scholarly journals 3D Modelling of Mass Transfer into Bio-Composite

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2257
Author(s):  
Marouane Kabbej ◽  
Valérie Guillard ◽  
Hélène Angellier-Coussy ◽  
Caroline Wolf ◽  
Nathalie Gontard ◽  
...  
Keyword(s):  
Relative Permeability ◽  
Volume Fraction ◽  
Water Vapor Permeability ◽  
High Volume ◽  
Phase Model ◽  
Vapor Permeability ◽  
Three Dimensional Model ◽  
Two Phase ◽  
Phase Structures ◽  
Three Phase

A three-dimensional model structure that allows considering interphase layer around permeable inclusions is developed to predict water vapor permeability in composite materials made of a matrix Poly(3-HydroxyButyrate-co-3-HydroxyValerate) (PHBV) including Wheat Straw Fiber (WSF) particles. About 500 two-phase structures corresponding to composites of different particles volume fractions (5.14−11.4−19.52 % v/v) generated using experimental particles’ size distribution have permitted to capture all the variability of the experimental material. These structures have served as a basis to create three-phase structures including interphase zone of altered polymer property surrounding each particle. Finite Element Method (FEM) applied on these structures has permitted to calculate the relative permeability (ratio between composite and neat matrix permeability P/Pm). The numerical results of the two-phase model are consistent with the experimental data for volume fraction lower than 11.4 %v/v but the large upturn of the experimental relative permeability for highest volume fraction is not well represented by the two-phase model. Among hypothesis made to explain model’s deviation, the presence of an interphase with its own transfer properties is numerically tested: numerical exploration made with the three-phase model proves that an interphase of 5 µm thick, with diffusivity of Di ≥ 1 × 10−10 m2.s−1, would explain the large upturn of permeability at high volume fraction.

Deposition of Chloride in Two-Phase Flow for the Superheater via Numerical Simulation

2011 ◽  
Vol 354-355 ◽  
pp. 236-239 ◽  
Author(s):  
Song Ying Chen ◽  
Jun Jie Mao
Keyword(s):  
Flue Gas ◽  
Two Phase Flow ◽  
Volume Fraction ◽  
Three Dimensional ◽  
High Volume ◽  
Phase Flow ◽  
Dimensional Model ◽  
Three Dimensional Model ◽  
Two Phase ◽  
Velocity Magnitude

This paper reports the results of a study on the reason for chlorine-induced corrosion in the superheater, the factor of corrsion is caused by the chloride deposit. A three-dimensional model is performed in order to analyse chloride particles deposit in the flue-gas. The use of CFD codes for modeling of two-phase flow, it is important to know whether or not deposition will be present in some sensitive location. The RNG k-ε turbulence model and mixture model are employed in the article. The predicted results show that the volume fraction of particles phase varies along with the flow field. Chloride particles may deposit where the area of high volume fraction. Actually, under the condition of different velocity magnitude, the deposition of chloride particles is existed on the border of the baffle and at the bottom of the vessel.

Transport of organochlorine pesticides in soil columns enhanced by dissolved organic carbon

1997 ◽  
Vol 35 (7) ◽  
pp. 139-145 ◽  
Author(s):  
Jiann-Yuan Ding ◽  
Shian-Chee Wu
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Organochlorine Pesticides ◽  
Transport Model ◽  
Phase Model ◽  
Soil Columns ◽  
Two Phase ◽  
Three Phase ◽  
Phase Transport ◽  
Remediation Of Soil

The objective of this study is to quantify the effects of humic acid solution infiltration on the transport of organochlorine pesticides (OCPs) in soil columns using a three-phase transport model. From experimental results, it is found that the dissolved organic carbon enhances the transport of OCPs in the soil columns. In the OCPs-only column, the concentration profiles of OCPs can be simulated well using a two-phase transport model with numerical method or analytical solution. In the OCPs-DOC column, the migrations of aldrin, DDT and its daughter compounds are faster than those in the OCPs-only column. The simulation with the three-phase model is more accurate than that with the two-phase model. In addition, significant decrease of the fluid pore velocities of the OCPs-DOC column was found. When DOC leachate is applied for remediation of soil or groundwater pollution, the decrease of mean pore velocities will be a crucial affecting factor.

Micromechanical analysis of effective mechanical properties of graphene/ZrO2-hybrid poly (methyl methacrylate) nanocomposites

2021 ◽  
pp. 251659842110388
Author(s):  
Ankit Rathi ◽  
S. I. Kundalwal
Keyword(s):  
Methyl Methacrylate ◽  
Elastic Properties ◽  
Mechanical Performance ◽  
Volume Fraction ◽  
Element Model ◽  
Two Phase ◽  
Effective Elastic Properties ◽  
Poly Methyl Methacrylate ◽  
Three Phase ◽  
Effective Mechanical Properties

In this study, the tensile properties of two-phase and three-phase graphene/ZrO2-hybrid poly (methyl methacrylate) (PMMA) nanocomposites are investigated by developing finite element model using ANSYS. Primarily, the effective elastic properties of two- and three-phase graphene/ZrO2-hybrid PMMA nanocomposites (GRPCs) are estimated by developing mechanics of material (MOM) model. Results indicated that the effective elastic properties of GRPCs increase with an increase in the volume fraction of graphene. Also, the stiffness of GRPCs is increased by 78.12% with increasing in the volume fraction of graphene from 0.1 to 0.5 Vf. The incorporation of an additional ZrO2 interphase significantly improved the mechanical performance of resulting GRPCs.

An Edge Dislocation in a Three-Phase Composite Cylinder Model

1991 ◽  
Vol 58 (1) ◽  
pp. 75-86 ◽  
Author(s):  
H. A. Luo ◽  
Y. Chen
Keyword(s):  
Edge Dislocation ◽  
Stable Equilibrium ◽  
Phase Model ◽  
Composite Cylinder ◽  
Two Phase ◽  
Trapping Mechanism ◽  
Three Phase ◽  
Cylinder Model ◽  
Stable Equilibrium Position ◽  
The Stability

An exact solution is given for the stress field due to an edge dislocation embedded in a three-phase composite cylinder. The force on the dislocation is then derived, from which a set of simple approximate formulae is also suggested. It is shown that, in comparison with the two-phase model adopted by Dundurs and Mura (1964), the three-phase model allows the dislocation to have a stable equilibrium position under much less stringent combinations of the material constants. As a result, the so-called trapping mechanism of dislocations is more likely to take place in the three-phase model. Also, the analysis and calculation show that in the three-phase model the orientation of Burgers vector has only limited influence on the stability of dislocation. This behavior is pronouncedly different from that predicted by the two-phase model.

Relative Permeability Characterization for Water-Alternating-Gas Injection in Oil Reservoirs

SPE Journal ◽  
2016 ◽  
Vol 21 (03) ◽  
pp. 0799-0808 ◽  
Author(s):  
H.. Shahverdi ◽  
M.. Sohrabi
Keyword(s):  
Relative Permeability ◽  
Gas Injection ◽  
Hysteresis Effect ◽  
Oil Reservoirs ◽  
Unsteady State ◽  
Two Phase ◽  
Water Alternating Gas ◽  
Three Phase ◽  
Phase Water ◽  
Wag Injection

Summary Large quantities of oil usually remain in oil reservoirs after conventional waterfloods. A significant part of this remaining oil can still be economically recovered by water-alternating-gas (WAG) injection. WAG injection involves drainage and imbibition processes taking place sequentially; therefore, the numerical simulation of the WAG process requires reliable knowledge of three-phase relative permeability (kr) accounting for cyclic-hysteresis effects. In this study, the results of a series of unsteady-state two-phase displacements and WAG coreflood experiments were used to investigate the behavior of three-phase kr and hysteresis effects in the WAG process. The experiments were performed on two different cores with different characteristics and wettability conditions. An in-house coreflood simulator was developed to obtain three-phase relative permeability values directly from unsteady-state WAG experiments by history matching the measured recovery and differential-pressure profiles. The results show that three-phase gas relative permeability is reduced in consecutive gas-injection cycles and consequently the gas mobility and injectivity drop significantly with successive gas injections during the WAG process, under different rock conditions. The trend of hysteresis in the relative permeabilty of gas (krg) partly contradicts the existing hysteresis models available in the literature. The three-phase water relative permeability (krw) of the water-wet (WW) core does not exhibit considerable hysteresis effect during different water injections, whereas the mixed-wet (MW) core shows slight cyclic hysteresis. This may indicate a slight increase of the water injectivity in the subsequent water injections in the WAG process under MW conditions. Insignificant hysteresis is observed in the oil relative permeability (kro) during different gas-injection cycles for both WW and MW rocks. However, a considerable cyclic-hysteresis effect in kro is observed during water-injection cycles of WAG, which is attributed to the reduction of the residual oil saturation (ROS) during successive water injections. The kro of the WW core exhibits much-more cyclic-hysteresis effect than that of the MW core. No models currently exist in reservoir simulators that can capture the observed cyclic-hysteresis effect in oil relative permeability for the WAG process. Investigation of relative permeability data obtained from these displacement tests at different rock conditions revealed that there is a significant discrepancy between two-phase and three-phase relative permeability of all fluids. This highlights that not only the three-phase relative permeability of the intermediate phase (oil), but also the three-phase kr of the wetting phase (water) and nonwetting phase (gas) are functions of two independent saturations.

An Experimental Investigation of Viscous-Oil Recovery Efficiency as a Function of Voidage-Replacement Ratio

SPE Journal ◽  
2016 ◽  
Vol 21 (04) ◽  
pp. 1236-1253 ◽  
Author(s):  
Tae Wook Kim ◽  
E.. Vittoratos ◽  
A. R. Kovscek
Keyword(s):  
Relative Permeability ◽  
Oil Recovery ◽  
Crude Oils ◽  
Replacement Ratio ◽  
Two Phase ◽  
Foamy Oil ◽  
Three Phase ◽  
Solution Gas Drive ◽  
Gas Drive ◽  
Solution Gas

Summary Recovery processes with a voidage-replacement ratio (VRR) (VRR = injected volume/produced volume) of unity rely solely on viscous forces to displace oil, whereas a VRR of zero relies on solution-gas drive. Activating a solution-gas-drive mechanism in combination with waterflooding with periods of VRR less than unity (VRR < 1) may be optimal for recovery. Laboratory evidence suggests that recovery for VRR < 1 is enhanced by emulsion flow and foamy (i.e., bubbly) crude oil at pressures under bubblepoint for some crude oils. This paper investigates the effect of VRR for two crude oils referred to as A1 (88 cp and 6.2 wt% asphaltene) and A2 (600 cp and 2.5 wt% asphaltene) in a sandpack system (18-in. length and 2-in. diameter). The crude oils are characterized with viscosity, asphaltene fraction, and acid/base numbers. A high-pressure experimental sandpack system (1 darcy and Swi = 0) was used to conduct experiments with VRRs of 1.0, 0.7, and 0 for both oils. During waterflood experiments, we controlled and monitored the rate of fluid injection and production to obtain well-characterized VRR. On the basis of the production ratio of fluids, the gas/oil and /water relative permeabilities were estimated under two-phase-flow conditions. For a VRR of zero, the gas relative permeability of both oils exhibited extremely low values (10−6−10−4) caused by internal gas drive. Waterfloods with VRR < 1 displayed encouraging recovery results. In particular, the final oil recovery with VRR = 0.7 [66.2% original oil in place (OOIP)] is more than 15% greater than that with VRR = 1 (55.6% OOIP) with A1 crude oil. Recovery for A2 with VRR = 0.7 (60.5% OOIP) was identical to the sum of oil recovery for solution-gas drive (19.1% OOIP) plus waterflooding (40.1% OOIP). An in-line viewing cell permitted inspection of produced fluid morphology. For A1 and VRR = 0.7, produced oil was emulsified, and gas was dispersed as bubbles, as expected for a foamy oil. For A2 and VRR < 1, foamy oil was not clearly observed in the viewing cell. In all cases, the water cut of VRR = 1 is clearly greater than that of VRR = 0.7. Finally, three-phase relative permeability was explored on the basis of the experimentally determined two-phase oil/water and liquid/gas relative permeability curves. Well-known algorithms for three-phase relative permeability, however, did not result in good history matches to the experimental data. Numerical simulations matched the experimental recovery vs. production time acceptably after modification of the measured krg and krow relationships. A concave shape for oil relative permeability that is suggestive of emulsified oil in situ was noted for both systems. The degree of agreement with experimental data is sensitive to the details of gas (gas/oil system) and oil (oil/water system) mobility.

scholarly journals Numerical investigation of nanoparticles slip mechanisms impact on the natural convection heat transfer characteristics of nanofluids in an enclosure

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Muritala Alade Amidu ◽  
Yacine Addad ◽  
Mohamed Kamel Riahi ◽  
Eiyad Abu-Nada
Keyword(s):  
Heat Transfer ◽  
Rayleigh Number ◽  
Volume Fraction ◽  
Full Range ◽  
Convection Heat Transfer ◽  
Phase Model ◽  
Brownian Diffusion ◽  
Two Phase ◽  
Great Satisfaction ◽  
Drift Flux

AbstractThis study intends to give qualitative results toward the understanding of different slip mechanisms impact on the natural heat transfer performance of nanofluids. The slip mechanisms considered in this study are Brownian diffusion, thermophoretic diffusion, and sedimentation. This study compares three different Eulerian nanofluid models; Single-phase, two-phase, and a third model that consists of incorporating the three slip mechanisms in a two-phase drift-flux. These slip mechanisms are found to have different impacts depending on the nanoparticle concentration, where this effect ranges from negligible to dominant. It has been reported experimentally in the literature that, with high nanoparticle volume fraction the heat transfer deteriorates. Admittingly, classical nanofluid models are known to underpredict this impairment. To address this discrepancy, this study focuses on the effect of thermophoretic diffusion and sedimentation outcome as these two mechanisms turn out to be influencing players in the resulting heat transfer rate using the two-phase model. In particular, the necessity to account for the sedimentation contribution toward qualitative modeling of the heat transfer is highlighted. To this end, correlations relating the thermophoretic and sedimentation coefficients to the nanofluid concentration and Rayleigh number are proposed in this study. Numerical experiments are presented to show the effectiveness of the proposed two-phase model in approaching the experimental data, for the full range of Rayleigh number in the laminar flow regime and for nanoparticles concentration of (0% to 3%), with great satisfaction.

scholarly journals Development of LDPE Crystallinity in LDPE/Cu Composites

2021 ◽  
Author(s):  
Makki Abdelmouleh ◽  
Ilyes Jedidi
Keyword(s):  
Phase Change Materials ◽  
Research Work ◽  
Orthorhombic Phase ◽  
Copper Particle ◽  
Phase Model ◽  
Spectral Simulation ◽  
Two Phase ◽  
Cu Films ◽  
Three Phase

This chapter summarizes the study of the filler (ie copper) effect on LDPE phasic composition in LDPE/Cu composites prepared in solution. During this research work, a particular effort is focused on the use of DSC under non-standard conditions. Therewith, the presence of copper microparticles has a great effect on the network phase than on the crystalline long-range-order phase of LDPE structure. Furthermore, LDPE phasic composition in absence and presence of copper microparticles is investigated by FTIR spectroscopy followed by a spectral simulation of the band that appeared at 720 cm−1 corresponding to the CH2. Anywise, the two-phase model confirmed that no variation is observed of LDPE phase composition for all copper contents into LDPE/Cu films. However, with the three-phase model the orthorhombic phase fraction was found to be constant compared to the fraction of amorphous and that of network phase were found to increase and decrease respectively with increase in the copper particle load in the film. Overall, the thermal and structural behavior of LDPE in presence of copper particles allows this type to be used as phase change materials (PCMs) by adding a paraffin fraction in the LDPE/Cu composite. An update of the most relevant work carried out in the field of phasic characterization of polyethylene is presented in this chapter.

A Semianalytical Approach for Analysis of Wells Exhibiting Multiphase Transient Linear Flow: Application to Field Data

SPE Journal ◽  
2020 ◽  
Vol 25 (06) ◽  
pp. 3265-3279
Author(s):  
Hamidreza Hamdi ◽  
Hamid Behmanesh ◽  
Christopher R. Clarkson
Keyword(s):  
Numerical Model ◽  
Relative Permeability ◽  
History Matching ◽  
Volatile Oil ◽  
Low Permeability ◽  
Two Phase ◽  
Linear Flow ◽  
Field Case ◽  
Three Phase ◽  
Relative Permeability Curves

Summary Rate-transient analysis (RTA) is a useful reservoir/hydraulic fracture characterization method that can be applied to multifractured horizontal wells (MFHWs) producing from low-permeability (tight) and shale reservoirs. In this paper, we applied a recently developed three-phase RTA technique to the analysis of production data from an MFHW completed in a low-permeability volatile oil reservoir in the Western Canadian Sedimentary Basin. This RTA technique is used to analyze the transient linear flow regime for wells operated under constant flowing bottomhole pressure (BHP) conditions. With this method, the slope of the square-root-of-time plot applied to any of the producing phases can be used to directly calculate the linear flow parameter xfk without defining pseudovariables. The method requires a set of input pressure/volume/temperature (PVT) data and an estimate of two-phase relative permeability curves. For the field case studied herein, the PVT model is constructed by tuning an equation of state (EOS) from a set of PVT experiments, while the relative permeability curves are estimated from numerical model history-matchingresults. The subject well, an MFHW completed in 15 stages, produces oil, water, and gas at a nearly constant (measured downhole) flowing BHP. This well is completed in a low-permeability,near-critical volatile oil system. For this field case, application of the recently proposed RTA method leads to an estimate of xfk that is in close agreement (within 7%) with the results of a numerical model history match performed in parallel. The RTA method also provides pressure–saturation (P–S) relationships for all three phases that are within 2% of those derived from the numerical model. The derived P–S relationships are central to the use of other RTA methods that require calculation of multiphase pseudovariables. The three-phase RTA technique developed herein is a simple-yet-rigorous and accurate alternative to numerical model history matching for estimating xfk when fluid properties and relative permeability data are available.

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