scholarly journals Glycerol Assisted Pretreatment of Lignocellulose Wheat Straw Materials as a Promising Approach for Fabrication of Sustainable Fibrous Filler for Biocomposites

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 388
Author(s):  
Hamayoun Mahmood ◽  
Saqib Mehmood ◽  
Ahmad Shakeel ◽  
Tanveer Iqbal ◽  
Mohsin Ali Kazmi ◽  
...  
Keyword(s):  
Flexural Strength ◽  
Wheat Straw ◽  
Raw Materials ◽  
Agricultural Waste ◽  
Hot Water ◽  
Raw Material ◽  
Dilute Acid ◽  
Material Source ◽  
Thermal Stability Of ◽  
Composite Samples

Glycerol pretreatment is a promising method for the environmentally-friendly transformation of lignocellulosic materials into sustainable cellulose-rich raw materials (i.e., biopolymer) to fabricate biocomposites. Here, a comparison of aqueous acidified glycerol (AAG) pretreatment of wheat straw (WS) with alkaline, hot water, and dilute acid pretreatments on the thermal and mechanical characteristics of their fabricated composite board is presented. A comparison of total energy expenditure during WS pretreatment with AAG and other solutions was estimated and a comparative influence of AAG processing on lignocellulosic constituents and thermal stability of WS fiber was studied. Results imply that AAG pretreatment was superior in generating cellulose-rich fiber (CRF) as compared to other pretreatments and enhanced the cellulose contents by 90% compared to raw WS fiber. Flexural strength of acidic (40.50 MPa) and hot water treated WS composite (38.71 MPa) was higher compared to the value of 33.57 MPa for untreated composite, but AAG-treated composites exhibited lower values of flexural strength (22.22 MPa) compared to untreated composite samples. Conversely, AAG pretreatment consumed about 56% lesser energy for each kg of WS processed as compared to other pretreatments. These findings recognize that glycerol pretreatment could be a clean and new pretreatment strategy to convert agricultural waste into high-quality CRF as a sustainable raw material source for engineered biocomposite panels.

scholarly journals WOOD COMPONENTS AS SOURCES OF PENTO-CONTAINING RAW MATERIALS FOR SYNTHESIS OF USEFUL COMPOUNDS, PRODUCTS AND REAGENTS

2021 ◽  
Vol 64 (3) ◽  
pp. 107-115
Author(s):  
Irina A. Chetvertneva ◽  
Oleg Kh. Karimov ◽  
Galina A. Teptereva ◽  
Natalia S. Tivas ◽  
Eldar M. Movsumzade ◽  
...  
Keyword(s):  
Raw Materials ◽  
Condensation Reaction ◽  
Agricultural Waste ◽  
Monomer Unit ◽  
Paper Industry ◽  
Raw Material ◽  
Chemical Transformations ◽  
Covalent Bonds ◽  
Industry Waste ◽  
Wood Processing

The paper considers the main components and products of wood processing, agricultural waste, pulp and paper industry waste and qualifies them as sources of pentose-containing resource-renewable domestic raw materials. The article describes in detail the structural components of wood as a natural polymer, which contains aromatic and carbohydrate parts. It is noted that these poly-mers are promising as raw materials for the production of useful chemical products. The role of lignin, cellolose and hemicellulose in the design of mechanical and structural properties of wood is considered. The article considers the features of the sulfonation reactions of the lignin monomer unit depending on the pH of the medium: acidic, neutral and alkaline. There are three main reac-tions that occur simultaneously with lignin in the process of wood delignification during sulfite cooking, such as the sulfonation reaction, the hydrolytic destruction reaction, and the condensation reaction. It is shown that the lignin-hemicellulose matrix contains three types of interconnected mesh structures: the lignin itself; a network of covalent bonds of lignin with hemicelluloses, and a network whose structure is obtained due to the hydrogen bond and the forces of the physical inter-action of lignin and hemicelluloses. The features of chemical transformations of the monomeric aromatic link of lignosulfonate – phenylpropane unit in the processes of wood delignification, the main chemical reactions of wood raw material delignification under the conditions of sulfite and neutral-sulfite brews are shown. The method of quantitative determination of monosaccharides in the composition of the carbohydrate part is proposed.

Optimal Design and Techno-Economic Analysis for Corncob Particles Briquettes: A Literature Review of the Utilization of Agricultural Waste and Analysis Calculation

2021 ◽  
Author(s):  
Asep Bayu Dani Nandiyanto ◽  
Nissa Nur Azizah ◽  
Gabriela Chelvina Santiuly Girsang
Keyword(s):  
Optimal Design ◽  
Literature Review ◽  
Economic Analysis ◽  
Large Scale ◽  
Net Present Value ◽  
Raw Materials ◽  
Agricultural Waste ◽  
Raw Material ◽  
Variable Cost ◽  
Scale Production

Corncob is usually disposed of directly as waste, creating problems in the environment, while it can be converted into valuable materials. This research aimed to evaluate the literature review on briquette production from agricultural waste (using non-binder and cold press with a binder) and the current works on techno-economic analysis, to propose an optimal design for the production of briquette from corncob waste, and to perform a techno-economic analysis based on the selected optimal processing method. The engineering perspective based on stoichiometry and mass balance showed the potential corncob briquette manufacture in both home and large scales due to the possible use of inexpensive and commercially available equipment and raw materials. The economic perspective [based on several economic evaluation factors (i.e., gross profit margin, payback period, break-even point, cumulative net present value, return of investment, internal rate return, and profitability index) under ideal and non-ideal conditions by considering internal (i.e., sales, raw materials, utilities, and variable cost) and external aspects (i.e., tax)] confirmed the prospective development of the project in the large-scale production with a lifetime of more than 18 years. The main issue in the project is the raw material (i.e. tapioca flour), giving the most impact on the project’s feasibility. Even in severe conditions, the project is feasible. The great endurance was also confirmed in the case of a higher tax rate. This study demonstrates the importance of producing corncob-based briquettes for improving the economic value and giving alternatives for problem solvers in the utilization of agricultural waste.

scholarly journals THERMAL STABILITY OF Pinus oocarpa AND MAIZE COB PARTICLEBOARDS

2015 ◽  
Vol 39 (4) ◽  
pp. 348-354 ◽  
Author(s):  
Mário Vanoli Scatolino ◽  
Thiago de Paula Protásio ◽  
Rafael Farinassi Mendes ◽  
Lourival Marin Mendes
Keyword(s):  
Thermal Stability ◽  
Agricultural Waste ◽  
Urea Formaldehyde ◽  
Curve Analysis ◽  
Raw Material ◽  
Waste Materials ◽  
Pressing Cycle ◽  
Pinus Oocarpa ◽  
Maize Cob ◽  
Thermal Stability Of

Agricultural waste materials are generated in large quantities in Brazil. These can accumulate and cause serious environmental problems. One of the most commonly generated wastes in the brazilian agricultural culture is the maize cob. Being lignocellulosic in nature, the maize cob can find use as the raw material in the production of particleboards mainly concerned with furniture making. Therefore, studies regarding its thermal stability and fire resistance would be interesting. The aim of this study was to evaluate the combustibility and thermal stability of the particleboards produced from maize cob and Pinus oocarpa wood. The percentages in which maize cob was associated with Pinus oocarpa were 0%, 25%, 50%, 75% and 100%. The panels were produced using 8% urea-formaldehyde and 1% paraffin. The pressing cycle parameters included: temperature 150 °C, pressure of 3.92 MPa during 10 min. The combustibility curve analysis showed that the panels containing 25% content of maize cob had higher resistance to combustion. In general, the thermal stability decreased as the wood substitution by maize cob increased.

scholarly journals Alpian, Yanciluk, dan Wahyu Supriyati

2020 ◽  
Vol 13 (02) ◽  
pp. 22-31
Author(s):  
Agrienvi
Keyword(s):  
Energy Demand ◽  
Alternative Energy ◽  
Raw Materials ◽  
Agricultural Waste ◽  
Economic Value ◽  
Forest Products ◽  
Raw Material ◽  
Wood Pellets ◽  
Industry Waste ◽  
Simple Technology

Energy demand increase follow to population growth factors, high exploration costs, rising world oil prices andthe difficulty of finding sources of oil reserves. These factors cause the governments of several countries toimmediately produce alternative energy that is renewable and environmentally friendly. Wood pellets are analternative energy source. The availability of raw materials is very easy to obtain. Raw materials for wood pelletsfrom the exploitation waste such as logging residues, branches and twigs, wood industry waste such as scraps,sawdust and bark, agricultural waste such as straw and husks. Waste that is developed into a product will produce ahigher economic value. Making pellets from wood waste is an alternative energy material for meeting people's energyneeds. The opportunity to develop wood pellets as fuel is wide open because of the vast potential of forests inIndonesia and the large amount of waste from forest products, both from timber industry waste and exploitationwaste. Equipment, raw materials and the process of making pellets in a simple manner need to be socialized to thepublic so that they can be applied especially for the utilization of potential waste that can be used as raw material formaking pellets.Keywords : wood pellets, waste, simple technology, renewable energy

scholarly journals Technology of Dvaravati Pottery: A View from Petrographic Analysis.

2012 ◽  
Vol 31 ◽  
pp. 4 ◽  
Author(s):  
Duangkamol Aussavamas
Keyword(s):  
Raw Materials ◽  
Distribution Patterns ◽  
Raw Material ◽  
Archaeological Sites ◽  
Petrographic Analysis ◽  
Material Distribution ◽  
Material Source ◽  
Period Analysis ◽  
Production Techniques ◽  
Central Thailand

This study focuses on the examination of aspects of the carinated pottery of the Dvaravati period. This type of pottery is one of the most prominent types found in a large number of Dvaravati sites in Thailand. Samples used for this study were collected from excavations at archaeological sites located in several regions of Thailand including Northern, Northeastern and Central Thailand. The carinated potteries were analyzed using petrographic analysis. The objective of this work was to examine the pottery fabric. This method is used to establish sources of raw materials, and whether production techniques, decorations, and firing temperature show patterns associated with the raw material source distributions. It is also possible to reconstruct the production technology of the vessels. Knowing the source of raw materials (source of clay and temper) and understanding the patterns of manufacturing and decorative processes help better understand material distribution patterns of the Dvaravati period. Analysis shows that Dvaravati earthenware pottery raw materials include both primary and secondary clays, and that temper used was both organic matter (rice chaff) and grogs (fired clay mixed with iron oxide). Evidence for wheel-thrown production was associated with all decoration styles, and finishing techniques included plain, polishing, incising, cord marking, red slip and black burnishing. The firing temperatures were as low as 400-550° C. These samples indicate there was general homogeneity over a wide area, but also the presence of regional groups of pottery. This suggests the widespread circulation of pottery styles among various production centers during the Dvaravati period.

scholarly journals Production of briquettes from Indonesia agricultural biomass waste by using pyrolysis process and comparing the characteristics

Eksergi ◽  
2021 ◽  
Vol 18 (1) ◽  
pp. 13
Author(s):  
Sri Wahyu Murni ◽  
Tutik Muji Setyoningrum ◽  
Muhamad Maulana Azimatun Nur
Keyword(s):  
Raw Materials ◽  
Agricultural Waste ◽  
Calorific Value ◽  
Matter Content ◽  
Raw Material ◽  
Cellulose Content ◽  
Pressing Pressure ◽  
Pyrolysis Process ◽  
Biomass Waste ◽  
Stem Wood

Indonesia biomass waste is a potential feedstock as a source of renewable energy since it can be converted into carcoal briquettes. However, the production of the briquettes using pyrolysis process using the agricultural waste was lacking. In this research, briquette was made from palm shells,  corncob and soybean stem wood due to its high availability and have high cellulose content. The purpose of this research was to produce briquettes from three kind of raw materials by employing pyrolysis process and compared the characteristics. The briquette was made from different type of raw materials (palm shells, corncob and soybean stem) and  the concentration of binder : 3-7 %. Pyrolysis was done at  500 °C, and 100 kg / cm2 of pressing pressure. Results showed that, the best charcoal briquette was achieved from palm shells by using 5% binder, which resulted 4,1% moisture content, 3.4% ash content,  15% volatile matter content, 77.5% carbon content,  7075 cal/g calorific value and  1.4 kg/cm2 compresive strength. It is found that the concentration of binder and raw material influenced the quality of the briquettes. In overall, the production of the briquettes by employing pyrolysis method could meet the standard.

scholarly journals TECHNOLOGY AND EQUIPMENT FOR PROCESSING ACTIVATED AGRICULTURAL PLANT WASTE INTO BIOETHANOL

2022 ◽  
Vol 16 (4) ◽  
pp. 59-67
Author(s):  
Dmitriy Prosvirnikov ◽  
Denis Tuncev ◽  
Bulat Ziganshin
Keyword(s):  
Enzymatic Hydrolysis ◽  
Acid Hydrolysis ◽  
Wheat Straw ◽  
Raw Materials ◽  
Raw Material ◽  
Pine Wood ◽  
Agricultural Plant ◽  
Plant Waste ◽  
Hydrolysis Temperature ◽  
Reducing Substances

The article is devoted to the development of technology and equipment for the production of bioethanol from agricultural plant waste, activated by the steam explosion method. The value and novelty of research lies in obtaining new data on the effective acidic and enzymatic hydrolysis of activated raw materials, and developing a technology for the conversion of plant raw materials into bioethanol. The studies were carried out on the basis of the Department of Wood Materials Processing of Kazan National Research Technological University (Republic of Tatarstan, Kazan). A pilot plant for the production of bioethanol and the principle of its operation are presented. Pine wood waste and wheat straw (collected in Kukmor region of the Republic of Tatarstan in the period August-September 2021) were used as raw materials. Steam-explosive activation of raw materials was carried out at temperatures of 165 ⁰C and 210 ⁰C for 5 minutes. Acid hydrolysis parameters: H2SO4 concentration - 0.5% and 1.5%, hydromodule 1:15, hydrolysis temperature - 187⁰C, hydrolysis duration - 5 hours. Enzymatic hydrolysis parameters: preparation - Cellulox-A (OOO PO Sibbiopharm, Russia) - 6 and 12 g/kg of raw material, hydrolysis temperature - 45 ⁰C, substrate pH 4.7 (acetate buffer), raw material concentration in the substrate 33 g/l, the duration of hydrolysis is 72 h. Alcoholic fermentation of hydrolysates was carried out at 32-34⁰C using Saccharomyces cerevisiae yeast, fermentation duration 7 h, yeast concentration 25 g/l. The bioethanol yield in % of reducing substances was recalculated after determining the mass yield. It is concluded that the vapor-explosive activation of pine wood at a temperature of 210 ºC makes it possible to obtain by acid hydrolysis and anaerobic fermentation of reducing substances up to 0.26 kg (0.33 l) of ethanol from 1 kg of activated raw materials, and activation of wheat straw at the same temperature allows obtaining up to 0.172 kg (0.218 l) ethanol with 1 kg of activated straw

TEKNOLOGI PENGOLAHAN DAN PEMANFAATAN KARBON AKTIF UNTUK INDUSTRI

2010 ◽  
Vol 2 (2) ◽  
pp. 43
Author(s):  
Effendi Arsad
Keyword(s):  
Activated Carbon ◽  
Raw Materials ◽  
Sugar Industry ◽  
Agricultural Waste ◽  
Chemical Properties ◽  
Shrimp Farming ◽  
Raw Material ◽  
Petroleum Chemical ◽  
Materials Used ◽  
Chemical Materials

The  activated carbon is very important  for has  processed product activated carbon.   In south Kalimantan has a big prospects due to the big potential of the raw material provided by the nature and industrial waste. There are a lot of raw materials that can be used for the manufacture of activated carbon such as  agricultural waste, sugarcane waste, waste of sawn timber, lives stock waste and coal  processing waste.Manufacture of activated carbon can be done in  ways: chemical  and physical processes. Activation  is very important in the manufacture of activated carbon in addition to the raw materials used. Activated carbon is charcoal that has undergone changes in chemical properties  and physical properties due to be activated with the activator chemical materials or can by heating at high temperatures, so that absorption , surface area, and the ability to absorb become as very good. Activated carbon is used as an absorbent to absorb heavy metals, in medicine and food, on liquor, petroleum chemical, shrimp farming, the sugar industry of gas purification, catalyst and fertilizer processing.Key wood :  technology  processed, activated carbon

Target Kappa Number for AS/AQ Pulping of Wheat Straw

2011 ◽  
Vol 236-238 ◽  
pp. 1431-1436
Author(s):  
Jing Liu ◽  
Katsuya Nagata
Keyword(s):  
Mass Transfer ◽  
Wheat Straw ◽  
Transition Point ◽  
Phase Transfer ◽  
Raw Materials ◽  
Kraft Pulping ◽  
Kappa Number ◽  
Experimental Results ◽  
Raw Material ◽  
Pulp Yield

Alkaline sulfite/anthraquinone (AS/AQ) pulping of wheat straw under different conditions was conducted in this study. A transition point of kappa number at approximately 6.5 was observed based on all experimental results. This transition point can be regarded as the phase transfer point in AS/AQ pulping from bulk to residual delignification. Effective delignification without great lost of pulp yield can be achieved before kappa number was below this transition point during AS/AQ pulping of wheat straw. It is found that the ratio of cooking liquid to solid should not be lower than 6, if good mass transfer of chemicals and lignin dissolving is needed. As the ratio of Na2SO3 to NaOH dosage ranged from 0.4 to 2.4, low proportion of Na2SO3 allows effective delignification while no serious degradation of carbohydrate. Moreover, similar to kraft pulping, addition of AQ in the range of 0.05% to 0.25% is useful to remove lignin and protect the carbohydrate during AS/AQ pulping. Finally, although the transition point of kappa number may be changed while different raw material used for same pulping process or different pulping process for same raw materials, it is of interest and important for mill practice.

scholarly journals Experimental Investigation on Use of Wheat Straw Ash and Bentonite in Self-Compacting Cementitious System

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Rao Arsalan Khushnood ◽  
Syed Ali Rizwan ◽  
Shazim Ali Memon ◽  
Jean-Marc Tulliani ◽  
Giuseppe Andrea Ferro
Keyword(s):  
Flexural Strength ◽  
Water Absorption ◽  
Wheat Straw ◽  
Raw Materials ◽  
Flow Behavior ◽  
Strength Development ◽  
Test Results ◽  
Acid Attack ◽  
Secondary Raw Materials ◽  
Straw Ash

In this research, we evaluated the feasibility of wheat straw ash and bentonite (raw and heated at 150°C for 8 hrs) as secondary raw materials in self-compacting paste (SCP). The fresh and hardened properties of SCP formulations including water and superplasticizer demand, flow behavior, compressive and flexural strength development, water absorption, and acid attack resistance were evaluated. Moreover, porosity, microstructural, and mineralogical investigations were also carried out on SCP formulations. Test results showed that the properties of SCP formulations in fresh state depend on the morphology of secondary raw materials. For heated bentonite and wheat straw ash formulations, the 28 days of compressive and flexural strength were higher or almost similar to reference SCP formulation. Among SCP formulations, wheat straw ash formulation was found to be more effective in consuming free lime and showed significant decrease in porosity with time, which in turn improved the resistance of this SCP formulation against water absorption and acid attack. Based on the test results, it can be concluded that the successful utilization of wheat straw ash and bentonite SCP formulations will offer durable and environmental friendly option to construction industry.

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