scholarly journals Preparation of p-Phenylenediamine Modified Graphene Foam/Polyaniline@Epoxy Composite with Superior Thermal and EMI Shielding Performance

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2324
Author(s):  
Liusi Wang ◽  
Haoliang Li ◽  
Shuxing Xiao ◽  
Mohan Zhu ◽  
Junhe Yang
Keyword(s):  
Electromagnetic Interference ◽  
In Situ Polymerization ◽  
Hot Spot ◽  
Casting Process ◽  
Conductive Network ◽  
Graphene Foam ◽  
Integrated Devices ◽  
Reduced Modulus ◽  
The Stability ◽  
Modified Graphene

With the development of integrated devices, the local hot spot has become a critical problem to guarantee the working efficiency and the stability. In this work, we proposed an innovative approach to deliver graphene foam/polyaniline@epoxy composites (GF/PANI@EP) with improvement in the thermal and mechanical property performance. The graphene foam was firstly modified by the grafting strategy of p-phenylenediamine to anchor reactive sites for further in-situ polymerization of PANI resulting in a conductive network. The thermal conductivity (κ) and electromagnetic interference shielding (EMI) performance of the optimized GF/PANI4:1@EP is significantly enhanced by 238% and 1184%, respectively, compared to that of pristine EP with superior reduced modulus and hardness. Such a method to deliver GF composites can not only solve the agglomeration problem in traditional high content filler casting process, but also provides an effective way to build up conductive network with low density for thermal management of electronic devices.

scholarly journals Interface Engineered Microcellular Magnetic Conductive Polyurethane Nanocomposite Foams for Electromagnetic Interference Shielding

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Guolong Sang ◽  
Pei Xu ◽  
Tong Yan ◽  
Vignesh Murugadoss ◽  
Nithesh Naik ◽  
...  
Keyword(s):  
Electromagnetic Interference ◽  
Magnetic Loss ◽  
Interfacial Polarization ◽  
Conductive Network ◽  
Shielding Effectiveness ◽  
Electromagnetic Interference Shielding ◽  
Multiple Reflections ◽  
Conduction Loss ◽  
Composite Foams ◽  
Emi Se

Abstract Lightweight microcellular polyurethane (TPU)/carbon nanotubes (CNTs)/ nickel-coated CNTs (Ni@CNTs)/polymerizable ionic liquid copolymer (PIL) composite foams are prepared by non-solvent induced phase separation (NIPS). CNTs and Ni@CNTs modified by PIL provide more heterogeneous nucleation sites and inhibit the aggregation and combination of microcellular structure. Compared with TPU/CNTs, the TPU/CNTs/PIL and TPU/CNTs/Ni@CNTs/PIL composite foams with smaller microcellular structures have a high electromagnetic interference shielding effectiveness (EMI SE). The evaporate time regulates the microcellular structure, improves the conductive network of composite foams and reduces the microcellular size, which strengthens the multiple reflections of electromagnetic wave. The TPU/10CNTs/10Ni@CNTs/PIL foam exhibits slightly higher SE values (69.9 dB) compared with TPU/20CNTs/PIL foam (53.3 dB). The highest specific EMI SE of TPU/20CNTs/PIL and TPU/10CNTs/10Ni@CNTs/PIL reaches up to 187.2 and 211.5 dB/(g cm−3), respectively. The polarization losses caused by interfacial polarization between TPU substrates and conductive fillers, conduction loss caused by conductive network of fillers and magnetic loss caused by Ni@CNT synergistically attenuate the microwave energy.

scholarly journals An Evaluation of the Stability of Mould Flux Properties in the Process of Continuous Steel Casting

2017 ◽  
Vol 62 (2) ◽  
pp. 885-889 ◽  
Author(s):  
J. Falkus
Keyword(s):  
Process Parameters ◽  
Liquidus Temperature ◽  
Casting Process ◽  
Continuous Steel Casting ◽  
Time Intervals ◽  
Equal Time ◽  
Industrial Experiments ◽  
Mould Flux ◽  
Steel Cast ◽  
The Stability

AbstractThis paper presents research on the mould slag formed on the basis of two mould fluxes. In the conducted industrial experiments, slag was sampled in equal time intervals between adding subsequent portions of mould flux. The research focused on the an evaluation of the stability of slag parameters by assessing the change in its liquidus temperature. It was shown that a mould flux needs to be assessed individually taking into account the casting process parameters and the steel cast grade.

scholarly journals Investigation of Silicon Nanoparticle-Polystyrene Hybrids

2019 ◽  
Vol 2 (2) ◽  
pp. 49-50
Author(s):  
Madihah Khan ◽  
Alyxandra Thiessen ◽  
I Teng Cheong ◽  
Sarah Milliken ◽  
Jonathan G. C. Veinot
Keyword(s):  
Silicon Nanoparticles ◽  
In Situ Polymerization ◽  
Toxic Substance ◽  
Homogeneous Mixture ◽  
Silicon Nanoparticle ◽  
Molecular Weights ◽  
Abundant Element ◽  
The Stability ◽  
Led Lights

Current LED lights are created with quantum dots made of metals like selenium, tellurium, and cadmium which can be toxic. Silicon is used as a non-toxic substance and is the second most abundant element in the earth's crust. When silicon is prepared at a nanometer size, unique luminesce optical properties emerge that can be tuned using sized surface chemistry. Therefore, silicon nanoparticles can be used as an alternative emitter for LED lights. To produce hydride-terminated silicon nanoparticles we must synthesize the particles. Hydrogen silsesquioxane (HSQ) is processed at 1100 °C for one hour causing Si to cluster and form a SiO2 matrix, also known as the composite. The composite is then manually crushed in ethanol. The solution is further ground using glass beads, then filtered to get the composite powder. The final step is the HF etching. The hydride-terminated particles are then functionalized using three different methods to synthesize silicon nanoparticle-polystyrene hybrids, which determine the magnitude of luminosity and the quality of the hybrids. We spin coat each method and results were analyzed. Method 1 uses heat to functionalize hydride-terminated silicon nanoparticles with styrene. This process also causes styrene to attach to styrene to form a polystyrene chain. Method 1 gave a homogeneous mixture which yielded a consistent, bright and homogenous film. In method 2, dodecyl-terminated silicon nanoparticles are mixed with premade polystyrene. While this method gave better control of the amount of silicon nanoparticles inside the polymer hybrid, a homogeneous mixture was not created due to the different structures of polystyrene and dodecyl chains. Method 3 has dodecyl-terminated silicon with in-situ styrene polymerization. It generated a homogeneous mixture. The in-situ polymerization stabilizes the particles, allowing for brighter luminescence. Because of the stability and lower molecular weight, the mixture was easier to dissolve. We concluded that the different methods resulted in different polymer molecular weights and this created distinct properties between the polymer hybrids when spin-coating.    

scholarly journals Performance of Two Different Flight Configurations for Drone-Borne Magnetic Data

Sensors ◽  
2021 ◽  
Vol 21 (17) ◽  
pp. 5736
Author(s):  
Filippo Accomando ◽  
Andrea Vitale ◽  
Antonello Bonfante ◽  
Maurizio Buonanno ◽  
Giovanni Florio
Keyword(s):  
Electromagnetic Interference ◽  
Source Parameters ◽  
Spectral Characteristics ◽  
Magnetic Data ◽  
Prototype System ◽  
Control Dataset ◽  
Periodic Data ◽  
Ground Magnetic ◽  
The Stability ◽  
Careful Processing

The compensation of magnetic and electromagnetic interference generated by drones is one of the main problems related to drone-borne magnetometry. The simplest solution is to suspend the magnetometer at a certain distance from the drone. However, this choice may compromise the flight stability or introduce periodic data variations generated by the oscillations of the magnetometer. We studied this problem by conducting two drone-borne magnetic surveys using a prototype system based on a cesium-vapor magnetometer with a 1000 Hz sampling frequency. First, the magnetometer was fixed to the drone landing-sled (at 0.5 m from the rotors), and then it was suspended 3 m below the drone. These two configurations illustrate endmembers of the possible solutions, favoring the stability of the system during flight or the minimization of the mobile platform noise. Drone-generated noise was filtered according to a CWT analysis, and both the spectral characteristics and the modelled source parameters resulted analogously to that of a ground magnetic dataset in the same area, which were here taken as a control dataset. This study demonstrates that careful processing can return high quality drone-borne data using both flight configurations. The optimal flight solution can be chosen depending on the survey target and flight conditions.

Study on the Causes and Prevention Measures of Shrinkage Defects of Heavy V-Belt Pulley in the Production

2014 ◽  
Vol 722 ◽  
pp. 231-234
Author(s):  
Gui Qin Jin ◽  
Tao Yan ◽  
Cui Feng Chen
Keyword(s):  
Chemical Composition ◽  
Hot Spot ◽  
Casting Process ◽  
Shrinkage Porosity ◽  
Shrinkage Cavity ◽  
Optimized Design ◽  
Prevention Measures ◽  
Pouring Temperature ◽  
Performance Requirements ◽  
Shrinkage Defects

Shrinkage cavity and shrinkage porosity, often occurring during the production of heavy v-belt pulley roughcast, may lead to the decrease of the pulley performance and further result in casting rejection. Therefore, it is necessary to study the causes and prevention measures of shrinkage defects of the casting. The material of V-belt pulley roughcast at issue is HT250 and it adopts resin sand casting process. With a large amount of practice in workshop and times of revision of the design of foundry technology, we have found that the shrinkage in the hot spot of heavy v-belt pulley roughcast can be reduced or even eliminated to fully meet the performance requirements with a moderate control of pouring temperature and speed, an optimized design of foundry technology, and a strict limitation of chemical composition. This finding will bring illumination to the production process of other heavy pulley roughcast.

Significantly enhanced and precisely modeled thermal conductivity in polyimide nanocomposites with chemically modified graphene via in situ polymerization and electrospinning-hot press technology

2018 ◽  
Vol 6 (12) ◽  
pp. 3004-3015 ◽  
Author(s):  
Yongqiang Guo ◽  
Genjiu Xu ◽  
Xutong Yang ◽  
Kunpeng Ruan ◽  
Tengbo Ma ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
In Situ Polymerization ◽  
Hot Press ◽  
Conductivity Model ◽  
Chemically Modified ◽  
Thermal Conductivity Model ◽  
Modified Graphene ◽  
Thermal Conductivities

Significantly improved thermal conductivities and a more accurate thermal conductivity model were achieved.

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