scholarly journals Thermoreversible Polymer Gels in DMF Formed from Charge- and Crystallization-Induced Assembly

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2056
Author(s):  
Tao Zhang ◽  
Guangtao Chang ◽  
Qipeng Guo

Polymer organogels formed through dynamic interactions are interesting for various applications. The fabrication of polymer organogels in polar solvents through ionic interaction is rare, although such organogels in non-polar organic solvents have been well studied. Herein, polymer organogels in a polar solvent N,N-dimethyl formamide (DMF) were fabricated from a triblock copolymer, poly(4-vinyl pyridine)-block-poly(ethylene glycol)-block-poly(4-vinyl pyridine) (4VPm-EGn-4VPm), and a fluorinated surfactant, perfluorooctanoic acid (PFOA), and their microphase separation and properties were studied. Ordered microphase separation and the crystalline structures were revealed by small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS), respectively. All the 4VPm-EGn-4VPm/PFOA organogels are sensitive to temperature, and the ratio of PFOA to pyridine groups reversibly. The polymer organogels are also responsive to triethylamine and triethylammonium acetate.

1995 ◽  
Vol 2 (1) ◽  
pp. 63-70 ◽  
Author(s):  
Kung Linliu ◽  
Show-An Chen ◽  
T. L. Yu ◽  
Tsang-Lang Lin ◽  
Chih-Hao Lee ◽  
...  

1996 ◽  
Vol 100 (5) ◽  
pp. 1725-1730 ◽  
Author(s):  
B. K. Annis ◽  
J. D. Londono ◽  
G. D. Wignall ◽  
R. G. Snyder

1991 ◽  
Vol 24 (22) ◽  
pp. 5980-5990 ◽  
Author(s):  
C. Santa Cruz ◽  
N. Stribeck ◽  
H. G. Zachmann ◽  
F. J. Balta Calleja

1996 ◽  
Vol 29 (22) ◽  
pp. 7034-7037 ◽  
Author(s):  
Chang Hyung Lee ◽  
Hiromu Saito ◽  
Takashi Inoue ◽  
Shuichi Nojima

2000 ◽  
Vol 33 (10) ◽  
pp. 3818-3827 ◽  
Author(s):  
Shoichi Kutsumizu ◽  
Hiroyuki Tagawa ◽  
Yoshio Muroga ◽  
Shinichi Yano

2008 ◽  
Vol 41 (15) ◽  
pp. 5818-5829 ◽  
Author(s):  
Michelle M. Mok ◽  
Saswati Pujari ◽  
Wesley R. Burghardt ◽  
Christine M. Dettmer ◽  
SonBinh T. Nguyen ◽  
...  

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