scholarly journals A New Approach Based on Glued Multi-Ultra High Molecular Weight Polyethylene Forms to Fabricate Bone Replacement Products

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2545
Author(s):  
Tarek Dayyoub ◽  
Aleksey Maksimkin ◽  
Fedor Senatov ◽  
Sergey Kaloshkin ◽  
Natalia Anisimova ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Phenol Formaldehyde ◽  
Peel Strength ◽  
Mechanical Tests ◽  
Cortical Layer ◽  
Compressive Yield Strength ◽  
Ene Reaction ◽  
Promising Development ◽  
Ultra High Molecular Weight

Three types of glue based on thiol-ene reaction, polyvinyl alcohol (PVA)/cellulose, and phenol formaldehyde were prepared and applied on modified ultra-high molecular weight polyethylene (UHMWPE) samples grafted by cellulose. In comparison with unmodified UHMWPE samples, T-peel tests on the modified and grafted UHMWPE films showed an increase in the peel strength values for the glues based on thiol-ene reaction, PVA/cellulose, and phenol formaldehyde by 40, 29, and 41 times, respectively. The maximum peel strength value of 0.62 Kg/cm was obtained for the glue based on phenol formaldehyde. Mechanical tests for the cylindrical multi-UHMWPE forms samples, made of porous UHMWPE as a trabecular layer and an armored layer (cortical layer) that consists of bulk and UHMWPE films, indicated an improvement in the mechanical properties of these samples for all glue types, as a result of the UHMWPE films existence and the increase in the number of their layers. The maximum compressive yield strength and compressive modulus values for the armored layer (bulk and six layers of the UHMWPE films using the glue based on thiol-ene reaction) were 44.1 MPa (an increase of 17%) and 1130 MPa (an increase of 36%), respectively, in comparison with one armored layer of bulk UHMWPE. A hemocompatibility test carried out on these glues clarified that the modified UHMWPE grafted by cellulose with glues based on PVA/cellulose and thiol-ene reaction were classified as biocompatible materials. These multi-UHMWPE forms composites can be considered a promising development for joint reconstruction.

Derivation of the material models for ultra-high molecular-weight polyethylene fiber-reinforced armor-grade composites with different architectures

2016 ◽  
Vol 33 (3) ◽  
Author(s):  
Mica Grujicic ◽  
Jennifer Snipes ◽  
S. Ramaswami ◽  
Vasudeva Avuthu ◽  
Chian-Fong Yen ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Design Methodology ◽  
Critical Role ◽  
Fiber Reinforcement ◽  
Mechanical Tests ◽  
Transverse Impact ◽  
Material Models ◽  
Polyethylene Fiber ◽  
Ultra High Molecular Weight

Purpose To overcome the problem of inferior through-the-thickness mechanical properties displayed by armor-grade composites based on 2-D reinforcement architectures, armor-grade composites based on 3D fiber-reinforcement architectures have recently been investigated experimentally. Design/methodology/approach The subject of the present work is armor-grade composite materials reinforced using ultra-high-molecular-weight polyethylene fibers and having four (two 2D and two 3D) prototypical architectures, as well as the derivation of the corresponding material models. The effect of the reinforcement architecture is accounted for by constructing the appropriate unit cells (within which the constituent materials and their morphologies are represented explicitly) and subjecting them to a series of virtual mechanical tests. The results obtained are used within a post-processing analysis to derive and parameterize the corresponding homogenized-material models. One of these models (specifically, the one for 0°/90° cross-collimated fiber architecture) was directly validated by comparing its predictions with the experimental counterparts. The other models are validated by examining their physical soundness and details of their predictions. Lastly, the models are integrated as user-material subroutines, and linked with a commercial finite-element package, in order to carry out a transient non-linear dynamics analysis of ballistic transverse impact of armor-grade composite-material panels with different reinforcement architectures. Findings It is found that the reinforcement architecture plays a critical role in the overall ballistic limit of the armor panel, as well as in its structural and damage/failure response. Originality/value To the authors’ knowledge, the present work is the first reported attempt to assess, computationally, the utility and effectiveness of 3D fiber-reinforcement architectures for ballistic impact applications.

scholarly journals Structure, processing and performance of ultra-high molecular weight polyethylene (IUPAC Technical Report). Part 3: deformation, wear and fracture

2020 ◽  
Vol 92 (9) ◽  
pp. 1503-1519
Author(s):  
Clive Bucknall ◽  
Volker Altstädt ◽  
Dietmar Auhl ◽  
Paul Buckley ◽  
Dirk Dijkstra ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Tensile Tests ◽  
Mechanical Tests ◽  
Dominant Factor ◽  
Stress Strain ◽  
Entanglement Density ◽  
Wide Range ◽  
And Performance ◽  
Ultra High Molecular Weight

AbstractThree grades of polyethylene, with weight-average relative molar masses, ${\bar{M}}_{\text{W}}$, of approximately 0.6 × 106, 5 × 106, and 9 × 106, were supplied as compression mouldings by a leading manufacturer of ultra-high molecular weight polyethylene (UHMWPE). They were code-named PE06, PE5, and PE9, respectively. Specimens cut from these mouldings were subjected to a wide range of mechanical tests at 23 °C. In tensile tests, deformation was initially elastic and dominated by crystallinity, which was highest in PE06. Beyond the yield point, entanglement density became the dominant factor, and at 40 % strain, the rising stress–strain curves for PE5 and PE9 crossed the falling PE06 curve. Fracture occurred at strains above 150 %. Differences in stress–strain behaviour between PE5 and PE9 were relatively small. A similar pattern of behaviour was observed in wear tests; wear resistance showed a marked increase when ${\bar{M}}_{\text{W}}$ was raised from 0.6 × 106 to 5 × 106, but there was no further increase when it was raised to 9 × 106. It is concluded that the unexpected similarity in behaviour between PE5 and PE9 was due to incomplete consolidation during moulding, which led to deficiencies in entanglement at grain boundaries; they were clearly visible on the surfaces of both tensile and wear specimens. Fatigue crack growth in 10 mm thick specimens was so severely affected by inadequate consolidation that it forms the basis for a separate report – Part 4 in this series.

Biomaterial Models Adjustment and Comparison for Ultra-High Molecular Weight Polyethylene in Finite Element Models

2018 ◽  
Author(s):  
Humberto Corro-Hernández ◽  
Agustín Vidal-Lesso ◽  
Elías Ledesma ◽  
Antonio de Jesús Balvantín-García
Keyword(s):  
Molecular Weight ◽  
Finite Element ◽  
High Molecular Weight ◽  
Numerical Solutions ◽  
Constant Strain Rate ◽  
Mechanical Tests ◽  
Isotropic Hardening ◽  
Load Curve ◽  
Prosthesis And Implants ◽  
Ultra High Molecular Weight

GUR1050 is a medical grade variety of ultra-high molecular weight polyethylene (UHMWPE) intended for use on total joint prosthesis and implants. Probes of this material were characterized on a compression test following ASTM norms and lineaments. Available data from these mechanical tests is fitted on multiple material models. Achieved results on numerical solutions of finite element modeling (FEM) of the tests are discussed, looking for the best one available in order to simulate with accuracy GUR1050 behavior, with specific interest on the load curve results, showing the pertinence of using certain models on different conditions. It was found that the use of a bilinear isotropic hardening model assures the best fit for GUR1050 behavior in uniaxial compression under a constant strain rate.

scholarly journals Effect of Borpolymer on Mechanical and Structural Parameters of Ultra-High Molecular Weight Polyethylene

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3398
Author(s):  
Sakhayana N. Danilova ◽  
Afanasy A. Dyakonov ◽  
Andrey P. Vasilev ◽  
Aitalina A. Okhlopkova ◽  
Aleksei G. Tuisov ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Polymer Composites ◽  
High Molecular Weight ◽  
Supramolecular Structure ◽  
Structural Parameters ◽  
Mechanical Tests ◽  
Structural Studies ◽  
Scanning Calorimetry ◽  
X Ray Crystallography ◽  
Ultra High Molecular Weight

The paper presents the results of studying the effect of borpolymer (BP) on the mechanical properties, structure, and thermodynamic parameters of ultra-high molecular weight polyethylene (UHMWPE). Changes in the mechanical characteristics of polymer composites material (PCM) are confirmed and complemented by structural studies. X-ray crystallography (XRC), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and infrared spectroscopy (IR) were used to study the melting point, morphology and composition of the filler, which corresponds to the composition and data of the certificate of the synthesized BP. Tensile and compressive mechanical tests were carried out in accordance with generally accepted standards (ASTM). It is shown that BP is an effective modifier for UHMWPE, contributing to a significant increase in the deformation and strength characteristics of the composite: tensile strength of PCM by 56%, elongation at break by 28% and compressive strength at 10% strain by 65% compared to the initial UHMWPE, due to intensive changes in the supramolecular structure of the matrix. Structural studies revealed that BP does not chemically interact with UHMWPE, but due to its high adhesion to the polymer, it acts as a reinforcing filler. SEM was used to establish the formation of a spherulite supramolecular structure of polymer composites.

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