scholarly journals New Insight on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on Azobenzene/Graphene Hybrid Additives in Polyethylene Oxide

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2954
Author(s):  
Qais M. Al-Bataineh ◽  
Ahmad A. Ahmad ◽  
Ahmad M. Alsaad ◽  
Ahmad Telfah
Keyword(s):  
Thin Films ◽  
Time Evolution ◽  
Polyethylene Oxide ◽  
Azo Dye ◽  
Molecular Switches ◽  
Solar Thermal Energy ◽  
Uv Illumination ◽  
Storage Media ◽  
Hybrid Thin Films ◽  
Kinetics Of

In this work, we reported a new insight on the kinetics of photoisomerization and time evolution of hybrid thin films considering the azo-dye methyl red (MR) incorporated with graphene accommodated in polyethylene oxide (PEO). The kinetics of photoisomerization and time-evolution of hybrid thin films were investigated using UV-Vis s and FTIR spectroscopies, as well as appropriate models developed with new analytical methods. The existence of azo-dye MR in the complex is crucial for the resource action of the trans↔cis cycles through UV-illumination ↔ Visible-illumination relaxations. The results of the UV–Vis and the FTIR investigations prove the cyclical trans ↔ cis-states. Consequently, PEO-(MR-Graphene) hybrid composite thin films can be introduced as possible applicants for photochromic molecular switches, light-gated transistors, and molecular solar thermal energy storage media.

scholarly journals Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 841
Author(s):  
Qais M. Al-Bataineh ◽  
A. A. Ahmad ◽  
A. M. Alsaad ◽  
I. A. Qattan ◽  
Ihsan A. Aljarrah ◽  
...  
Keyword(s):  
Thin Films ◽  
Energy Storage ◽  
Thermal Energy ◽  
Energy Barrier ◽  
Processing Time ◽  
Solar Thermal Energy ◽  
Storage Media ◽  
Nanocomposite Thin Films ◽  
Isomerization Energy ◽  
Kinetics Of

We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I2 nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO-BDK-MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO-BDK-MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

Optical Poling of Phenyl-Silica Hybrid Thin Films Doped with Azo-Dye Chromophore

1999 ◽  
Vol 38 (Part 2, No. 9A/B) ◽  
pp. L1029-L1031 ◽  
Author(s):  
Kenji Kitaoka ◽  
Nobuaki Matsuoka ◽  
Jinhai Si ◽  
Tsuneo Mitsuyu ◽  
Kazuyuki Hirao
Keyword(s):  
Thin Films ◽  
Azo Dye ◽  
Hybrid Thin Films ◽  
Silica Hybrid

scholarly journals Optical-Poling of an Azo-Dye Chromophore Doped Silica Hybrid Thin Films.

1999 ◽  
Vol 107 (1246) ◽  
pp. 522-526 ◽  
Author(s):  
Kenji KITAOKA ◽  
Jinhai SI ◽  
Tsuneo MITSUYU ◽  
Kazuyuki HIRAO
Keyword(s):  
Thin Films ◽  
Azo Dye ◽  
Hybrid Thin Films ◽  
Silica Hybrid

Inhomogeneous Broadening of Photoluminescence Spectra and Kinetics of Nanometer-Thick (Phenethylammonium)2PbI4 Perovskite Thin Films: Implications for Optoelectronics

2021 ◽  
Author(s):  
Vladimir S. Chirvony ◽  
Isaac Suárez ◽  
Jesús Rodríguez-Romero ◽  
Rubén Vázquez-Cárdenas ◽  
Jesus Sanchez-Diaz ◽  
...  
Keyword(s):  
Thin Films ◽  
Inhomogeneous Broadening ◽  
Photoluminescence Spectra ◽  
Kinetics Of

Fast oxygen exchange kinetics of pore-free Bi1−xSrxFeO3−δ thin films

2011 ◽  
Vol 13 (37) ◽  
pp. 16530 ◽  
Author(s):  
Anja Wedig ◽  
Rotraut Merkle ◽  
Benjamin Stuhlhofer ◽  
Hanns-Ulrich Habermeier ◽  
Joachim Maier ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of

Investigation of electrodeposition kinetics of In, Sb, and Zn for advanced designing of InSb and ZnSb thin films

2020 ◽  
pp. 114967
Author(s):  
Dominika Rajska ◽  
Agnieszka Brzózka ◽  
Katarzyna E. Hnida-Gut ◽  
Grzegorz D. Sulka
Keyword(s):  
Thin Films ◽  
Kinetics Of

Solution processed transparent conductive hybrid thin films based on silver nanowires, zinc oxide and graphene

2021 ◽  
Vol 26 ◽  
pp. 102162
Author(s):  
Refik Arat ◽  
Guobin Jia ◽  
Jan Dellith ◽  
Andrea Dellith ◽  
Jonathan Plentz
Keyword(s):  
Thin Films ◽  
Zinc Oxide ◽  
Silver Nanowires ◽  
Solution Processed ◽  
Hybrid Thin Films
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