scholarly journals Water-Borne ZnO/Acrylic Nanocoating: Fabrication, Characterization, and Properties

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 717
Author(s):  
Tien Viet Vu ◽  
Thien Vuong Nguyen ◽  
Mohammad Tabish ◽  
Sehrish Ibrahim ◽  
Thi Huong Thuy Hoang ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Composite Coatings ◽  
Total Solid ◽  
Coating Properties ◽  
Acrylic Polymer ◽  
Nano Zno ◽  
Zno Particles ◽  
Acrylic Coatings ◽  
Self Cleaning ◽  
Water Borne

This work aims to explore how ZnO nanoparticles enhance the mechanical, photoaging, and self cleaning properties of water borne acrylic coating. Micro/nano ZnO particles (at 2 wt.% of total solid resin) were dispersed into the acrylic polymer matrices using ultrasonication to understand the effect of the size of the coating properties. The effect of ZnO particles on the properties of composite coatings (25 µm of thick) have been evaluated through various tests, such as abrasion measurement, ultraviolet/condensation (UV/CON) weathering aging, and methylene blue self cleaning. Experimental data indicated that the incorporation of ZnO particles enhanced both abrasion resistance and methylene blue removal efficiency of the water borne acrylic coatings, with nano ZnO particles being the best. However, the weathering degradation of nanocomposite coatings was more severe as compared to the coating with micro ZnO (at the same ZnO content).

Amelioration of anticorrosion and hydrophobic properties of epoxy/PDMS composite coatings containing nano ZnO particles

2016 ◽  
Vol 92 ◽  
pp. 54-65 ◽  
Author(s):  
Sh. Ammar ◽  
K. Ramesh ◽  
B. Vengadaesvaran ◽  
S. Ramesh ◽  
A.K. Arof
Keyword(s):  
Composite Coatings ◽  
Hydrophobic Properties ◽  
Nano Zno ◽  
Zno Particles

Comparative Characterization of Different Samples Containing Nano-ZnO Particles with Applicability in Topical Therapies

2019 ◽  
Vol 56 (3) ◽  
pp. 652-656
Author(s):  
Raul Chioibas ◽  
Florin Borcan ◽  
Ovidiu Mederle ◽  
Dana Stoian ◽  
Codruta Marinela Soica
Keyword(s):  
Synthesis Method ◽  
Pharmaceutical Preparations ◽  
Ultrasound Treatment ◽  
Heating Process ◽  
White Pigment ◽  
Nano Zno ◽  
Zno Particles ◽  
Repeated Freezing ◽  
Skin Healing

Zinc oxide (ZnO) is an inorganic compound used for its antiseptic and skin healing properties. It is an excellent protective filter against UV radiation and it can be used as white pigment in pharmaceutical preparations. In this study, nano-ZnO particles were obtained by ultrasound treatment, and respectively by repeated freezing/heating process. The influence of synthesis method and of ultrasound generator parameters on the particles size and stability was observed. The results reveal that were obtained samples with a very good stability and sizes between 15 and 96 nm. It was found that synthesis based on ultrasound treatment lead to the formation of nanoparticles with lower sizes.

scholarly journals Self-Cleaning Polyester Fabric Prepared with TiOF2 and Hexadecyltrimethoxysilane

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 387
Author(s):  
Euigyung Jeong ◽  
Heeju Woo ◽  
Yejin Moon ◽  
Dong Yun Lee ◽  
Minjung Jung ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Contact Angle ◽  
Treatment Method ◽  
Polyester Fabric ◽  
Anatase Tio2 ◽  
The Self ◽  
Water Contact ◽  
Direct Fluorination ◽  
Tomato Ketchup ◽  
Self Cleaning

In this study, self-cleaning polyester (PET) fabrics were prepared using TiOF2 and hexadecyltrimethoxysilane(HDS) treatment. TiOF2 was synthesized via direct fluorination of a precursor TiO2 at various reaction temperatures. The prepared PET fabrics had superior photocatalytic self-cleaning properties compared with anatase TiO2/HDS-treated PET fabrics under UV and sunlight with 98% decomposition of methylene blue. TiOF2/HDS-treated PET fabrics also had superior superhydrophobic self-cleaning properties compared with anatase TiO2/HDS-treated PET fabrics with a 161° water contact angle and 6° roll-off angle. After the self-cleaning tests of the non-dyed TiOF2/HDS-treated PET fabrics, we prepared dyed TiOF2/HDS-treated PET fabrics to test practical aspects of the treatment method. These PET fabrics were barely stained by tomato ketchup; even when stained, they could be self-cleaned within 4 h. These results suggest that practical self-cleaning PET fabrics with superhydrophobicity and photocatalytic degradation could be prepared using TiOF2/HDS-treatment.

scholarly journals Design and Performance of Novel Self-Cleaning g-C3N4/PMMA/PUR Membranes

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 850 ◽  
Author(s):  
Ladislav Svoboda ◽  
Nadia Licciardello ◽  
Richard Dvorský ◽  
Jiří Bednář ◽  
Jiří Henych ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Thin Layers ◽  
Photocatalytic Reaction ◽  
Potential Toxicity ◽  
Material Loss ◽  
Contaminant Control ◽  
Biological Contaminant ◽  
Self Cleaning ◽  
And Performance ◽  
Photocatalytic Applications

In the majority of photocatalytic applications, the photocatalyst is dispersed as a suspension of nanoparticles. The suspension provides a higher surface for the photocatalytic reaction in respect to immobilized photocatalysts. However, this implies that recovery of the particles by filtration or centrifugation is needed to collect and regenerate the photocatalyst. This complicates the regeneration process and, at the same time, leads to material loss and potential toxicity. In this work, a new nanofibrous membrane, g-C3N4/PMMA/PUR, was prepared by the fixation of exfoliated g-C3N4 to polyurethane nanofibers using thin layers of poly(methyl methacrylate) (PMMA). The optimal amount of PMMA was determined by measuring the adsorption and photocatalytic properties of g-C3N4/PMMA/PUR membranes (with a different PMMA content) in an aqueous solution of methylene blue. It was found that the prepared membranes were able to effectively adsorb and decompose methylene blue. On top of that, the membranes evinced a self-cleaning behavior, showing no coloration on their surfaces after contact with methylene blue, unlike in the case of unmodified fabric. After further treatment with H2O2, no decrease in photocatalytic activity was observed, indicating that the prepared membrane can also be easily regenerated. This study promises possibilities for the production of photocatalytic membranes and fabrics for both chemical and biological contaminant control.

Preparation and Co (II) Removal of ZnO/Poly-Piperazineamide Nanofiltration Membranes

2017 ◽  
Author(s):  
Xiaoguang Zhang ◽  
Xuexing Chen ◽  
Qingchun Chen ◽  
Zhaolong Deng ◽  
Yan Liu ◽  
...  
Keyword(s):  
Reaction Time ◽  
Monomer Concentration ◽  
Attenuated Total Reflection ◽  
Radioactive Nuclide ◽  
Separation Performance ◽  
Separation Mechanism ◽  
Nanofiltration Membranes ◽  
Terephthaloyl Chloride ◽  
Nano Zno ◽  
Zno Particles

A series of nanofiltration membranes were prepared by interfacial polymerization of piperazine and terephthaloyl chloride on the surface of polyacrylonitrile (PAN) ultrafiltration membranes. ZnO nanoparticles were incorporated in the active separation layer to modify the performances of the membranes. The preparation conditions as the monomer concentration, dosage of nano-ZnO particles and the reaction time on removal of a simulated radioactive nuclide Co (II) were investigated. Fourier transform infrared in attenuated total reflection mode verified the formation of polyamide on the PAN ultrafiltration membrane. The scanning electron microscope images showed that the nano-ZnO particles can homogeneously fixed on the membrane surface. The retention of Co (II) increased with increasing the dosage of nano-ZnO in the range of 0∼0.03 g. Further adding more nano-ZnO, the rejection rate of Co (II) first decreased and then increased. The concentration of piperazine and terephthaloyl chloride showed similar effect on removal of Co (II) ion. 5 minutes polymerization time was sufficient to form an active separation layer on the substrate membrane which changed the separation mechanism from ultrafiltration to nanofiltration. The separation performance of NF3 prepared by the following conditions was optimum: 0.03g nano-ZnO, 0.6 wt% piperazine, 0.5 wt% terephthaloyl chloride, and the reaction time was 15 min. The rejection rates of 1000 mg/L Na2SO4 and Co2+ in CoCl2 solution were 90% and 75% respectively. The Co (II) removal rate can be increased to nearly 90% by using ethylenediaminetetraacetic acid disodium salt. Increasing the operation pressure or the feeding concentration of Co (II) can also improve the performances of the membranes in this experiment.

scholarly journals Fabrication of Superhydrophobic AA5052 Aluminum Alloy Surface with Improved Corrosion Resistance and Self Cleaning Property

Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 390 ◽  
Author(s):  
Qian Zhao ◽  
Tiantian Tang ◽  
Fang Wang
Keyword(s):  
Contact Angle ◽  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Materials Science ◽  
Composite Coatings ◽  
Alloy Surface ◽  
Corrosion Resistant ◽  
Self Cleaning ◽  
Aa5052 Aluminum Alloy ◽  
Aluminum Alloy Surface

The development of a self-cleaning and corrosion resistant superhydrophobic coating for aluminum alloy surfaces that is durable in aggressive conditions has attracted great interest in materials science. In the present study, a superphydrophobic film was fabricated on an AA5052 aluminum alloy surface by the electrodeposition of Ni–Co alloy coating, followed by modification with 6-(N-allyl-1,1,2,2-tetrahydro-perfluorodecyl) amino-1,3,5-triazine-2,4-dithiol monosodium (AF17N). The surface morphology and characteristics of the composite coatings were investigated by means of scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), atomic force microscope (AFM) and contact angle (CA). The corrosion resistance of the coatings was assessed by electrochemical tests. The results showed that the surface exhibited excellent superhydrophobicity and self-cleaning performance with a contact angle maintained at 160° after exposed to the atmosphere for 240 days. Moreover, the superhydrophobic coatings significantly improved the corrosion resistant performance of AA5052 aluminum alloy substrate in 3.5 wt.% NaCl solution.

Synthesis and Property of Water Borne Polyurethane/Modified Nano-ZnO Composites Packaging Membranes

2013 ◽  
Vol 469 ◽  
pp. 167-170 ◽  
Author(s):  
Xin Li ◽  
Shu Cai Li ◽  
Li Qiang Huang
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Mechanical Testing ◽  
Propionic Acid ◽  
Nano Zno ◽  
Phase Property ◽  
Dimethylol Propionic Acid ◽  
Scanning Electron ◽  
Water Borne

Water borne polyurethane /modified nano-ZnO composites packaging membranes were synthesized from modified nano-ZnO, polybutyleneadipate glycol (PBA), polycaprolactone (PCL) isophorne diisocyanate (IPDI), dimethylol propionic acid (DMPA), ethylenediamine(EDA) by self-emulsified method. The phase property, mechanical, antibacterial and anti-ultraviolet properties of the composites packaging membranes influenced by the modified nano-ZnO content were studied by scanning electron microscopy (SEM), mechanical testing, and antibacterial testing. And the relative results were analysed.

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