scholarly journals Multi-Stressed Nano and Micro-Silica/Silicone Rubber Composites with Improved Dielectric and High-Voltage Insulation Properties

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1400
Author(s):  
Faiza Faiza ◽  
Abraiz Khattak ◽  
Aqeel Ur Rehman ◽  
Asghar Ali ◽  
Azhar Mahmood ◽  
...  

The scope of silicone rubber (SiR) is confined due to the deprivation of its dielectric propertiesupon exposure to various ambient stresses. The aim of this research is to develop silicone rubber-based composites by employing inorganic oxide fillers for improved dielectric and high voltage insulation properties for widening its scope in the field of electrical appliances. This study reports the preparation of different composites of silicone rubber with varying concentrations of micro and nano-silica fillers. The dielectric propertytrends of these as-prepared neat and impregnated samples were examined via an indigenously developed weathering chamber capable of applying multiple stresses of acid rain, heat, humidity, UVA radiation, and salt fog. Dielectric constant values were measured before and after applying stresses. Upon applying stresses, a periodic decline in dielectric constant was observed. Improved dielectric properties were obtained by adding micro and nano-silica as fillers. A nano silica-incorporated silicone rubber product exhibited good potential for dual applications as dielectric and high voltage insulation.

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3567
Author(s):  
Faiza Faiza ◽  
Abraiz Khattak ◽  
Safi Ullah Butt ◽  
Kashif Imran ◽  
Abasin Ulasyar ◽  
...  

Silicone rubber is a promising insulating material that has been performing well for different insulating and dielectric applications. However, in outdoor applications, environmental stresses cause structural and surface degradations that diminish its insulating properties. This effect of degradation can be reduced with the addition of a suitable filler to the polymer chains. For the investigation of structural changes and hydrophobicity four different systems were fabricated, including neat silicone rubber, a micro composite (with 15% micro-silica filler), and nanocomposites (with 2.5% and 5% nanosilica filler) by subjecting them to various hydrothermal conditions. In general, remarkable results were obtained by the addition of fillers. However, nanocomposites showed the best resistance against the applied stresses. In comparison to neat silicone rubber, the stability of the structure and hydrophobic behavior was better for micro-silica, which was further enhanced in the case of nanocomposites. The inclusion of 5% nanosilica showed the best results before and after applying aging conditions.


Author(s):  
Nurbahirah Norddin ◽  
Intan Mastura Saadon ◽  
Najwa Kamarudin ◽  
Norain Rahim ◽  
Jeefferie bin Abd Razak

<span>This paper is about preparation of silicone rubber (SiR) samples with different filler for high-voltage insulation purpose. The fillers used were silica from waste glass, calcium carbonate from cockle shell, silica/calcium carbonate and wollastonite. All the fillers were crushed into powder and undergo internal mixer and hot press as a material preparation. It was expected that the combination of filler with silicone rubber would give better result when experiencing ageing process. The direct current (DC) inclined plane test was used to investigate the tracking and erosion on silicone rubber composites. The tracking length was observed between the top and bottom electrode. Comparison would then be made between the silicone rubbers with different fillers based on the result obtained from the experiment.</span>


2009 ◽  
Vol 36 (9) ◽  
pp. 33-35
Author(s):  
S.E. Shakhovets ◽  
S.F. Rosinkevich ◽  
B.L. Smirnov ◽  
O.O. Nikolaev

Author(s):  
Rafal Anyszka ◽  
Xiaozhen He ◽  
Amirhossein Mahtabani ◽  
Wilma K Dierkes ◽  
Anke Blume

In this study an effective surface functionalization of fumed nano-silica for dielectric insulation composites is developed. A three step modification procedure was applied: 1. Silanization of the silica surface with (3-glycidoxypropyl)trimethoxysilane (GOPTMS); 2. Grafting of an acrylonitrile-butadiene telechelic oligomer terminated with two carboxylic acid groups (o-NBR); 3. Hydrogenation of the unsaturated polybutadiene segments for better compatibilization with the saturated polyolefin matrices and for higher dielectric performance.The deposition of the coupling system was monitored by thermogravimetric analysis (TGA) revealing 6.4 wt. % of GOPTMS and 13.6 wt. % of o-NBR bond to the silica, resulting in an exceptionally high total deposition (20.0 wt. %). The o-NBR grafting was analyzed qualitatively by Fourier transform infrared spectroscopy (FTIR) showing successful deposition of o-NBR and effective hydrogenation.The silica modified according to this procedure is a promising functional nano-filler for high-voltage insulation composites allowing improved dispersion and distribution in polyolefine matrices and therefore enhancing their electrical properties.


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