scholarly journals Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2095
Author(s):  
Sunny Skaria ◽  
Kenneth J. Berk
Keyword(s):  
Calcium Phosphate ◽  
Physical Properties ◽  
Bioactive Compound ◽  
Release Profile ◽  
Dental Composite ◽  
Dental Composites ◽  
Attenuated Total Reflectance ◽  
Ion Release ◽  
Total Reflectance ◽  
Surface Precipitation

The aim of this study was to synthesize and characterize a novel methacrylate-functionalized calcium phosphate (MCP) to be used as a bioactive compound for innovative dental composites. The characterization was accomplished by attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The incorporation of MCP as a bioactive filler in esthetic dental composite formulations and the ability of MCP containing dental composites to promote the precipitation of hydroxyapatite (HAp) on the surfaces of those dental composites was explored. The translucency parameter, depth of cure, degree of conversion, ion release profile, and other physical properties of the composites were studied with respect to the amount of MCP added to the composites. Composite with 3 wt.% MCP showed the highest flexural strength and translucency compared to the control composite and composites with 6 wt.% and 20 wt.% MCP. The progress of the surface precipitation of hydroxyapatite on the MCP containing dental composites was studied by systematically increasing the MCP content in the composite and the time of specimen storage in Dulbecco’s phosphate-buffered solution with calcium and magnesium. The results suggested that good bioactivity properties are exhibited by MCP containing composites. A direct correlation between the percentage of MCP in a composite formulation, the amount of time the specimen was stored in PBS, and the deposition of hydroxyapatite on the composite’s surface was observed.

scholarly journals Experimental Dental Composites Containing a Novel Methacrylate-Functionalized Calcium Phosphate Component: Evaluation of Bioactivity and Physical Properties

2021 ◽  
Author(s):  
SUNNY SKARIA ◽  
KENNETH J BERK
Keyword(s):  
Calcium Phosphate ◽  
Physical Properties ◽  
Bioactive Compound ◽  
Dental Composite ◽  
Dental Composites ◽  
Attenuated Total Reflectance ◽  
X Ray Diffraction ◽  
Ion Release ◽  
Surface Precipitation ◽  
Properties Of Composites

The aim of this study was to synthesize and characterize a novel Methacrylate- functionalized Calcium Phosphate (MCP) used as a bioactive compound for innovative dental composites. The characterization was accomplished by Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR), X-Ray Diffraction Analysis (XRDA), Scanning Electron Microscopy (SEM), and EnergyDispersive Spectroscopy (EDS). The incorporation of MCP as a bioactive filler in esthetic dental composite formulations and the ability of MCP containing dental composites to promote precipitation of hydroxyapatite (HAp) on the surfaces of those dental composites was explored. The translucency parameter, depth of cure, degree of conversion, ion release profile, and other physical properties of composites were studied with respect to the amount of MCP added to the composites. Composites containing 3 Wt.%, 6 Wt.%, and 20 Wt.% MCP were evaluated at 7, 14, and 21 days. The progress of surface precipitation of hydroxyapatite on MCP-containing dental composites was studied by systematically increasing the MCP content in the composite and the time of specimen storage in Dulbecco’s phosphate-buffered solution with calcium and magnesium. It was found that there was a direct correlation between the percentage of MCP in a composite formulation, the amount of time the specimen was stored in PBS, and the deposition of hydroxyapatite on the composite’s surface

Mechanical Properties of Machinable Zirconia Dental Composites

2007 ◽  
Vol 336-338 ◽  
pp. 1587-1589
Author(s):  
Wen Xu Li ◽  
Hua Zhao ◽  
Ying Song ◽  
Bin Su ◽  
Fu Ping Wang
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Calcium Phosphate ◽  
Flexural Strength ◽  
Dental Composite ◽  
The Other ◽  
Dental Composites ◽  
Composite Ceramics ◽  
Cad Cam ◽  
The Common

Ca3(PO4)2/ZrO2 dental composite ceramics using for CAD/CAM system were prepared and the effects of weak phases on microstructures and mechanical properties were studied. The results showed that intergranular spreads happened with the increasing Ca3(PO4)2 contents due to the discontinuity of weak interfaces between Zirconia and Calcium phosphate in matrix. So the flexural strength and hardness of the Ca3(PO4)2/ZrO2 composite ceramics were decreased effectively, which improved the machinability of the composites. On the other hand, strong interfaces between Zirconias increased the integrality of the ceramic structures. ZrO2 composite Ceramics with 15% Ca3(PO4)2 were sintered at 1350°C. The flexural strength is 300.44MPa, fracture toughness is 4.36 MPam1/2, and hardness is 6.69 GPa. The cutting exponent of the Ca3(PO4)2/ZrO2 composite ceramics is obviously lower than that of the common commercial Vita Mark II and Dicor MGC ceramics, which shows good mechanical properties and machinability.

scholarly journals Alendronate-Eluting Biphasic Calcium Phosphate (BCP) Scaffolds Stimulate Osteogenic Differentiation

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Sung Eun Kim ◽  
Young-Pil Yun ◽  
Deok-Won Lee ◽  
Eun Young Kang ◽  
Won Jae Jeong ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Osteogenic Differentiation ◽  
Biphasic Calcium Phosphate ◽  
Bone Substitutes ◽  
Calcium Deposition ◽  
Attenuated Total Reflectance ◽  
Total Reflectance ◽  
X Ray ◽  
Stimulation Of

Biphasic calcium phosphate (BCP) scaffolds have been widely used in orthopedic and dental fields as osteoconductive bone substitutes. However, BCP scaffolds are not satisfactory for the stimulation of osteogenic differentiation and maturation. To enhance osteogenic differentiation, we prepared alendronate- (ALN-) eluting BCP scaffolds. The coating of ALN on BCP scaffolds was confirmed by scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). Anin vitrorelease study showed that release of ALN from ALN-eluting BCP scaffolds was sustained for up to 28 days.In vitroresults revealed that MG-63 cells grown on ALN-eluting BCP scaffolds exhibited increased ALP activity and calcium deposition and upregulated gene expression of Runx2, ALP, OCN, and OPN compared with the BCP scaffold alone. Therefore, this study suggests that ALN-eluting BCP scaffolds have the potential to effectively stimulate osteogenic differentiation.

scholarly journals Calcium Chloride Treated Highly Elastane Cotton Fabrics as Antibacterial, Comfortable and Environmentally Friendly Materials

Fibers ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 70
Author(s):  
Nilufer Yildiz Varan ◽  
Yavuz Caydamli
Keyword(s):  
Antibacterial Activity ◽  
Physical Properties ◽  
Calcium Chloride ◽  
Physical Performance ◽  
Environmentally Friendly ◽  
Cotton Fabrics ◽  
Attenuated Total Reflectance ◽  
Total Reflectance ◽  
Good Antibacterial Activity ◽  
Stiffness Handle

In the paper, the results of experiments on high elastane cotton crochet warp knitting fabrics treated with different calcium chloride solutions by the pad-dry-cure method have been reported. The tests for evaluating the antibacterial activity, thermophysiological comfort properties, physical performance of the samples were performed. In addition, the characterization analyses, including SEM, EDX, FTIR-attenuated total reflectance (ATR), and XRD, afforded indications of the good crosslinking of the CaCl2 onto the cotton/elastane samples. At a higher degree of activity, the calcium-chloride-treated fabrics were rated as having good antibacterial activity, being exceptionally breathable, and being comfortable with good physical properties such as stiffness, handle, and whiteness properties.

Mechanical characterization and ion release of bioactive dental composites containing calcium phosphate particles

2018 ◽  
Vol 84 ◽  
pp. 161-167 ◽  
Author(s):  
Livia C. Natale ◽  
Marcela C. Rodrigues ◽  
Yvette Alania ◽  
Marina D.S. Chiari ◽  
Leticia C.C. Boaro ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Mechanical Characterization ◽  
Dental Composites ◽  
Ion Release ◽  
Calcium Phosphate Particles

Light-cured dental composites characterization by Electron Microscopy

1990 ◽  
Vol 48 (4) ◽  
pp. 428-429
Author(s):  
B. M. Culbertson ◽  
M. L. Devinev ◽  
E. C. Kao
Keyword(s):  
Electron Microscopy ◽  
Mechanical Analysis ◽  
Service Performance ◽  
Dental Composite ◽  
Dental Composites ◽  
Neat Resin ◽  
Scanning Calorimetry ◽  
Research Meeting ◽  
Formulation Variables

The service performance of current dental composite materials, such as anterior and posterior restoratives and/or veneer cements, needs to be improved. As part of a comprehensive effort to find ways to improve such materials, we have launched a broad spectrum study of the physicochemical and mechanical properties of photopolymerizable or visible light cured (VLC) dental composites. The commercially available VLC materials being studied are shown in Table 1. A generic or neat resin VLC system is also being characterized by SEM and TEM, to more fully understand formulation variables and their effects on properties.At a recent dental research meeting, we reported on the differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) characterization of the materials in Table 1. It was shown by DSC and DMA that the materials are substantially undercured by commonly used VLC techniques. Post curing in an oral cavity or a dry environment at 37 to 50°C for 7 or more hours substantially enhances the cure of the materials.

The Utilization of Ftir (Fourier Transform Infra-Red) Method Combined with Chemometrics For Authentication of Indonesian Coffee Powder

2017 ◽  
Vol 9 (3) ◽  
Author(s):  
Firmansyah A. ◽  
Winingsih W. ◽  
Soebara Y S
Keyword(s):  
Fourier Transform ◽  
Natural Product ◽  
High Performance ◽  
Principal Component ◽  
Raw Material ◽  
Attenuated Total Reflectance ◽  
Coffee Bean ◽  
Product Analysis ◽  
Total Reflectance ◽  
And Cluster Analysis

Analysis of natural product remain challenging issues for analytical chemist, since natural products are complicated system of mixture. The most popular methods of choice used for quality control of raw material and finished product are high performance liquid chromatography (HPLC), gas chromatography (GC) and mass spectrometry (MS). The utilization of FTIR-ATR (Fourier Transform Infrared-Attenuated Total Reflectance) method in natural product analysis is still limited. This study attempts to expand the use of FTIR spectroscopy in authenticating Indonesian coffee powder.The coffee samples studied were taken from nine regions in Indonesia, namely Aceh Gayo, Flores, Kintamani, Mandheling, Papua, Sidikalang, Toraja, Kerinci and Lampung.The samples in the form of coffee bean from various regions were powdered . The next step conducted was to determine the spectrum using the FTIR-ATR (Attenuated Total Reflectance) using ZnSe crystal of 8000 resolution. Spectrum samples, then, were analyzed using chemometrics. The utilized chemometric model was the principal component analysis (PCA) and cluster analysis (CA). Based on the chemometric analysis, there are similarities between Aceh Gayo coffee with Toraja coffee, Mandailing coffee, Kintamani coffee and Flores coffee. Sidikalang coffee has a similarity to Flores coffee; Papua coffee has a similarity to Sidikalang coffee; Lampung coffee has a similarity to Sidikalang coffee, while Kerinci coffee has a similarity to Papua coffee.

Quality evaluation of tugaksheeree samples by ATR-FTIR spectroscopy using multicomponent analysis

2020 ◽  
Vol 10 ◽  
Author(s):  
Nikunj D. Patel ◽  
Niranjan S. Kanaki
Keyword(s):  
Principal Component Analysis ◽  
Cluster Analysis ◽  
Quality Evaluation ◽  
Principal Component ◽  
Hierarchical Cluster ◽  
Attenuated Total Reflectance ◽  
Chemometric Methods ◽  
Total Reflectance ◽  
Fingerprint Region ◽  
Ftir Technique

Background: Numerous Ayurvedic formulations contains tugaksheeree as key ingredient. Tugaksheereeis the starch gained from the rhizomes of two plants, Curcuma angustifoliaRoxb. (Zingiberaceae) and Marantaarundinacea (MA) Linn. (Marantaceae). Objective: The primary concerns in quality assessment of Tugaksheeree occur due to adulteration or substitution. Method: In current study, Fourier transform infrared (FTIR) technique with attenuated total reflectance (ATR) facility was used to evaluate tugaksheeree samples. Total 10 different samples were studied and transmittance mode was kept to record the spectra devoid of pellets of KBR. Further treatment was given with multi component tools by considering fingerprint region of the spectra. Multivariate analysis was performed by various chemometric methods. Result: Multi component methods like Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA)were used to discriminate the tugaksheeree samples using Minitab software. Conclusion: This method can be used as a tool to differentiate samples of tugaksheeree from its adulterants and substitutes.

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