scholarly journals Py–FTIR–GC/MS Analysis of Volatile Products of Automobile Shredder Residue Pyrolysis

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2734
Author(s):  
Bin Yang ◽  
Ming Chen

Automobile shredder residue (ASR) pyrolysis produces solid, liquid, and gaseous products, particularly pyrolysis oil and gas, which could be used as renewable alternative energy resources. Due to the primary pyrolysis reaction not being complete, the yield of gaseous product is low. The pyrolysis tar comprises chemically unstable volatiles before condensing into liquid. Understanding the characteristics of volatile products will aid the design and improvement of subsequent processes. In order to accurately analyze the chemical characteristics and yields of volatile products of ASR primary pyrolysis, TG–FTIR–GC/MS analysis technology was used. According to the analysis results of the Gram–Schmidt profiles, the 3D stack plots, and GC/MS chromatograms of MixASR, ASR, and its main components, the major pyrolytic products of ASR included alkanes, olefins, and alcohols, and both had dense and indistinguishable weak peaks in the wavenumber range of 1900–1400 cm−1. Many of these products have unstable or weaker chemical bonds, such as =CH–, =CH2, –C=C–, and –C=CH2. Hence, more syngas with higher heating values can be obtained with further catalytic pyrolysis gasification, steam gasification, or higher temperature pyrolysis.

1996 ◽  
Vol 11 (9) ◽  
pp. 2368-2375 ◽  
Author(s):  
Hossein Maleki ◽  
Lawrence R. Holland ◽  
Gwyn M. Jenkins ◽  
R. L. Zimmerman ◽  
Wally Porter

Polymeric carbon artifacts are particularly difficult to make in thick section. Heating rate, temperature, and sample thickness determine the outcome of carbonization of resin leading to a glassy polymeric carbon ware. Using wedge-shaped samples, we found the maximum thickness for various heating rates during gelling (300 K–360 K), curing (360 K–400 K), postcuring (400 K–500 K), and precarbonization (500 K–875 K). Excessive heating rate causes failure. In postcuring the critical heating rate varies inversely as the fifth power of thickness; in precarbonization this varies inversely as the third power of thickness. From thermogravimetric evidence we attribute such failure to low rates of diffusion of gaseous products of reactions occurring within the solid during pyrolysis. Mass spectrometry shows the main gaseous product is water vapor; some carboniferous gases are also evolved during precarbonization. We discuss a diffusion model applicable to any heat-treatment process in which volatile products are removed from solid bodies.


Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1682 ◽  
Author(s):  
Bin Yang ◽  
Ming Chen

Pyrolysis and gasification have gradually become the main means to dispose of automobile shredder residue (ASR), since these methods can reduce the volume and quality of landfill with lower cost and energy recovery can be conducted simultaneously. As the ASR pyrolysis process is integrated, the results of pyrolysis reactions of organic components and the interaction among polymeric components can be clarified by co-pyrolysis thermogravimetric experiments. The results show that the decomposition mechanisms of textiles and foam are markedly changed by plastic in the co-pyrolysis process, but the effect is not large for rubber and leather. This effect is mainly reflected in the pyrolysis temperature and pyrolysis rate. The pyrolytic trend and conversion curve shape of the studied ASR can be predicted by the main polymeric components with a parallel superposition model. The pyrolytic product yields and characterizations of gaseous products were analyzed in laboratory-scale non-isothermal pyrolysis experiments at finished temperatures of 500 °C, 600 °C, and 700 °C. The results prove that the yields of pyrolytic gas products are determined by the thermal decomposition of organic substances in the ASR and final temperature.


2001 ◽  
Vol 42 (5) ◽  
pp. 573-586 ◽  
Author(s):  
S Galvagno ◽  
F Fortuna ◽  
G Cornacchia ◽  
S Casu ◽  
T Coppola ◽  
...  

2018 ◽  
Vol 197 ◽  
pp. 09005
Author(s):  
Bregas Siswahjono Tatag Sembodo ◽  
Hary Sulistyo ◽  
Wahyudi Budi Sediawan ◽  
Mohammad Fahrurrozi

Corncobs are potentially processed into bio-oil through thermochemical liquefaction processes. It is difficult to construct kinetics models based on the compounds involved in the reaction. It would be made four kinetic models based on four reaction products, i.e., solids, bio-oil, gas and volatile products. The purposes of the study were to seek kinetics model of thermochemical liquefaction of corncobs in ethanol-water solution and to study the effect of ethanol concentration. The experiment of liquefaction processes of corncobs in ethanol-water solution using sodium carbonate catalyst was performed in the 150 ml autoclave equipped with a magnetic stirrer in the temperature up to 280°C. Four kinetic models were applied to predict the yield of four reaction product lumps. The calculation results were compared to the experimental data. Compared to the others, model 4 was the most realistic and closely matching to the experimental data. In model 4 the reaction mechanism was assumed that biomass (corncobs) first decomposed into bio-oil, followed by decomposition of bio-oil into volatile products reversibly and, finally, volatile products decomposed into gaseous products. The yield of bio-oil increased from 42.05% to 54.93% by increasing to ethanol concentration of 0% to 40%.


2016 ◽  
Vol 19 (3) ◽  
pp. 96-109
Author(s):  
Phung Thi Kim Le ◽  
Viet Tan Tran ◽  
Thien Luu Minh Nguyen ◽  
Viet Vuong Pham ◽  
Truc Thanh Nguyen ◽  
...  

Finding alternative energy sources for fossil fuels was a global matter of concern, especially in developing countries. Rice husk, an abundant biomass in Viet Nam, was used to partially replace fossil fuels by gasification process. The study was conducted on the pilot plant fixed bed up-draft gasifier with two kind of gasification agents, pure air and air-steam mixture. Mathematical modeling and computer simulations were also used to describe and optimize the gasification processes. Mathematical modeling was based on Computational Fluid Dynamics method and simulation was carried by using Ansys Fluent software. Changes in outlet composition of syngas components (CO, CO2, CH4, H2O, H2) and temperature of process, in relation with ratio of steam in gasification agents, were presented. Obtained results indicated concentration of CH4, H2 in outlet was increased significantly when using air-steam gasification agents than pure air. The discrepancies among the gasification agents were determined to improve the actual process.


2021 ◽  
Vol 73 (06) ◽  
pp. 34-37
Author(s):  
Judy Feder

We talk about “the energy transition” as if it were some type of unified, global event. Instead, numerous approaches to energy transitions are taking place in parallel, with all of the “players” moving at different paces, in different directions, and with different guiding philosophies. Which companies are best positioned to survive and thrive, and why? This article takes a look at what several top energy research and business intelligence firms are saying. What a Difference a Year Makes Prior to 2020—in fact, as recently as the 2014 bust that followed the shale boom—the oil and gas industry weathered downturns by “tightening their belts” and “doing more with less” in the form of cutting capital expenditures and costs, tapping credit lines, and improving operational efficiency. Adopting advanced digitalization and cognitive technologies as integral parts of the supply chain from 2015 to 2019 led to significant performance improvements as companies dealt with “shale shock.” Then, in 2020, a strange thing happened. Just as disruptive technologies like electric vehicles and solar photovoltaic and new batteries were gaining traction and decarbonization and environmental, social, and governance (ESG) issues were rising to the top of global social and policy agendas, COVID-19 left companies with almost nothing to squeeze from their supply chains, and budget cuts had a direct impact on operational performance and short-term operational plans. To stabilize their returns, many oil and gas companies revised and reshaped their portfolios and business strategies around decarbonization and alternative energy sources. The result: The investment in efforts toward effecting energy transition surpassed $500 billion for the first time in early 2021 ($501.3 billion, a 9% increase over 2019, according to BloombergNEF) despite the economic disruption caused by COVID-19. According to Wood Mackenzie, carbon emissions and carbon intensity are now key metrics in any project’s final investment decision. And, Rystad Energy said that greenhouse-gas emissions are declining faster than what is outlined in many conventional models regarded as aggressive scenarios. In Rystad’s model, electrification levels will reach 80% by 2050. A Look at the Playing Field: Energy Transition Pillars In a February 2021 webinar, Rystad discussed what leading exploration and production (E&P) companies are doing to keep up with the energy transition and stay investable in the rapidly changing market environment. The consulting firm researched the top 25 E&P companies based on their oil and gas production in 2020 and analyzed how they approach various market criteria in “three pillars of energy transition in the E&P sector” that the firm regards as key distinguishers and important indicators of potential success (Fig. 1). The research excludes national oil companies (NOCs) except for those with international activity (INOCs). Rystad says these 25 companies are responsible for almost 40% of global hydrocarbon production and the same share of global E&P investments and believes the trends within this peer group are representative on a global scale.


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