scholarly journals Printability Study of a Conductive Polyaniline/Acrylic Formulation for 3D Printing

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2068
Author(s):  
Goretti Arias-Ferreiro ◽  
Ana Ares-Pernas ◽  
Aurora Lasagabáster-Latorre ◽  
Nora Aranburu ◽  
Gonzalo Guerrica-Echevarria ◽  
...  
Keyword(s):  
3D Printing ◽  
Low Cost ◽  
Electronic Devices ◽  
Maximum Amount ◽  
Gel Point ◽  
Digital Light Processing ◽  
Conductive Composites ◽  
Printing Quality ◽  
Conductive Polyaniline ◽  
Pure Resin

There is need for developing novel conductive polymers for Digital Light Processing (DLP) 3D printing. In this work, photorheology, in combination with Jacobs working curves, efficaciously predict the printability of polyaniline (PANI)/acrylate formulations with different contents of PANI and photoinitiator. The adjustment of the layer thickness according to cure depth values (Cd) allows printing of most formulations, except those with the highest gel point times determined by photorheology. In the working conditions, the maximum amount of PANI embedded within the resin was ≃3 wt% with a conductivity of 10−5 S cm−1, three orders of magnitude higher than the pure resin. Higher PANI loadings hinder printing quality without improving electrical conductivity. The optimal photoinitiator concentration was found between 6 and 7 wt%. The mechanical properties of the acrylic matrix are maintained in the composites, confirming the viability of these simple, low-cost, conductive composites for applications in flexible electronic devices.

scholarly journals Effects of Filament Diameter Tolerances in Fused Filament Fabrication

2016 ◽  
Vol 2 (1) ◽  
pp. 44-47 ◽  
Author(s):  
Carolina Cardona ◽  
Abigail H Curdes ◽  
Aaron J Isaacs
Keyword(s):  
3D Printing ◽  
Low Cost ◽  
Acrylonitrile Butadiene Styrene ◽  
Fused Filament Fabrication ◽  
Important Indicator ◽  
Extrusion Rate ◽  
Filament Diameter ◽  
Printing Quality ◽  
3D Printers ◽  
And Control

Fused filament fabrication (FFF) is one of the most popular additive manufacturing (3D printing) technologies due to the growing availability of low-cost desktop 3D printers and the relatively low cost of the thermoplastic filament used in the 3D printing process. Commercial filament suppliers, 3D printer manufacturers, and end-users regard filament diameter tolerance as an important indicator of the 3D printing quality. Irregular filament diameter affects the flow rate during the filament extrusion, which causes poor surface quality, extruder jams, irregular gaps in-between individual extrusions, and/or excessive overlap, which eventually results in failed 3D prints. Despite the important role of the diameter consistency in the FFF process, few studies have addressed the required tolerance level to achieve highest 3D printing quality. The objective of this work is to develop the testing methods to measure the filament tolerance and control the filament fabrication process. A pellet-based extruder is utilized to fabricate acrylonitrile butadiene styrene (ABS) filament using a nozzle of 1.75 mm in diameter. Temperature and extrusion rate are controlled parameters. An optical comparator and an array of digital calipers are used to measure the filament diameter. The results demonstrate that it is possible to achieve high diameter consistency and low tolerances (0.01mm) at low extrusion temperature (180 °C) and low extrusion rate (10 in/min). 

scholarly journals High-performance 3D printing of hydrogels by water-dispersible photoinitiator nanoparticles

2016 ◽  
Vol 2 (4) ◽  
pp. e1501381 ◽  
Author(s):  
Amol A. Pawar ◽  
Gabriel Saada ◽  
Ido Cooperstein ◽  
Liraz Larush ◽  
Joshua A. Jackman ◽  
...  
Keyword(s):  
3D Printing ◽  
Aqueous Solutions ◽  
High Performance ◽  
Light Emitting Diode ◽  
Low Cost ◽  
Water Soluble ◽  
Visible Range ◽  
Digital Light Processing ◽  
Uv Curable ◽  
Water Dispersible

In the absence of water-soluble photoinitiators with high absorbance in the ultraviolet (UV)–visible range, rapid three-dimensional (3D) printing of hydrogels for tissue engineering is challenging. A new approach enabling rapid 3D printing of hydrogels in aqueous solutions is presented on the basis of UV-curable inks containing nanoparticles of highly efficient but water-insoluble photoinitiators. The extinction coefficient of the new water-dispersible nanoparticles of 2,4,6-trimethylbenzoyl-diphenylphosphine oxide (TPO) is more than 300 times larger than the best and most used commercially available water-soluble photoinitiator. The TPO nanoparticles absorb significantly in the range from 385 to 420 nm, making them suitable for use in commercially available, low-cost, light-emitting diode–based 3D printers using digital light processing. The polymerization rate at this range is very fast and enables 3D printing that otherwise is impossible to perform without adding solvents. The TPO nanoparticles were prepared by rapid conversion of volatile microemulsions into water-dispersible powder, a process that can be used for a variety of photoinitiators. Such water-dispersible photoinitiator nanoparticles open many opportunities to enable rapid 3D printing of structures prepared in aqueous solutions while bringing environmental advantages by using low-energy curing systems and avoiding the need for solvents.

Proposal of an Innovative Benchmark for the Evaluation of 3D Printing Accuracy for Photopolymers

2022 ◽  
Vol 1048 ◽  
pp. 279-290
Author(s):  
Paolo Minetola ◽  
Vinicius de Freitas Pacheco ◽  
Marcelo Massarani ◽  
Flaviana Calignano ◽  
Giovanni Marchiandi
Keyword(s):  
3D Printing ◽  
Low Cost ◽  
Coordinate Measuring Machine ◽  
Geometric Accuracy ◽  
Digital Light Processing ◽  
Dimensional Measurements ◽  
Measuring Machine ◽  
T Values ◽  
Two Machines ◽  
Better Than

In recent years, the diffusion of additive manufacturing (AM) or 3D printing (3DP) techniques for polymers have been boosted by the expiration of earlier patents from the last century and the development of low-cost machines. Since these technologies become more widespread, there is a need to assess the capability and accuracy of low-cost machines in terms of dimensional and geometric tolerance. To this aim, this work proposes an innovative reference part for benchmarking layerwise processes that involve the curing of photopolymers. The geometry of the part is conceived to include several classical shapes that are easily measurable for defining the part accuracy in terms of ISO IT grades and GD&T values. Two replicas of the reference part were fabricated by stereolithography (SLA) and digital light processing (DLP) using two machines and related proprietary materials by Sharebot Company. The replicas were printed with a layer thickness of 50 μm for the DLP process and 100 μm for the SLA one. The results of dimensional measurements of the replicas, that were carried out using a Coordinate Measuring Machine (CMM), show that the geometric accuracy of the time-consuming DLP process is slightly better than that of stereolithography.

BeamMaker: an open hardware high-resolution digital fabricator for the masses

2014 ◽  
Vol 20 (3) ◽  
pp. 245-255 ◽  
Author(s):  
Ariel Calderon ◽  
James Griffin ◽  
Juan Cristóbal Zagal
Keyword(s):  
Low Cost ◽  
High Surface ◽  
Public Access ◽  
3D Printer ◽  
Digital Light Processing ◽  
Content Type ◽  
High Surface Quality ◽  
Open Hardware ◽  
Printing Quality ◽  
3D Printers

Purpose – The democratization of invention is a long lasting desire for the advancement of society. Having access to education and the means of production appears as the major factors for the implementation of this goal. 3D printing is a revolutionary technology that has the potential to bring digital manufacturing to everyone. However, the rise of personal fabrication requires an increase in printing quality, a reduction on machine cost and an increase in knowledge shared by the open hardware community. The purpose of this paper is to explore the development of a new Open Hardware printer project to address these points. Design/methodology/approach – The authors have designed and constructed a low-cost photopolymer-based 3D printer called BeamMaker. The printer is connected to a host computer and a digital-light-processing projector. This work details the design process and how improvements were implemented to reach good printing quality. The authors provide public access to the instructions, software, source code, parts list, user manual and STL and CAD files. Findings – The BeamMaker printer can build objects with a high surface quality that is comparable to the quality obtained by industrial photopolymer-based 3D printers. When testing the ability to print a sample cylinder, the printer shows higher accuracy when compared to other personal 3D printers. These findings are encouraging considering the low cost of the system. Research limitations/implications – The printing failure rate of the system has not been measured to date. The system requires some improvements to produce large objects. Practical implications – The printer cost is just USD380. This is five to eight times less expensive than popular personal 3D printers available today. The cost is 30 times less expensive than a personal photopolymer 3D printer produced by a main commercial company and yet producing results of similar quality. The authors expect good avenues for collaboration from the open-source community to continue improving these systems. Social implications – The high cost of current personal 3D printers prevents users from developing countries from entering into the open hardware trend. A dramatic reduction in printer cost such as that explored in this work might contribute to the real democratization of personal fabrication. Originality/value – The authors report on the status of three other photopolymer-based personal 3D printer projects. To the best of the authors' knowledge, BeamMaker is the first fully open hardware 3D printer project which uses this technology.

Functional inks and extrusion-based 3D printing of 2D materials: a review of current research and applications

Nanoscale ◽  
2020 ◽  
Vol 12 (37) ◽  
pp. 19007-19042 ◽  
Author(s):  
Kamrul Hassan ◽  
Md Julker Nine ◽  
Tran Thanh Tung ◽  
Nathan Stanley ◽  
Pei Lay Yap ◽  
...  
Keyword(s):  
3D Printing ◽  
High Throughput ◽  
2D Materials ◽  
Low Cost ◽  
Electronic Devices ◽  
Next Generation ◽  
Disruptive Technologies

Graphene and related 2D materials offer an ideal platform for next generation disruptive technologies and in particular the potential to produce printed electronic devices with low cost and high throughput.

scholarly journals Microstructured Surface Plasmon Resonance Sensor Based on Inkjet 3D Printing Using Photocurable Resins with Tailored Refractive Index

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2518
Author(s):  
Nunzio Cennamo ◽  
Lorena Saitta ◽  
Claudio Tosto ◽  
Francesco Arcadio ◽  
Luigi Zeni ◽  
...  
Keyword(s):  
Surface Plasmon Resonance ◽  
3D Printing ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Optical Sensor ◽  
Low Cost ◽  
3D Print ◽  
Spr Sensor ◽  
Resonance Sensor ◽  
3D Printed

In this work, a novel approach to realize a plasmonic sensor is presented. The proposed optical sensor device is designed, manufactured, and experimentally tested. Two photo-curable resins are used to 3D print a surface plasmon resonance (SPR) sensor. Both numerical and experimental analyses are presented in the paper. The numerical and experimental results confirm that the 3D printed SPR sensor presents performances, in term of figure of merit (FOM), very similar to other SPR sensors made using plastic optical fibers (POFs). For the 3D printed sensor, the measured FOM is 13.6 versus 13.4 for the SPR-POF configuration. The cost analysis shows that the 3D printed SPR sensor can be manufactured at low cost (∼15 €) that is competitive with traditional sensors. The approach presented here allows to realize an innovative SPR sensor showing low-cost, 3D-printing manufacturing free design and the feasibility to be integrated with other optical devices on the same plastic planar support, thus opening undisclosed future for the optical sensor systems.

scholarly journals Rapid fabrication of MOF-based mixed matrix membranes through digital light processing

2021 ◽  
Author(s):  
Alexey Pustovarenko ◽  
Beatriz Seoane ◽  
Edy Abou-Hamad ◽  
Helen E King ◽  
Bert Weckhuysen ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
3D Printing ◽  
Processing Speed ◽  
Mixed Matrix Membranes ◽  
Scientific Interest ◽  
Mixed Matrix ◽  
Digital Light Processing ◽  
Additive Manufacturing Technology ◽  
Rapid Fabrication ◽  
Manufacturing Methods

3D printing, also known as additive manufacturing technology, has greatly expanded across multiple sectors of technology replacing classical manufacturing methods by combining processing speed and high precision. The scientific interest...

scholarly journals Fabrication and Compressive Behavior of a Micro-Lattice Composite by High Resolution DLP Stereolithography

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 785
Author(s):  
Chow Shing Shin ◽  
Yu Chia Chang
Keyword(s):  
High Resolution ◽  
Lattice Structure ◽  
Low Cost ◽  
Hierarchical Structures ◽  
Dip Coating ◽  
Unit Cell ◽  
Digital Light Processing ◽  
Unit Cell Size ◽  
Wide Range ◽  
And Performance

Lattice structures are superior to stochastic foams in mechanical properties and are finding increasing applications. Their properties can be tailored in a wide range through adjusting the design and dimensions of the unit cell, changing the constituent materials as well as forming into hierarchical structures. In order to achieve more levels of hierarchy, the dimensions of the fundamental lattice have to be small enough. Although lattice size of several microns can be fabricated using the two-photon polymerization technique, sophisticated and costly equipment is required. To balance cost and performance, a low-cost high resolution micro-stereolithographic system has been developed in this work based on a commercial digital light processing (DLP) projector. Unit cell lengths as small as 100 μm have been successfully fabricated. Decreasing the unit cell size from 150 to 100 μm increased the compressive stiffness by 26%. Different pretreatments to facilitate the electroless plating of nickel on the lattice structure have been attempted. A pretreatment of dip coating in a graphene suspension is the most successful and increased the strength and stiffness by 5.3 and 3.6 times, respectively. Even a very light and incomplete nickel plating in the interior has increase the structural stiffness and strength by more than twofold.

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