Rafał Oliwa ◽  
Grzegorz Budzik ◽  
Łukasz Przeszłowski ◽  
...  
Keyword(s):  
3D Printing ◽  
Polymer Composites ◽  
Functional Properties ◽  
Charpy Impact ◽  
Scanning Calorimetry ◽  
Multiwalled Carbon ◽  
Hybrid Filler ◽  
Static Tensile ◽  
Ft Ir ◽  
Charpy Impact Strength

As part of the present work, polymer composites used in 3D printing technology, especially in Melted and Extruded Manufacturing (MEM) technology, were obtained. The influence of modified fillers such as alumina modified silica, quaternary ammonium bentonite, lignin/silicon dioxide hybrid filler and unmodified multiwalled carbon nanotubes on the properties of polycarbonate (PC) composites was investigated. In the first part of the work, the polymer and its composites containing 0.5–3 wt.% filler were used to obtain a filament using the proprietary technological line. The moldings for testing functional properties were obtained with the use of 3D printing and injection molding techniques. In the next part of the work, the rheological properties—mass flow rate (MFR) and mechanical properties—Rockwell hardness, Charpy impact strength and static tensile strength with Young’s modulus were examined. The structure of the obtained composites was also described and determined using scanning electron microscopy (SEM). The porosity, roughness and dimensional stability of samples obtained by 3D printing were also determined. On the other hand, the physicochemical properties were presented on the basis of the research results using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), wide angle X-ray scattering analysis (WAXS) and Fourier Transform infrared spectroscopy (FT-IR). Additionally, the electrical conductivity of the obtained composites was investigated. On the basis of the obtained results, it was found that both the amount and the type of filler significantly affected the functional properties of the composites tested in the study.

scholarly journals Preliminary Characterization of Novel LDPE-Based Wear-Resistant Composite Suitable for FDM 3D Printing

Materials ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 2520 ◽  
Author(s):  
Piotr Olesik ◽  
Marcin Godzierz ◽  
Mateusz Kozioł
Keyword(s):  
3D Printing ◽  
Tensile Tests ◽  
Waste Glass ◽  
Scanning Calorimetry ◽  
Path Direction ◽  
Pin On Disc ◽  
Static Tensile ◽  
Fine Glass ◽  
3D Printed ◽  
Ldpe Composites

Low-density polyethylene (LDPE) composites reinforced with finely powdered waste glass were identified as a potential material for 3D printed structures for use in low-duty frictional applications. A recently published 3D printing model was used to calculate the limits in the filament feed rate and printing speed. Tribological tests (pin-on-disc method) of the printed composites were performed for different print-path directions. Differential scanning calorimetry (DSC) was performed on the samples and the composites showed a higher crystallinity compared with LDPE, which partially explains the higher elastic modulus of the composites determined during static tensile tests. Using a fine glass powder as reinforcement improved the wear resistance of LDPE by 50% due to the formation of a sliding film on the sample’s surface. An evident effect of friction direction vs. the printed path direction on wear was found; which was likely related to differences in the removal of friction products from the friction area for different print-path directions. The LDPE composites with fine waste glass particles are promising materials for low-duty frictional applications and should be the subject of further research.

scholarly journals Study of the Influence of the Almond Shell Variety on the Mechanical Properties of Starch-Based Polymer Biocomposites

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2049 ◽  
Author(s):  
Ana Ibáñez García ◽  
Asunción Martínez García ◽  
Santiago Ferrándiz Bou
Keyword(s):  
Charpy Impact ◽  
X Ray Diffraction ◽  
Almond Shell ◽  
Scanning Calorimetry ◽  
Commercial Mixture ◽  
Hardness Tests ◽  
Twin Screw ◽  
Ft Ir ◽  
Mechanical Tensile ◽  
The Individual

This article is focused on the development of a series of biodegradable and eco-friendly biocomposites based on starch polymer (Mater-Bi DI01A) filled with 30 wt% almond shell (AS) of different varieties (Desmayo Rojo, Largueta, Marcona, Mollar, and a commercial mixture of varieties) to study the influence of almond variety in the properties of injected biodegradable parts. The different AS varieties are analysed by means of Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), Scanning Electron Microscopy (SEM), and X-ray Diffraction (XRD). The biocomposites are prepared in a twin-screw extruder and characterized in terms of their mechanical (tensile, flexural, Charpy impact, and hardness tests) and thermal properties (differential scanning calorimetry (DSC) and TGA). Despite observing differences in the chemical composition of the individual varieties with respect to the commercial mixture, the results obtained from the mechanical characterisation of the biocomposites do not present significant differences between the diverse varieties used. From these results, it was concluded that the most recommended option is to work with the commercial mixture of almond shell varieties, as it is easier and cheaper to acquire.

scholarly journals Comparison of the efficiency of the most effective heterogeneous nucleating agents for Poly(lactic acid)

2021 ◽  
Author(s):  
Tatyana Ageyeva ◽  
József Gábor Kovács ◽  
Tamás Tábi
Keyword(s):  
Lactic Acid ◽  
Tensile Modulus ◽  
Charpy Impact ◽  
Nucleating Agent ◽  
Poly Lactic Acid ◽  
Nucleating Agents ◽  
Scanning Calorimetry ◽  
Injection Molded ◽  
Heat Deflection Temperature ◽  
Charpy Impact Strength

AbstractWe selected the thirteen most effective nucleating agents for Poly(lactic acid) (PLA) from the literature, and synthesized and compounded them with two different PLA grades: 3001D (1.4% D-lactide content) and 3100HP (0.5% D-lactide content, considered PLLA). We determined the crystallinity and crystallization of PLA with different nucleating agents in identical conditions (same nucleating agent content, same cooling rate) with the help of differential scanning calorimetry. We compared the efficiency of each nucleating agent and found that for both PLA grades, Zinc PhenylPhosphonate was the most effective. However, even when nucleated PLA was injection molded into a cold mold (25 °C), it still could not fully crystallize during cooling and the heat deflection temperature did not increase significantly. The maximum achieved crystallinity, in this case, was between 32.4 and 35.7%. On the contrary, when a 90 °C “hot mold” and in-mold crystallization together were applied, the specimens achieved full crystallization during the injection molding cycle (crystallinity was between 44.5 and 50.0%), and the heat deflection temperature increased to an average of 88.8 °C. We also examined the mechanical properties of the nucleated PLA and found that the usage of nucleating agents together with a hot mold improved tensile strength, tensile modulus, and Charpy impact strength but decreased elongation at break.

Preparation and Characterization of Compounds Based on Poly(hydroxymethylacrylamide) and Post-consumer Polypropylene

2016 ◽  
Vol 10 (3) ◽  
pp. 291-298 ◽  
Author(s):  
Ilma Cirne ◽  
◽  
Maria Esperidiao ◽  
Jaime Boaventura ◽  
Elizabete Lucas ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Food Packaging ◽  
Low Cost ◽  
Condensation Reaction ◽  
Polymerization Reaction ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Swelling Capacity ◽  
Ft Ir

In this work, in order to obtain materials with potential for treatment of water from oil industry, polymer composites were synthesized by polymerization reaction via free radical using n-hydroxymethyl acrylamide (HMAA) in the presence of post-consumer polypropylene (PP) with subsequent condensation reaction catalyzed by heating, which avoids the use of crosslinking agents. The products were characterized by Fourier transform infrared spectroscopy (FT-IR), optical microscopy (OM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and X-ray diffraction (XRD). Moreover, the bulk density and the degree of swelling were also determined. The synthesis was shown to be reproducible and led to achieving polymer composites with high levels of PP after usage from food packaging, which can be associated with a relatively low cost of production. The swelling capacity and the thermal stability of the composite increased with increasing PP content in the mixture.

scholarly journals MODIFIED POLYLACTIDE FILAMENTS FOR 3D PRINTING WITH IMPROVED MECHANICAL PROPERTIES

2016 ◽  
Vol 7 (2) ◽  
Author(s):  
Janez Slapnik ◽  
Rajko Bobovnik ◽  
Maja Mešl ◽  
Silvester Bolka
Keyword(s):  
Thermal Properties ◽  
3D Printing ◽  
Impact Strength ◽  
Charpy Impact ◽  
Charpy Impact Test ◽  
Core Shell ◽  
Mechanical And Thermal Properties ◽  
3D Printed ◽  
Injection Molded ◽  
Charpy Impact Strength

We investigated the effects of two different types of impact modifiers, i.e. core-shell rubber and aliphatic polyester, on the mechanical and thermal properties of polylactide (PLA) filaments for 3D printing. First, PLA/impact modifier blends with various concentrations of impact modifiers were prepared by melt blending in a co-rotating twin screw extruder and test specimens by injection molding. The mechanical and thermal properties of blends were investigated by tensile and bending tests, dynamic mechanical analysis (DMA) and Charpy impact test. It was found that core-shell rubber remarkably improved Charpy impact strength at loadings above 5 wt % (up to 746 %). As shown by DMA, the PLA/10 wt % core-shell rubber blend exhibited better damping performance as compared to neat PLA over the whole examined frequency range, especially at high frequencies, which explained the increase in impact strength. The filament for a fused deposition modeling (FDM), 3D printer was prepared from blend with the highest impact strength (PLA/10 wt % core-shell rubber), whereas PLA and acrylonitrile-butadiene-styrene copolymer (ABS) filaments were used for reference. Test specimens were prepared by using a consumer FDM 3D printer. The mechanical and thermal properties were investigated by tensile and bending tests, DMA, Charpy impact test, and ultra-fast differential scanning calorimetry (Flash DSC). Specimens from PLA blend exhibited 109 % increase in Charpy impact strength as compared to neat PLA. In contrast to injection molded specimens, 3D printed PLA blend exhibited higher tensile E modulus than neat PLA, which was ascribed to improved interlayer adhesion. Moreover, DMA and Flash DSC analysis of 3D printed specimens showed an increase in the glass transition temperature as compared to injection molded specimens. This phenomenon was ascribed to reduction of free volume because of slow cooling in 3D printing process, which is also the reason for increased tensile E modulus of the PLA blend. All tested PLA, PLA blend and ABS filaments were in amorphous state as shown by Flash DSC analysis. Bending test showed an increased toughness of PLA blend in comparison to neat PLA and also higher toughness as compared to ABS. The modified polylactide (PLA/10 wt % core-shell rubber) filament thus combines easy processability of PLA filament and impact toughness of ABS filament.

scholarly journals Thermal Aging of Menzolit BMC 3100

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Pavol Kostial ◽  
Zora Kostialova Jancikova ◽  
Ondrej Krejcar ◽  
Kamil Kuca ◽  
Oluwaseun Fadeyi ◽  
...  
Keyword(s):  
Physical Properties ◽  
Thermal Aging ◽  
Room Temperature ◽  
Negative Impact ◽  
Charpy Impact ◽  
Thermomechanical Analysis ◽  
Material Degradation ◽  
Scanning Calorimetry ◽  
Shape Stability ◽  
Charpy Impact Strength

This paper deals with the influence of thermal aging on physical properties of a composite material, Menzolit BMC 3100. First, we present a number of analysis, FTIR (infrared spectroscopy), DSC (differential scanning calorimetry), TMA (thermomechanical analysis), TGA (thermogravimetric analysis), and HDT (heat deflection temperature), to understand the material performance under heat, and then, we carry out a test of toughness and strength using Charpy impact strength and Brinell hardness. Finally, we present optical surface analysis of the material under investigation by carrying out aging analysis at increments from room temperature up to 300°C. It was observed that above 200°C, the material begins to degrade at the surface, especially its organic component, polyester resin. This type of degradation has a negative impact on a variety of its physical properties. Exposure to temperatures above 200°C reduces the material’s hardness, toughness, and shape stability, likewise, material degradation was found to increase with higher thermal loads almost linearly for all the observed properties.

scholarly journals Characteristics of ADI Ductile Cast Iron with Single Addition of 1.56% Ni

2017 ◽  
Vol 62 (4) ◽  
pp. 2273-2280
Author(s):  
B. Mrzygłód ◽  
A. Kowalski ◽  
I. Olejarczyk-Wożenska ◽  
T. Giętka ◽  
M. Głowacki
Keyword(s):  
Mechanical Properties ◽  
Cast Iron ◽  
Ductile Iron ◽  
Charpy Impact ◽  
Ductile Cast Iron ◽  
Microstructure And Mechanical Properties ◽  
Static Tensile ◽  
Single Addition ◽  
Charpy Impact Strength ◽  
The Impact

Abstract The results of examinations of microstructure and an analysis of its impact on selected mechanical properties of austempered ductile iron (ADI) were presented in the paper. The ADI was produced from the ductile iron containing 1.56% Ni only alloying addition. The effect of the austempering time and temperature on the microstructure and mechanical properties of the examined cast iron was considered. Constant conditions of austenitizing were assumed and six variants of the austempering treatment were adopted. The studyof mechanical properties included a static tensile test, Charpy impact strength test and Brinellhardness measurement. This work complements the knowledge about alloying additions effect on microstructure and mechanical properties of ADI and focuses on the impact of a single alloying element (Ni).

Thermal Behaviour of Candesartan Active substance and in pharmaceutical compounds

2017 ◽  
Vol 68 (8) ◽  
pp. 1895-1902
Author(s):  
Ioana Cristina Tita ◽  
Eleonora Marian ◽  
Bogdan Tita ◽  
Claudia Crina Toma ◽  
Laura Vicas
Keyword(s):  
Thermal Behaviour ◽  
Active Substance ◽  
Pharmaceutical Research ◽  
Pharmaceutical Product ◽  
Nitrogen Atmosphere ◽  
Pure Substance ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Ft Ir

Thermal analysis is one of the most frequently used instrumental techniques in the pharmaceutical research, for the thermal characterization of different materials from solids to semi-solids, which are of pharmaceutical relevance. In this paper, simultaneous thermogravimetry/derivative thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC) were used for characterization of the thermal behaviour of candesartan cilexetil � active substance (C-AS) under dynamic nitrogen atmosphere and nonisothermal conditions, in comparison with pharmaceutical product containing the corresponding active substance. It was observed that the commercial samples showed a different thermal profile than the standard sample, caused by the presence of excipients in the pharmaceutical product and to possible interaction of these with the active substance. The Fourier transformed infrared spectroscopy (FT-IR) and X-ray powder diffraction (XRPD) were used as complementary techniques adequately implement and assist in interpretation of the thermal results. The main conclusion of this comparative study was that the TG/DTG and DSC curves, together with the FT-IR spectra, respectively X-ray difractograms constitute believe data for the discrimination between the pure substance and pharmaceutical forms.

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