scholarly journals Polymer Brush Coating and Adhesion Technology at Scale

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1475 ◽  
Author(s):  
Kristian Birk Buhl ◽  
Asger Holm Agergaard ◽  
Mie Lillethorup ◽  
Jakob Pagh Nikolajsen ◽  
Steen Uttrup Pedersen ◽  
...  
Keyword(s):  
Polymer Brushes ◽  
High Performance ◽  
Large Scale ◽  
Polymer Brush ◽  
Dissimilar Materials ◽  
Industrial Applications ◽  
Polymer Materials ◽  
Full Potential ◽  
Scale Production ◽  
Precise Control

Creating strong joints between dissimilar materials for high-performance hybrid products places high demands on modern adhesives. Traditionally, adhesion relies on the compatibility between surfaces, often requiring the use of primers and thick bonding layers to achieve stable joints. The coatings of polymer brushes enable the compatibilization of material surfaces through precise control over surface chemistry, facilitating strong adhesion through a nanometer-thin layer. Here, we give a detailed account of our research on adhesion promoted by polymer brushes along with examples from industrial applications. We discuss two fundamentally different adhesive mechanisms of polymer brushes, namely (1) physical bonding via entanglement and (2) chemical bonding. The former mechanism is demonstrated by e.g., the strong bonding between poly(methyl methacrylate) (PMMA) brush coated stainless steel and bulk PMMA, while the latter is shown by e.g., the improved adhesion between silicone and titanium substrates, functionalized by a hydrosilane-modified poly(hydroxyethyl methacrylate) (PHEMA) brush. This review establishes that the clever design of polymer brushes can facilitate strong bonding between metals and various polymer materials or compatibilize fillers or nanoparticles with otherwise incompatible polymeric matrices. To realize the full potential of polymer brush functionalized materials, we discuss the progress in the synthesis of polymer brushes under ambient and scalable industrial conditions, and present recent developments in atom transfer radical polymerization for the large-scale production of brush-modified materials.

Recent advances in graphene based nano-composites for automotive and off-highway vehicle applications

2019 ◽  
Vol 03 ◽  
Author(s):  
Ramkumar Kandasamy
Keyword(s):  
Composite Materials ◽  
Polymer Matrix ◽  
High Performance ◽  
Large Scale ◽  
Dissimilar Materials ◽  
Nano Composites ◽  
Scale Production ◽  
Machinery Industry ◽  
Nonlinear Properties ◽  
Design Engineers

: Nano-composites comprised of a polymer matrix and various types of nanosized fillers have remained as one of the most important engineering materials and continue to draw great interest in the research community and industry. In particular, graphene based nano-composites with high thermal conductivity, excellent mechanical, electrical and optical properties, becomes important and promising filler for making the next generation, high performance composite materials. : Automotive and off-highway machinery industry are extensively viewed as being the industry in which the highest volume of advanced composite materials such as graphene based nano-composites will be used in the future to produce lighter, stronger, more energy-efficient, and safe vehicles. Design, modeling, analyzing and methods for large-scale production of the graphene based nano-composites in automotive and off-highway machinery applications considering it’s mechanical, functional and interface properties between the graphene and polymer matrix under severe loading conditions is challenging, potentially due to nonlinear properties, joining of dissimilar materials and high demand of computations. While graphene based material strategies have been investigated and demonstrated to be effective for structural application in various industries includes electronics, electromechanical and energy systems, currently there is limited research highlighting the specific knowledge available for design engineers and researchers concerned with lightweight and stronger solutions by use of graphene based materials for automotive off-highway vehicle applications. : The present review presents, an overview of the latest studies that utilize graphene-based nanomaterials and their composites in automotive and off-highway machinery applications. First, the paper describes the concept of traditional composites used in present engineering industries considering its advantages and limitations, then highlights the key benefits of using nanostructured carbon material, such as graphene through some recent studies available in the literature. Then depicts the various mechanisms of integrating graphene as polymer reinforcements within composite materials, which have been found based on the survey, and their related modeling, designing, and manufacturing capabilities suitable for automotive and off-highway machinery industry. Finally outlines the available experimental evidence for graphene based composites. In order to lay the groundwork for future work in this exciting area, the paper discusses close by several future prospects as well as the current challenges in this field.

Scalable Microfluidic Platform for Flexible Configuration of and Experiments with Microtissue Multiorgan Models

2018 ◽  
Vol 24 (1) ◽  
pp. 79-95 ◽  
Author(s):  
Christian Lohasz ◽  
Nassim Rousset ◽  
Kasper Renggli ◽  
Andreas Hierlemann ◽  
Olivier Frey
Keyword(s):  
Large Scale ◽  
Plastic Material ◽  
Microtiter Plate ◽  
Scale Production ◽  
Experimental Conditions ◽  
Precise Control ◽  
Open Design ◽  
Gravity Driven ◽  
Gravity Driven Flow

Microphysiological systems hold the promise to increase the predictive and translational power of in vitro substance testing owing to their faithful recapitulation of human physiology. However, the implementation of academic developments in industrial settings remains challenging. We present an injection-molded microfluidic microtissue (MT) culture chip that features two channels with 10 MT compartments each and that was designed in compliance with microtiter plate standard formats. Polystyrene as a chip material enables reliable, large-scale production and precise control over experimental conditions due to low adsorption or absorption of small, hydrophobic molecules at or into the plastic material in comparison with predecessor chips made of polydimethylsiloxane. The chip is operated by tilting, which actuates gravity-driven flow between reservoirs at both ends of every channel, so that the system does not require external tubing or pumps. The flow rate can be modulated by adjusting the tilting angle on demand. The top-open design of the MT compartment enables efficient MT loading using standard or advanced pipetting equipment, ensures oxygen availability in the chip, and allows for high-resolution imaging. Every channel can be loaded with up to 10 identical or different MTs, as demonstrated by culturing liver and tumor MTs in the same medium channel on the chip.

scholarly journals Continuous, Strong, Porous Silk Firoin-Based Aerogel Fibers toward Textile Thermal Insulation

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1899 ◽  
Author(s):  
Haiwei Yang ◽  
Zongqian Wang ◽  
Zhi Liu ◽  
Huan Cheng ◽  
Changlong Li
Keyword(s):  
Heat Transfer ◽  
Thermal Insulation ◽  
Hollow Fiber ◽  
High Performance ◽  
Large Scale ◽  
Low Density ◽  
Potential Candidate ◽  
Scale Production ◽  
Insulation Material ◽  
High Porosity

Aerogel fiber, with the characteristics of ultra-low density, ultra-high porosity, and high specific surface area, is the most potential candidate for manufacturing wearable thermal insulation material. However, aerogel fibers generally show weak mechanical properties and complex preparation processes. Herein, through firstly preparing a cellulose acetate/polyacrylic acid (CA/PAA) hollow fiber using coaxial wet-spinning followed by injecting the silk fibroin (SF) solution into the hollow fiber, the CA/PAA-wrapped SF aerogel fibers toward textile thermal insulation were successfully constructed after freeze-drying. The sheath (CA/PAA hollow fiber) possesses a multiscale porous structure, including micropores (11.37 ± 4.01 μm), sub-micron pores (217.47 ± 46.16 nm), as well as nanopores on the inner (44.00 ± 21.65 nm) and outer (36.43 ± 17.55 nm) surfaces, which is crucial to the formation of a SF aerogel core. Furthermore, the porous CA/PAA-wrapped SF aerogel fibers have many advantages, such as low density (0.21 g/cm3), high porosity (86%), high strength at break (2.6 ± 0.4 MPa), as well as potential continuous and large-scale production. The delicate structure of multiscale porous sheath and ultra-low-density SF aerogel core synergistically inhibit air circulation and limit convective heat transfer. Meanwhile, the high porosity of aerogel fibers weakens heat transfer and the SF aerogel cellular walls prevent infrared radiation. The results show that the mat composed of these aerogel fibers exhibits excellent thermal insulating properties with a wide working temperature from −20 to 100 °C. Therefore, this SF-based aerogel fiber can be considered as a practical option for high performance thermal insulation.

scholarly journals Superior Pseudocapacitive Storage of a Novel Ni3Si2/NiOOH/Graphene Nanostructure for an All-Solid-State Supercapacitor

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Jing Ning ◽  
Maoyang Xia ◽  
Dong Wang ◽  
Xin Feng ◽  
Hong Zhou ◽  
...  
Keyword(s):  
Solid State ◽  
High Performance ◽  
Large Scale ◽  
Specific Capacity ◽  
Three Dimensional ◽  
Chemical Vapor ◽  
Specific Area ◽  
High Energy ◽  
Scale Production ◽  
Free Standing

Abstract Recent developments in the synthesis of graphene-based structures focus on continuous improvement of porous nanostructures, doping of thin films, and mechanisms for the construction of three-dimensional architectures. Herein, we synthesize creeper-like Ni3Si2/NiOOH/graphene nanostructures via low-pressure all-solid melting-reconstruction chemical vapor deposition. In a carbon-rich atmosphere, high-energy atoms bombard the Ni and Si surface, and reduce the free energy in the thermodynamic equilibrium of solid Ni–Si particles, considerably catalyzing the growth of Ni–Si nanocrystals. By controlling the carbon source content, a Ni3Si2 single crystal with high crystallinity and good homogeneity is stably synthesized. Electrochemical measurements indicate that the nanostructures exhibit an ultrahigh specific capacity of 835.3 C g−1 (1193.28 F g−1) at 1 A g−1; when integrated as an all-solid-state supercapacitor, it provides a remarkable energy density as high as 25.9 Wh kg−1 at 750 W kg−1, which can be attributed to the free-standing Ni3Si2/graphene skeleton providing a large specific area and NiOOH inhibits insulation on the electrode surface in an alkaline solution, thereby accelerating the electron exchange rate. The growth of the high-performance composite nanostructure is simple and controllable, enabling the large-scale production and application of microenergy storage devices.

scholarly journals Towards High Performance Chemical Vapour Deposition V2O5 Cathodes for Batteries Employing Aqueous Media

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5558
Author(s):  
Dimitra Vernardou ◽  
Charalampos Drosos ◽  
Andreas Kafizas ◽  
Martyn E. Pemble ◽  
Emmanouel Koudoumas
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Large Scale ◽  
Electrode Materials ◽  
Low Cost ◽  
Aqueous Media ◽  
Chemical Vapour ◽  
Cost Effective ◽  
Scale Production ◽  
Environmentally Safe

The need for clean and efficient energy storage has become the center of attention due to the eminent global energy crisis and growing ecological concerns. A key component in this effort is the ultra-high performance battery, which will play a major role in the energy industry. To meet the demands in portable electronic devices, electric vehicles, and large-scale energy storage systems, it is necessary to prepare advanced batteries with high safety, fast charge ratios, and discharge capabilities at a low cost. Cathode materials play a significant role in determining the performance of batteries. Among the possible electrode materials is vanadium pentoxide, which will be discussed in this review, due to its low cost and high theoretical capacity. Additionally, aqueous electrolytes, which are environmentally safe, provide an alternative approach compared to organic media for safe, cost-effective, and scalable energy storage. In this review, we will reveal the industrial potential of competitive methods to grow cathodes with excellent stability and enhanced electrochemical performance in aqueous media and lay the foundation for the large-scale production of electrode materials.

scholarly journals Rapid estimation of notch stress intensity factors in 3D large-scale welded structures using the peak stress method

2018 ◽  
Vol 165 ◽  
pp. 17004 ◽  
Author(s):  
Alberto Campagnolo ◽  
Giovanni Meneghetti
Keyword(s):  
Stress Intensity ◽  
High Performance ◽  
Degrees Of Freedom ◽  
Large Scale ◽  
Peak Stress ◽  
Industrial Applications ◽  
Mode I ◽  
Present Contribution ◽  
Notch Stress ◽  
Welded Structure

The Peak Stress Method (PSM) is an engineering, FE-oriented application of the notch stress intensity factor (NSIF) approach to fatigue design of welded joints, which takes advantage of the singular linear elastic peak stresses from FE analyses with coarse meshes. Originally, the PSM was calibrated to rapidly estimate the NSIFs by using 3D, eight-node brick elements, taking advantage of the submodeling technique. 3D modelling of large-scale structures is increasingly adopted in industrial applications, thanks to the growing spread of high-performance computing (HPC). Based on this trend, the application of PSM by means of 3D models should possibly be even more speeded up. To do this, in the present contribution the PSM has been calibrated under mode I, II and III loadings by using ten-node tetra elements, which are able to directly discretize complex 3D geometries without the need for submodels. The calibration of the PSM has been carried out by analysing several 3D mode I, II and III problems. Afterwards, an applicative example has been considered, which is relevant to a large-scale steel welded structure, having overall size on the order of meters. Two 3D FE models, having global size of tetra elements equal to 5 and 1.66 mm, have been solved by taking advantage of HPC, being the global number of degrees of freedom equal to 10 and 140 millions, respectively. The NSIFs values estimated at the toe and root sides according to the PSM have been compared with those calculated by adopting a shell-to-solid technique.

Porous micro-spherical LiFePO4/CNT nanocomposite for high-performance Li-ion battery cathode material

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37830-37836 ◽  
Author(s):  
Wei Wei ◽  
Linlin Guo ◽  
Xiaoyang Qiu ◽  
Peng Qu ◽  
Maotian Xu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Cathode Material ◽  
High Performance ◽  
Large Scale ◽  
Low Cost ◽  
Scale Production ◽  
Li Ion Battery ◽  
Excellent Performance ◽  
Large Scale Production ◽  
Li Ion

Although many routes have been developed that can efficiently improve the electrochemical performance of LiFePO4 cathodes, few of them meet the urgent industrial requirements of large-scale production, low cost and excellent performance.

scholarly journals Environmental and Economic Analysis of FDM, SLS and MJF Additive Manufacturing Technologies

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4161 ◽  
Author(s):  
Vincenzo Tagliaferri ◽  
Federica Trovalusci ◽  
Stefano Guarino ◽  
Simone Venettacci
Keyword(s):  
Additive Manufacturing ◽  
High Performance ◽  
Large Scale ◽  
Fused Deposition Modeling ◽  
Production Capacity ◽  
Optimal Choice ◽  
Scale Production ◽  
Fused Deposition ◽  
Manufacturing Technologies ◽  
The Impact

In this study, the authors present a comparative analysis of different additive manufacturing (AM) technologies for high-performance components. Four 3D printers, currently available on the Italian national manufacturing market and belonging to three different AM technologies, were considered. The analysis focused on technical aspects to highlight the characteristics and performance limits of each technology, economic aspects to allow for an assessment of the costs associated with the different processes, and environmental aspects to focus on the impact of the production cycles associated with these technologies on the ecosystem, resources and human health. This study highlighted the current limits of additive manufacturing technologies in terms of production capacity in the case of large-scale production of plastic components, especially large ones. At the same time, this study highlights how the geometry of the object to be developed greatly influences the optimal choice between the various AM technologies, in both technological and economic terms. Fused deposition modeling (FDM) is the technology that exhibits the greatest limitations hindering mass production due to production times and costs, but also due to the associated environmental impact.

scholarly journals High-Level Production of a Thermostable Mutant of Yarrowia lipolytica Lipase 2 in Pichia pastoris

2019 ◽  
Vol 21 (1) ◽  
pp. 279
Author(s):  
Qinghua Zhou ◽  
Zhixin Su ◽  
Liangcheng Jiao ◽  
Yao Wang ◽  
Kaixin Yang ◽  
...  
Keyword(s):  
Pichia Pastoris ◽  
Yarrowia Lipolytica ◽  
Large Scale ◽  
Gene Dosage ◽  
Life Time ◽  
Industrial Applications ◽  
Culture Conditions ◽  
Scale Production ◽  
Large Scale Production ◽  
High Level

As a promising biocatalyst, Yarrowia lipolytica lipase 2 (YlLip2) is limited in its industrial applications due to its low thermostability. In this study, a thermostable YlLip2 mutant was overexpressed in Pichia pastoris and its half-life time was over 30 min at 80 °C. To obtain a higher protein secretion level, the gene dosage of the mutated lip2 gene was optimized and the lipase activity was improved by about 89%. Then, the YlLip2 activity of the obtained strain further increased from 482 to 1465 U/mL via optimizing the shaking flask culture conditions. Subsequently, Hac1p and Vitreoscilla hemoglobin (VHb) were coexpressed with the YlLip2 mutant to reduce the endoplasmic reticulum stress and enhance the oxygen uptake efficiency in the recombinant strains, respectively. Furthermore, high-density fermentations were performed in a 3 L bioreactor and the production of the YlLip2 mutant reached 9080 U/mL. The results demonstrated that the expression level of the thermostable YlLip2 mutant was predominantly enhanced via the combination of these strategies in P. pastoris, which forms a consolidated basis for its large-scale production and future industrial applications.

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