scholarly journals Rheology-Assisted Microstructure Control for Printing Magnetic Composites—Material and Process Development

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2143
Author(s):  
Balakrishnan Nagarajan ◽  
Martin A.W. Schoen ◽  
Simon Trudel ◽  
Ahmed Jawad Qureshi ◽  
Pierre Mertiny
Keyword(s):  
Manufacturing Process ◽  
Computer Aided Design ◽  
Quantum Interference ◽  
Permanent Magnets ◽  
Building Blocks ◽  
Magnetic Characteristics ◽  
Microstructure Control ◽  
Magnetic Composites ◽  
Uv Curable ◽  
Particle Alignment

Magnetic composites play a significant role in various electrical and electronic devices. Properties of such magnetic composites depend on the particle microstructural distribution within the polymer matrix. In this study, a methodology to manufacture magnetic composites with isotropic and anisotropic particle distribution was introduced using engineered material formulations and manufacturing methods. An in-house developed material jetting 3D printer with particle alignment capability was utilized to dispense a UV curable resin formulation to the desired computer aided design (CAD) geometry. Formulations engineered using additives enabled controlling the rheological properties and the microstructure at different manufacturing process stages. Incorporating rheological additives rendered the formulation with thixotropic properties suitable for material jetting processes. Particle alignment was accomplished using a magnetic field generated using a pair of permanent magnets. Microstructure control in printed composites was observed to depend on both the developed material formulations and the manufacturing process. The rheological behavior of filler-modified polymers was characterized using rheometry, and the formulation properties were derived using mathematical models. Experimental observations were correlated with the observed mechanical behavior changes in the polymers. It was additionally observed that higher additive content controlled particle aggregation but reduced the degree of particle alignment in polymers. Directionality analysis of optical micrographs was utilized as a tool to quantify the degree of filler orientation in printed composites. Characterization of in-plane and out-of-plane magnetic properties using a superconducting quantum interference device (SQUID) magnetometer exhibited enhanced magnetic characteristics along the direction of field structuring. Results expressed in this fundamental research serve as building blocks to construct magnetic composites through material jetting-based additive manufacturing processes.

scholarly journals Development and Characterization of Field Structured Magnetic Composites

Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2843
Author(s):  
Balakrishnan Nagarajan ◽  
Yingnan Wang ◽  
Maryam Taheri ◽  
Simon Trudel ◽  
Steven Bryant ◽  
...  
Keyword(s):  
Magnetic Particles ◽  
Monomer Conversion ◽  
Filler Loading ◽  
Magnetic Composites ◽  
Uv Curable ◽  
Epoxy Resin System ◽  
Out Of Plane ◽  
Combine Magnetic Field ◽  
Microstructural Morphology ◽  
Particle Alignment

Polymer composites containing ferromagnetic fillers are promising for applications relating to electrical and electronic devices. In this research, the authors modified an ultraviolet light (UV) curable prepolymer to additionally cure upon heating and validated a permanent magnet-based particle alignment system toward fabricating anisotropic magnetic composites. The developed dual-cure acrylate-based resin, reinforced with ferromagnetic fillers, was first tested for its ability to polymerize through UV and heat. Then, the magnetic alignment setup was used to orient magnetic particles in the dual-cure acrylate-based resin and a heat curable epoxy resin system in a polymer casting approach. The alignment setup was subsequently integrated with a material jetting 3D printer, and the dual-cure resin was dispensed and cured in-situ using UV, followed by thermal post-curing. The resulting magnetic composites were tested for their filler loading, microstructural morphology, alignment of the easy axis of magnetization, and degree of monomer conversion. Magnetic characterization was conducted using a vibrating sample magnetometer along the in-plane and out-of-plane directions to study anisotropic properties. This research establishes a methodology to combine magnetic field induced particle alignment along with a dual-cure resin to create anisotropic magnetic composites through polymer casting and additive manufacturing.

Mechanically-Tunable Quantum Interference in Ferrocene-Based Single-Molecule Junctions

2020 ◽  
Author(s):  
María Camarasa-Gómez ◽  
Daniel Hernangómez-Pérez ◽  
Michael S. Inkpen ◽  
Giacomo Lovat ◽  
E-Dean Fung ◽  
...  
Keyword(s):  
Single Molecule ◽  
Quantum Interference ◽  
Degrees Of Freedom ◽  
Building Blocks ◽  
Ferrocene Derivative ◽  
Single Molecule Junctions ◽  
Molecule Junction ◽  
Single Molecule Junction ◽  
The Impact ◽  
D Orbitals

Ferrocenes are ubiquitous organometallic building blocks that comprise a Fe atom sandwiched between two cyclopentadienyl (Cp) rings that rotate freely at room temperature. Of widespread interest in fundamental studies and real-world applications, they have also attracted<br>some interest as functional elements of molecular-scale devices. Here we investigate the impact of<br>the configurational degrees of freedom of a ferrocene derivative on its single-molecule junction<br>conductance. Measurements indicate that the conductance of the ferrocene derivative, which is<br>suppressed by two orders of magnitude as compared to a fully conjugated analog, can be modulated<br>by altering the junction configuration. Ab initio transport calculations show that the low conductance is a consequence of destructive quantum interference effects that arise from the hybridization of metal-based d-orbitals and the ligand-based π-system. By rotating the Cp rings, the hybridization, and thus the quantum interference, can be mechanically controlled, resulting in a conductance modulation that is seen experimentally.<br>

Constraints and limitations of concrete 3D printing in architecture

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chien-Ho Ko
Keyword(s):  
3D Printing ◽  
Manufacturing Process ◽  
Computer Aided Design ◽  
Research Approach ◽  
Layer By Layer ◽  
Content Type ◽  
Improve Design ◽  
Study Results ◽  
Computer Aided ◽  
Property Control

Purpose Additive manufacturing of concrete (AMoC) is an emerging technology for constructing buildings. However, due to the nature of the concrete property and constructing buildings in layers, constraints and limitations are encountered while applying AMoC in architecture. This paper aims to analyze the constraints and limitations that may be encountered while using AMoC in architecture. Design/methodology/approach A descriptive research approach is used to conduct this study. First, basic notions of AMoC are introduced. Then, challenges of AMoC, including hardware, material property, control and design, are addressed. Finally, strategies that may be used to overcome the challenges are discussed. Findings Factors influencing the success of AMoC include hardware, material, control methods, manufacturing process and design. Considering these issues in the early design phase is crucial to achieving a successful computer-aided design (CAD)/computer-aided manufacturing (CAM) integration to bring CAD and CAM benefits into the architecture industry. Originality/value In three-dimensional (3D) printing, objects are constructed layer by layer. Printing results are thus affected by the additive method (such as toolpath) and material properties (such as tensile strength and slump). Although previous studies attempt to improve AMoC, most of them focus on the manufacturing process. However, a successful application of AMoC in architecture needs to consider the possible constraints and limitations of concrete 3D printing. So far, research on the potential challenges of applying AMoC in architecture from a building lifecycle perspective is still limited. The study results of this study could be used to improve design and construction while applying AMoC in architecture.

scholarly journals Developing a reference material set for the magnetic properties of NdFeB alloy-based hard magnetic materials

2019 ◽  
Vol 15 (1) ◽  
pp. 21-27
Author(s):  
E. A. Volegova ◽  
T. I. Maslova ◽  
V. O. Vas’kovskiy ◽  
A. S. Volegov
Keyword(s):  
Magnetic Properties ◽  
Magnetic Materials ◽  
Permanent Magnets ◽  
Magnetic Loss ◽  
Magnetic Hysteresis ◽  
Hysteresis Loops ◽  
Magnetic Hysteresis Loop ◽  
Magnetic Characteristics ◽  
Hard Magnetic Materials ◽  
Certified Values

Introduction The introduction indicates the need for the use of permanent magnets in various technology fields. The necessity of measuring the limit magnetic hysteresis loop for the correct calculation of magnetic system parameters is considered. The main sources of error when measuring boundary hysteresis loops are given. The practical impossibility of verifying blocks of magnetic measuring systems element-by-element is noted. This paper is devoted to the development of reference materials (RMs) for the magnetic properties of hard magnetic materials based on Nd2Fe14B, a highly anisotropic intermetallic compound.Materials and measuring methods Nd-Fe-B permanent magnets were selected as the material for developing the RMs. RM certified values were established using a CYCLE‑3 apparatus included in the GET 198‑2017 State Primary Measurement Standard for units of magnetic loss power, magnetic induction of constant magnetic field in a range from 0.1 to 2.5 T and magnetic flux in a range from 1·10–5 to 3·10–2 Wb.Results and its discussion Based on the experimentally obtained boundary hysteresis loops, the magnetic characteristics were evaluated, the interval of permitted certified values was set, the measurement result uncertainty of certified values was estimated, the RM validity period was established and the first RM batch was released.Conclusion On the basis of conducted studies, the RM type for magnetic properties of NdFeB alloy-based hard magnetic materials was approved (MS NdFeB set). The developed RM set was registered under the numbers GSO 11059–2018 / GSO 11062–2018 in the State RM Register of the Russian Federation.

Barium and strontium ferrite-filled composites based on NBR and SBR

2018 ◽  
Vol 51 (5) ◽  
pp. 421-439 ◽  
Author(s):  
Ján Kruželák ◽  
Martina Matvejová ◽  
Rastislav Dosoudil ◽  
Ivan Hudec
Keyword(s):  
Barium Ferrite ◽  
Strontium Ferrite ◽  
Styrene Butadiene Rubber ◽  
Magnetic Characteristics ◽  
Butadiene Rubber ◽  
Magnetic Composites ◽  
Link Density ◽  
Cross Link Density ◽  
The Cross ◽  
Styrene Butadiene

In the first part of the research, rubber magnetic composites were prepared by incorporation of strontium and barium ferrite in concentration scale ranging from 0 to 200 phr into rubber matrices based on acrylonitrile–butadiene rubber and styrene–butadiene rubber. The main objective was to investigate the influence of the type and content of magnetic filler on the cross-link density, physical–mechanical and magnetic characteristics of the prepared composites. In the second part of the study, the content of magnetic fillers was kept on constant level—200 phr and the main aim was to investigate the change in mutual combination of both fillers on the cross-linking and properties of the rubber magnets. The results revealed that both fillers show reinforcement effect in the rubber matrices. The higher tensile strength of composites was achieved by application of barium ferrite. Magnetic properties of composite materials were significantly influenced by magnetic characteristics of magnetic fillers. Higher remanent magnetic induction of barium ferrite was reflected in higher remanent magnetization of the equivalent composites. On the other hand, higher coercivity of strontium ferrite resulted in higher coercivity of strontium ferrite-filled composites.

Laser Additive Manufacturing

3D Printing ◽  
2017 ◽  
pp. 154-171 ◽  
Author(s):  
Rasheedat M. Mahamood ◽  
Esther T. Akinlabi
Keyword(s):  
Additive Manufacturing ◽  
Manufacturing Process ◽  
Computer Aided Design ◽  
Selective Laser Sintering ◽  
Three Dimensional ◽  
Cad Model ◽  
Laser Additive Manufacturing ◽  
Computer Aided ◽  
Manufacturing Technologies ◽  
Aided Design

Laser additive manufacturing is an advanced manufacturing process for making prototypes as well as functional parts directly from the three dimensional (3D) Computer-Aided Design (CAD) model of the part and the parts are built up adding materials layer after layer, until the part is competed. Of all the additive manufacturing process, laser additive manufacturing is more favoured because of the advantages that laser offers. Laser is characterized by collimated linear beam that can be accurately controlled. This chapter brings to light, the various laser additive manufacturing technologies such as: - selective laser sintering and melting, stereolithography and laser metal deposition. Each of these laser additive manufacturing technologies are described with their merits and demerits as well as their areas of applications. Properties of some of the parts produced through these processes are also reviewed in this chapter.

scholarly journals Silicon-based spin and charge quantum computation

2005 ◽  
Vol 77 (2) ◽  
pp. 201-222 ◽  
Author(s):  
Belita Koiller ◽  
Xuedong Hu ◽  
Rodrigo B. Capaz ◽  
Adriano S. Martins ◽  
Sankar Das Sarma
Keyword(s):  
Quantum Computation ◽  
Quantum Interference ◽  
Quantum Computer ◽  
Building Blocks ◽  
Shallow Donor ◽  
Molecular Ions ◽  
Conduction Band Edge ◽  
Tunnel Coupling ◽  
Qubit Operations ◽  
Silicon Based

Silicon-based quantum-computer architectures have attracted attention because of their promise for scalability and their potential for synergetically utilizing the available resources associated with the existing Si technology infrastructure. Electronic and nuclear spins of shallow donors (e.g. phosphorus) in Si are ideal candidates for qubits in such proposals due to the relatively long spin coherence times. For these spin qubits, donor electron charge manipulation by external gates is a key ingredient for control and read-out of single-qubit operations, while shallow donor exchange gates are frequently invoked to perform two-qubit operations. More recently, charge qubits based on tunnel coupling in P+2 substitutional molecular ions in Si have also been proposed. We discuss the feasibility of the building blocks involved in shallow donor quantum computation in silicon, taking into account the peculiarities of silicon electronic structure, in particular the six degenerate states at the conduction band edge. We show that quantum interference among these states does not significantly affect operations involving a single donor, but leads to fast oscillations in electron exchange coupling and on tunnel-coupling strength when the donor pair relative position is changed on a lattice-parameter scale. These studies illustrate the considerable potential as well as the tremendous challenges posed by donor spin and charge as candidates for qubits in silicon.

scholarly journals Framework of models for selecting manufacturing processes and associated parameters for surface topographies

2019 ◽  
Vol 20 (3) ◽  
pp. 301
Author(s):  
Benoit Rosa ◽  
Maxence Bigerelle ◽  
Antoine Brient ◽  
Serge Samper
Keyword(s):  
Specific Surface ◽  
Surface Finish ◽  
Manufacturing Process ◽  
Computer Aided Design ◽  
Manufacturing Processes ◽  
Operating Parameters ◽  
Electro Discharge Machining ◽  
Surface Topographies ◽  
Computer Aided ◽  
Aided Design

Choosing appropriate manufacturing processes to create functional surfaces is a challenging issue for some industrials. A specific surface finish can be obtained by different manufacturing processes, each of them having a different economic impact. Currently, no tool could guarantee the surface function through the choice of a manufacturing process and its associated operating parameters. This paper aims at discussing about a framework of models for selecting conventional or innovative manufacturing processes and their associated parameters with regards to surface topographies and textures. To achieve this, a concept of decomposition of database is introduced. Manufacturing processes such as, electro discharge machining, water jet machining (used for texturing surfaces), sandblasting and laser cladding are modelled. Finally, a concept that links such a database with computer aided design (CAD) software in order to integrate surfaces functionalities and manufacturing processes directly into the design step is discussed.

Towards a Standards-Based Methodology for Extending Manufacturing Process Models for Sustainability Assessment

2018 ◽  
Author(s):  
Arvind Shankar Raman ◽  
Karl R. Haapala ◽  
K. C. Morris
Keyword(s):  
Manufacturing Process ◽  
Sustainability Assessment ◽  
Building Blocks ◽  
Cnc Machining ◽  
Process Models ◽  
Machining Processes ◽  
Complex Processes ◽  
Information Models ◽  
Computer Numerically Controlled ◽  
Application Specific

Over the past decade, several efforts have characterized manufacturing processes from a sustainability perspective. In addition, frameworks, methodologies, and standards development for characterizing and linking unit manufacturing process (UMP) models to construct manufacturing system models for supporting sustainability assessment have been pursued. In this paper these research efforts are first briefly reviewed, and then, ASTM standards derived from this work are described and built upon. The contribution of this research is to demonstrate how more formalization of these prior efforts will facilitate systematic reuse of developed models by encapsulating different aspects of complex processes into reusable building blocks. The research proposes a methodology to define template UMP information models, which can further be abstracted and customized to represent an application-specific, upgraded manufacturing process. The methodology developed is based on the ASTM standards of characterizing manufacturing process for sustainability characterization. The approach is demonstrated for analyzing manual and computer numerically controlled (CNC) machining processes.

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