scholarly journals Multifunctionality of Polypyrrole Polyethyleneoxide Composites: Concurrent Sensing, Actuation and Energy Storage

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2060 ◽  
Author(s):  
Nguyen Quang Khuyen ◽  
Rudolf Kiefer ◽  
Zane Zondaka ◽  
Gholamreza Anbarjafari ◽  
Anna-Liisa Peikolainen ◽  
...  
Keyword(s):  
Energy Storage ◽  
Material Properties ◽  
Electrochemical Reaction ◽  
Charge Storage ◽  
Specific Charge ◽  
Parallel Study ◽  
Reaction Energy ◽  
Charge Densities ◽  
Simultaneous Variation

In films of conducting polymers, the electrochemical reaction(s) drive the simultaneous variation of different material properties (reaction multifunctionality). Here, we present a parallel study of actuation-sensing-energy storage triple functionality of polypyrrole (PPy) blends with dodecylbenzenesulfonate (DBS-), PPy/DBS, without and with inclusion of polyethyleneoxide, PPy-PEO/DBS. The characterization of the response of both materials in aqueous solutions of four different salts indicated that all of the actuating, sensing and charge storage responses were, independent of the electrolyte, present for both materials, but stronger for the PPy-PEO/DBS films: 1.4× higher strains, 1.3× higher specific charge densities, 2.5× higher specific capacitances and increased ion-sensitivity towards the studied counterions. For both materials, the reaction energy, the material potential and the strain variations adapt to and sense the electrical and chemical (exchanged cation) conditions. The driving and the response of actuation, sensing and charge can be controlled/read, simultaneously, via just two connecting wires. Only the cooperative actuation of chemical macromolecular motors from functional cells has such chemical multifunctionality.

Thermal characterization of ABS-Graphene blended three dimensional printed functional prototypes for electro chemical energy storage

2018 ◽  
Vol 1 (1) ◽  
pp. 1-11 ◽  
Author(s):  
Kamaljit Singh Boparai ◽  
Rupinder Singh
Keyword(s):  
Energy Storage ◽  
Structural Changes ◽  
Fused Deposition Modeling ◽  
Morphological Changes ◽  
Three Dimensional ◽  
Thermal Characterization ◽  
Chemical Energy ◽  
Flow Index ◽  
Fused Deposition

This study highlights the thermal characterization of ABS-Graphene blended three dimensional (3D) printed functional prototypes by fused deposition modeling (FDM) process. These functional prototypes have some applications as electro-chemical energy storage devices (EESD). Initially, the suitability of ABS-Graphene composite material for FDM applications has been examined by melt flow index (MFI) test. After establishing MFI, the feedstock filament for FDM has been prepared by an extrusion process. The fabricated filament has been used for printing 3D functional prototypes for printing of in-house EESD. The differential scanning calorimeter (DSC) analysis was conducted to understand the effect on glass transition temperature with the inclusion of Graphene (Gr) particles. It has been observed that the reinforced Gr particles act as a thermal reservoir (sink) and enhances its thermal/electrical conductivity. Also, FT-IR spectra realized the structural changes with the inclusion of Gr in ABS matrix. The results are supported by scanning electron microscopy (SEM) based micrographs for understanding the morphological changes.

scholarly journals Exploiting the Amazing Diversity of Natural Source-Derived Polysaccharides: Modern Procedures of Isolation, Engineering, and Optimization of Antiviral Activities

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 136
Author(s):  
Bimalendu Ray ◽  
Martin Schütz ◽  
Shuvam Mukherjee ◽  
Subrata Jana ◽  
Sayani Ray ◽  
...  
Keyword(s):  
Structural Characteristics ◽  
Antiviral Drug ◽  
Natural Source ◽  
Target Interaction ◽  
Charge Densities ◽  
Linkage Pattern ◽  
Naturally Occurring ◽  
Antiviral Activities ◽  
One Step

Naturally occurring polysaccharide sulfates are highly diverse, owning variations in the backbone structure, linkage pattern and stereochemistry, branching diversity, sulfate content and positions of sulfate group(s). These structural characteristics bring about diverse sulfated polymers with dissimilar negative charge densities and structure–activity relationships. Herein, we start with a short discussion of techniques needed for extraction, purification, chemical sulfation, and structural characterization of polysaccharides. Processes of isolation and sulfation of plant-derived polysaccharides are challenging and usually involve two steps. In this context, we describe an integrated extraction-sulfation procedure that produces polysaccharide sulfates from natural products in one step, thereby generating additional pharmacological activities. Finally, we provide examples of the spectrum of natural source-derived polysaccharides possessing specific features of bioactivity, in particular focusing on current aspects of antiviral drug development and drug–target interaction. Thus, the review presents a detailed view on chemically engineered polysaccharides, especially sulfated derivatives, and underlines their promising biomedical perspectives.

The Elastic Characterization of Composite Based on Ultrasonic Waves

2021 ◽  
Author(s):  
Y. H. Park ◽  
J. Dana
Keyword(s):  
Composite Materials ◽  
Fatigue Failure ◽  
Elastic Constants ◽  
Material Properties ◽  
Weight Ratio ◽  
Transversely Isotropic ◽  
Ultrasonic Waves ◽  
Material Strength ◽  
Isotropic Composite

Abstract Anisotropic composite materials have been extensively utilized in mechanical, automotive, aerospace and other engineering areas due to high strength-to-weight ratio, superb corrosion resistance, and exceptional thermal performance. As the use of composite materials increases, determination of material properties, mechanical analysis and failure of the structure become important for the design of composite structure. In particular, the fatigue failure is important to ensure that structures can survive in harsh environmental conditions. Despite technical advances, fatigue failure and the monitoring and prediction of component life remain major problems. In general, cyclic loadings cause the accumulation of micro-damage in the structure and material properties degrade as the number of loading cycles increases. Repeated subfailure loading cycles cause eventual fatigue failure as the material strength and stiffness fall below the applied stress level. Hence, the stiffness degradation measurement can be a good indication for damage evaluation. The elastic characterization of composite material using mechanical testing, however, is complex, destructive, and not all the elastic constants can be determined. In this work, an in-situ method to non-destructively determine the elastic constants will be studied based on the time of flight measurement of ultrasonic waves. This method will be validated on an isotropic metal sheet and a transversely isotropic composite plate.

scholarly journals Fabrication and Characterization of Laser Scribed Supercapacitor Based on Polyimide for Energy Storage

2018 ◽  
Vol 778 ◽  
pp. 181-186 ◽  
Author(s):  
Tayyaba Malik ◽  
Shayan Naveed ◽  
Muhammad Muneer ◽  
Mohammad Ali Mohammad
Keyword(s):  
Energy Storage ◽  
Research Work ◽  
Electrical Energy ◽  
Energy Storage Devices ◽  
Super Capacitor ◽  
Storage Devices ◽  
Voltage Sweep ◽  
Tremendous Amount ◽  
The Stability

Recently, supercapacitors have attracted a tremendous amount of attention as energy-storage devices due to their high-power density, fast charge–discharge ability, excellent reversibility, and long cycling life. In this research work, we demonstrate a laser scribed super capacitor based on polyimide (PI) substrate for the storage of electrical energy. PI substrate of thickness 200μm and area 1cm × 1cm was reduced by a laser engraver with a 450 nm wavelength in the form of stackable supercapacitor electrodes. Although, PI itself exhibits non-conductive behavior; however, by laser irradiation we change the surface properties of PI and reduce its resistance. The chemical property of irradiated PI was characterized with XRD where the carbon peak was observed at 2*theta = 25.44, which confirms the reduction of PI material in to a graphene-like substance. The electrical conductivity was analyzed with a probe station and observed to be 1.6mS. Two conductive regions were assembled into a capacitor device by sandwiching a PVA/H3PO4 electrolyte in between. During the charging and discharging characterization of the capacitor device, current density was observed to be 1.5mA/cm2. Capacitance versus voltage analysis was carried out and the device showed 75mF/cm2 against a voltage sweep of ±2V. The galvanostatic charging and discharging curve shows a symmetric behavior with respect to time exhibiting the stability and durability of the device.

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