scholarly journals Tailored Interfaces in Fiber-Reinforced Elastomers: A Surface Treatment Study on Optimized Load Coupling via the Modified Fiber Bundle Debond Technique

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 36
Author(s):  
Julia Beter ◽  
Boris Maroh ◽  
Bernd Schrittesser ◽  
Inge Mühlbacher ◽  
Thomas Griesser ◽  
...  

The interface between the reinforcement and surrounding matrix in a fibrous composite is decisive and critical for maintaining component performance, durability, and mechanical structure properties for load coupling assessment, especially for highly flexible composite materials. The clear trend towards tailored solutions reveals that an in-depth knowledge on surface treating methods to enhance the fiber–matrix interfacial interaction and adhesion properties for an optimized load transfer needs to be ensured. This research aims to quantify the effect of several surface treatments for glass fibers applied in endless fiber-reinforced elastomers with pronounced high deformations. Due to this, the glass fiber surface is directly modified with selected sizings, using a wet chemical treatment, and characterized according to chemical and mechanical aspects. For this purpose, the interfacial adhesion performance between fibers and the surrounding matrix material is investigated by a modified fiber pull-out device. The results clearly show that an optimized surface treatment improves the interface strength and chemical bonding significantly. The fiber pull-out test confirms that an optimized fiber–matrix interface can be enhanced up to 85% compared to standard surface modifications, which distinctly provides the basis of enhanced performances on the component level. These findings were validated by chemical analysis methods and corresponding optical damage analysis.

1990 ◽  
Vol 17 (4) ◽  
pp. 610-620 ◽  
Author(s):  
Nemkumar Banthia

With the objective of understanding the reinforcing mechanisms of fibers in steel fiber reinforced concrete, the bond between the fibers and the surrounding matrix is studied by conducting single fiber pull-out tests on fibers bonded in cementitious matrices. Various matrix compositions and fiber geometries have been investigated and the effects of various other factors on the pull-out behavior of the fibers have been quantified through pull-out load–extension plots. Finally, the various modes of fiber–matrix load transfer have been discussed and the favorable and unfavorable conditions for such a transfer have been recognized. Key words: steel fiber reinforced concrete, toughness, fiber–matrix bond, deformed fiber, pull-out tests, load–extension plots.


Author(s):  
K.L. More ◽  
R.A. Lowden

The mechanical properties of fiber-reinforced composites are directly related to the nature of the fiber-matrix bond. Fracture toughness is improved when debonding, crack deflection, and fiber pull-out occur which in turn depend on a weak interfacial bond. The interfacial characteristics of fiber-reinforced ceramics can be altered by applying thin coatings to the fibers prior to composite fabrication. In a previous study, Lowden and co-workers coated Nicalon fibers (Nippon Carbon Company) with silicon and carbon prior to chemical vapor infiltration with SiC and determined the influence of interfacial frictional stress on fracture phenomena. They found that the silicon-coated Nicalon fiber-reinforced SiC had low flexure strengths and brittle fracture whereas the composites containing carbon coated fibers exhibited improved strength and fracture toughness. In this study, coatings of boron or BN were applied to Nicalon fibers via chemical vapor deposition (CVD) and the fibers were subsequently incorporated in a SiC matrix. The fiber-matrix interfaces were characterized using transmission and scanning electron microscopy (TEM and SEM). Mechanical properties were determined and compared to those obtained for uncoated Nicalon fiber-reinforced SiC.


e-Polymers ◽  
2017 ◽  
Vol 17 (2) ◽  
pp. 159-166 ◽  
Author(s):  
Hyeong Min Yoo ◽  
Dong-Jun Kwon ◽  
Joung-Man Park ◽  
Sang Hyuk Yum ◽  
Woo Il Lee

AbstractA lab scale structural reaction injection molding (S-RIM) piece of equipment was designed and used to fabricate glass fiber reinforced polydicyclopentadiene (p-DCPD) composites for three different fiber contents. In order to obtain information regarding the optimal process temperature (>80°C) and the curing time (<30 s), differential scanning calorimetry (DSC) was used to investigate the curing behavior of DCPD resin under isothermal conditions. Further, a norbornene-based silane treatment was used to improve the interfacial adhesion between the glass fibers and DCPD as confirmed by the micro-droplet pull-out test and scanning electron microscopy (SEM). Fabrication of glass fiber/p-DCPD composites with improved mechanical properties was carried out based on the optimized process conditions and surface treatment of glass fiber.


2019 ◽  
Vol 801 ◽  
pp. 251-257
Author(s):  
Tobias Gebken ◽  
Rüdiger Sachs ◽  
Markus Kühn ◽  
Jörg Ihde ◽  
Klaus Dröder ◽  
...  

Injection molding is an efficient manufacturing process for short-fiber reinforced plastic components and is used for the production of semi-structural or geometrically complex components. To improve stiffness and strength, continuous fibers can be locally integrated inside the part during manufacturing. A local integration of fibers is not feasible for high output manufacturing processes but can be achieved by direct impregnation of endless fibers in the injection molding process. It is a challenging option to integrate endless fibers in injection molded parts in means of fiber position and infiltration. Thereby, the knowledge of the flow process of the injected melt must be precisely understood in means of orientation of the fibers to achieve a correct position. In previous works the process parameters for the impregnation of fibers and the composite behavior of untreated fibers were investigated. As a result, the surface pretreatment of the fibers can have an important effect on the composite and the direct impregnation of fibers. An important focus of this work is the pretreatment of glass fibers by plasma. The influence of the plasma parameters resulting on the adhesion properties between fiber and matrix and thus the bond strength of the composite are evaluated and measures for further adhesive property improvement are shown.


2021 ◽  
Vol 11 (12) ◽  
pp. 5484
Author(s):  
Francesca Bompadre ◽  
Christina Scheffler ◽  
Toni Utech ◽  
Jacopo Donnini

Polymeric coatings are widely used to enhance the load bearing capacity and chemical durability of alkali-resistant glass (AR-glass) textile in cement-based composites. The contact zone between coated yarns and concrete matrix plays a major role to enable the stress transfer and has still to be improved for the full exploitation of the mechanical behavior of the composite. As a new approach, this paper studies how the addition of nanoclay particles in the polymer coating formulation can increase the chemical bond between organic coating and inorganic matrix. This includes the description of the water-based coating preparation by dispersing sodium montmorillonites, whereby the resulting coating nanostructure is characterized by X-ray diffraction and energy dispersive X-ray spectroscopy. Single glass fibers were treated by dip-coating. Atomic force microscopy was used to determine the surface roughness, and the effect on the fiber tensile properties was studied. Moreover, the morphological and chemical characteristics of the coatings were compared with the results obtained from single fiber pull-out (SFPO) tests. It was shown that the incorporation of nanoclays leads to increased interfacial shear strength arising from the ability of nanoclay particles to nucleate hydration products in the fiber-matrix contact zone.


2019 ◽  
Vol 3 (1) ◽  
pp. 4 ◽  
Author(s):  
Kazuto Tanaka ◽  
Saya Okuda ◽  
Yoshitaka Hinoue ◽  
Tsutao Katayama

Carbon fiber reinforced thermoplastics (CFRTPs) are expected to be used for the structural parts of automobiles and aircraft due to their mechanical properties, such as high specific stiffness, high specific strength, short molding times and high recyclability. The fiber/matrix interface of the composite plays an important role in transmitting stress from the matrix to the reinforcing fibers. It was reported that grafting of carbon nanotubes (CNTs) on the carbon fiber can improve the fiber/matrix interfacial property. We have reported that CNTs, which are directly grafted onto carbon fiber using Ni as the catalyst by the chemical vapor deposition (CVD) method, can improve the fiber/matrix interfacial shear strength (IFSS) of carbon fiber/polyamide 6 (PA6). For practical use of CFRTPs, it is important to clarify the effects of water absorption on the mechanical properties of the composite material. In this study, the effects of water absorption on the fiber–matrix interfacial shear strength (IFSS) of carbon fiber reinforced polyamide resin and CNT-grafted carbon fiber reinforced polyamide resin were clarified by the single fiber pull-out test for specimens preserved in air, then in water for 24 h and re-dried after water absorption. The IFSS of carbon fiber/PA6 was significantly decreased by water absorption. In contrast, CNT-grafted carbon fiber/PA6 showed smaller degradation of the IFSS by water absorption.


Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1862 ◽  
Author(s):  
Julia Beter ◽  
Bernd Schrittesser ◽  
Bernhard Lechner ◽  
Mohammad Reza Mansouri ◽  
Claudia Marano ◽  
...  

The aim of this work was to analyze the influence of fibers on the mechanical behavior of fiber-reinforced elastomers under cyclic loading. Thus, the focus was on the characterization of structure–property interactions, in particular the dynamic mechanical and viscoelastic behavior. Endless twill-woven glass fibers were chosen as the reinforcement, along with silicone as the matrix material. For the characterization of the flexible composites, a novel testing device was developed. Apart from the conventional dynamic mechanical analysis, in which the effect of the fiber orientation was also considered, modified step cycle tests were conducted under tensile loading. The material viscoelastic behavior was studied, evaluating both the stress relaxation response and the capability of the material to dissipate energy under straining. The effects of the displacement rate of the strain level, the amplitude of the strain applied in the loading–unloading step cycle test, and the number of the applied cycles were evaluated. The results revealed that an optimized fiber orientation leads to 30-fold enhanced stiffness, along with 10 times higher bearable stress. The findings demonstrated that tailored reinforced elastomers with endless fibers have a strong influence on the mechanical performance, affecting the structural properties significantly.


2017 ◽  
Vol 49 ◽  
pp. 1-9 ◽  
Author(s):  
S. Nallusamy ◽  
A. Karthikeyan

Recent research scenario reveals that the amalgamations of micro and nanoceramic fillers into fiber reinforced polymer composites have improved their performances in an excellent manner. In this research work, an investigation was attempted at in analyzing the wear behavior of glass fiber reinforced with epoxy resin using granite powder as a filler material in varying weight percentage ranging from 0-5%. Structural morphology of the prepared laminates was studied using SEM. Epoxy resin which was taken as matrix material was reinforced with a combination of chopped and woven roving mat glass fibers. Pin on disc method was applied for completing the wear test at different constraints of load, sliding distance and velocity for the investigation. Influence of granite powder in the composite was synthesized by calculating the specific wear rate and weight loss occurring at varying speed and normal load were applied on it. On examining by SEM worn surface wear rate of the prepared laminate at 5 wt% of granite provided better wear resistance as compared to other compositions and characterizations of worn surfaces.


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