scholarly journals Influence of the Degree of Cure in the Bulk Properties of Graphite Nanoplatelets Nanocomposites Printed via Stereolithography

Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1103 ◽  
Author(s):  
Alberto S. De León ◽  
Sergio I. Molina

In this work, we report on the fabrication via stereolithography (SLA) of acrylic-based nanocomposites using graphite nanoplatelets (GNPs) as an additive. GNPs are able to absorb UV–Vis radiation, thus blocking partial or totally the light path of the SLA laser. Based on this, we identified a range of GNP concentrations below 2.5 wt %, where nanocomposites can be successfully printed. We show that, even though GNP is well-dispersed along the polymeric matrix, nanocomposites presented lower degrees of cure and therefore worse mechanical properties when compared with pristine resin. However, a post-processing at 60 °C with UV light for 1 h eliminates this difference in the degree of cure, reaching values above 90% in all cases. In these conditions, the tensile strength is enhanced for 0.5 wt % GNP nanocomposites, while the stiffness is increased for 0.5–1.0 wt % GNP nanocomposites. Finally, we also demonstrate that 2.5 wt % GNP nanocomposites possess characteristic properties of semiconductors, which allows them to be used as electrostatic dispersion materials.

2018 ◽  
Vol 53 (13) ◽  
pp. 1815-1826
Author(s):  
Sheng Cai Tan ◽  
Jimmy KW Chan ◽  
Kian Ping Loh

This paper aims to investigate the effect of co-milling-assisted exfoliation of graphite into polyethylene and alumina matrices on the mechanical properties of the composites. Tensile mechanical properties of composite materials based on polyethylene reinforced with graphite and graphite-derived fillers at 0–0.75 wt% loading were investigated, while hardness and flexural properties of alumina composites with 0.25 wt% loading of the same additives were assessed. Exfoliated graphite, applied at 0.25–0.75 wt% in pre-exfoliated form or in a co-milling-assisted fashion, has been demonstrated to be effective in enhancing the tensile strength of polyethylene composites. Similar enhancement in hardness and flexural properties was observed in alumina composites with 0.25 wt% loading of the exfoliated graphite. Co-milling-assisted exfoliated graphite nanoplatelets additive introduction has been found to effect a more desirable mechanical properties enhancement in the composites investigated in this study.


Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 384
Author(s):  
Juan Tirado-Gallegos ◽  
Paul Zamudio-Flores ◽  
José Ornelas-Paz ◽  
Claudio Rios-Velasco ◽  
Guadalupe Olivas Orozco ◽  
...  

Apple starch films were obtained from apples harvested at 60, 70, 80 and 90 days after full bloom (DAFB). Mechanical properties and water vapor permeability (WVP) were evaluated. The apple starch films at 70 DAFB presented higher values in the variables of tensile strength (8.12 MPa), elastic modulus (3.10 MPa) and lower values of water vapor permeability (6.77 × 10−11 g m−1 s−1 Pa−1) than apple starch films from apples harvested at 60, 80 and 90 DAFB. Therefore, these films were chosen to continue the study incorporating ellagic acid (EA). The EA was added at three concentrations [0.02% (FILM-EA0.02%), 0.05% (FILM-EA0.05%) and 0.1% (FILM-EA0.1%) w/w] and compared with the apple starch films without EA (FILM-Control). The films were characterized by their physicochemical, optical, morphological and mechanical properties. Their thermal stability and antioxidant capacity were also evaluated. The FILM-Control and FILM-EA0.02% showed a uniform surface, while FILM-EA0.05% and FILM-EA0.1% showed a rough surface and insoluble EA particles. Compared to FILM-Control, EA modified the values of tensile strength, elasticity modulus and elongation at break. The antioxidant capacity increased as EA concentration did. EA incorporation allowed obtaining films with higher antioxidant capacity, capable of blocking UV light with better mechanical properties than film without EA.


Author(s):  
Mohan Bangaru ◽  
Thirumal Azhagan Murugan ◽  
Rajadurai Arunachalam

In the recent days, aerospace, automotive and defense sectors have been the main driving force behind the search of lighter and stronger materials in order to use in the production of vehicles. The growing demand for the production of light weight structural components and systems is fulfilled by the development of innovative metallic materials such as composites and alloys particularly based on aluminium because of their desirable properties such as low density, good castability, excellent strength and excellent corrosion resistance. Widely employed processes such as gravity and pressure die casting are used for processing aluminium alloys but the components exhibit several casting defects such as porosity, cracks, segregation and hot tears etc. This drives the industries to develop new processes which produce defect free components in shorter time as they have been under competitive pressure. Of the many such processes, squeeze casting has good capacity to produce less defective components. Squeeze casting is the process in which the molten metal solidifies under the application of pressure. The development of Aluminium Matrix Composites (AMCs) through squeeze casting has been one of the major areas of research in recent times. Research works on AMCs reinforced with micrometric particles have shown that the ability to strengthen the matrix alloy by them is lesser than nanometric particles. Metal matrices reinforced with nanoparticles are characterized by significant improvement in strength and wear resistance, improved ductility and improved dimensional stability at elevated temperatures. But, nanosized ceramic particles constitute problems during fabrication as it is extremely difficult to obtain uniform dispersion of nanoparticles in liquid metals owing to their high viscosity, poor wettability in the metal matrix, and a large surface-to-volume ratio. These problems induce agglomeration and clustering of nanoparticles. The nanoparticles can be dispersed uniformly in the metal matrix by means of employing ultrasonic cavitations. Ultrasonic cavitations include the formation, growth and collapse of micro-bubbles in liquids, under cyclic high intensity ultrasonic waves. The cavitation bubbles collapse and generate a huge amount of energy, which could be used in dispersion of the nanoparticles more uniformly in the melt. In this study, squeeze casting is combined with ultrasonic cavitations to develop Metal Matrix Nanocomposites (MMNCs) of AA6061 – SiCp as a maiden attempt. The impact of varying volume percentage of SiCp nanoparticles (average size of 45 nm – 65 nm) by ultrasonic cavitations on mechanical properties such as ultimate tensile strength and hardness exhibited by MMNCs were analyzed. In this research, volume percentage of SiCp nanoparticles was varied at 0.4%, 0.8% and 1.2% respectively by employing ultrasonic vibrations at the amplitude of 70 μm to the melt of AA6061. The melt of AA6061-SiCp was poured into the pre heated die cavity and squeeze pressure of 105 Mpa was applied over it for a certain period while developing MMNCs. Scanning Electron Microscope (SEM) images showed the uniform distribution of SiCp nanoparticles in AA6061 matrix. Energy Dispersive Spectroscopy (EDS) in SEM confirmed the incorporation of SiCp in AA6061 matrix. The obtained results confirmed the effectiveness of ultrasonic cavitations in squeeze casting process to disperse the nanoparticles of SiCp uniformly in AA6061 matrix. The mechanical properties of MMNCs such as ultimate tensile strength and hardness exhibited an increasing trend with respect to the increase in volume percentage of SiCp nanoparticles. Thus there prevails a great scope to develop MMNCs of aluminium using ultrasonic cavitations in squeeze casting process.


2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
Kareem Nada ◽  
Omar El-Mowafy

To investigate the effect of prepolymerization warming on composites' mechanical properties, three composites were evaluated: Clearfil Majesty (CM) (Kuraray), Z-100 (3M/ESPE), and Light-Core (LC) (Bisco). Specimens were prepared from each composite at room temperature as control and 2 higher temperatures (37∘Cand54∘C) to test surface hardness (SH), compressive strength (CS), and diametral tensile strength (DTS). Data were statistically analyzed using ANOVA and Fisher's LSD tests. Results revealed that prewarming CM and Z100 specimens significantly improved their SH mean values (P<0.05). Prewarming also improved mean CS values of Z100 specimens (P<0.05). Furthermore, DTS mean value of CM prepared at52∘was significantly higher than that of room temperature specimens (P<0.05). KHN, CS, and DTS mean values varied significantly among the three composites. In conclusion, Prewarming significantly enhanced surface hardness of 2 composites. Prewarming also improved bulk properties of the composites; however, this improvement was significant in only some of the tested materials.


2013 ◽  
Vol 748 ◽  
pp. 165-169 ◽  
Author(s):  
M. Rahmah Siti ◽  
Anika Zafiah M. Rus ◽  
S. Nurulsaidatulsyida ◽  
D.A. Talib ◽  
T.M.Y.S. Tuan Ya

This study reports on the effect of UV-light on the mechanical properties of bio polymer thin films (BPF) doped with 10 % Titanium Dioxide (TiO2). Bio monomer was mixed with 4, 4-methylenebis (phenylisocyanate) (MDI) to produce neat BPF and TiO2 was added to form BPF doped with 10 % TiO2. The film samples were irradiated in UV Accelerated Weatherometer at 50 °C with different exposure time. Universal Testing Machine was used to measure the tensile strength and the fracture surfaces of the tensile specimens were observed by Scanning Electron Microscopy (SEM). The maximum tensile strength of UV irradiated neat BPF is lower than BPF doped with 10 % TiO2 of 3.5 MPa and 4.2 MPa respectively. Stress of neat BPF was decreased from 3.7 MPa to 3.2 MPa after 144 hours of UV exposure at 50 °C while BPF doped with 10 % TiO2 decrease from 4.7 to 3.6 MPa. The Modulus Young of neat BPF is lower than BPF doped with 10 % TiO2 which are 0.32 GPa and 0.33 GPa respectively. The cumulative strain percentage irradiated neat BPF is lower than BPF doped with 10 % TiO2 with 98.7 % and 113.7 % respectively. Unexposed UV light of neat BPF and BPF doped with 10 % TiO2 were observed by SEM shows smooth fracture and brittle fracture respectively. Neat BPF and BPF doped with 10 % TiO2 exposed to UV light show higher ductility property as compared to unexposed BPF. The higher the exposure time of BPF to UV light, revealed systematic increment of tensile strength due to increased crosslink between isocyanate and hydroxyl group.


2015 ◽  
Vol 30 (8) ◽  
pp. 1045-1055 ◽  
Author(s):  
Dejin Zhao ◽  
Yanling Guo ◽  
Kaiyi Jiang ◽  
Hui Zhang

A new type of biocomposite, bamboo flour/copolyester (BFCP) composite for selective laser sintering (SLS™) was studied in this article. The bamboo flour was made from the bamboo residual of the bamboo production collected from a chopsticks factory. The BFCP composites of three mixture ratios (20/80, 25/75, and 30/70 (wt/wt)) were processed by SLS™. The proper processing parameters were determined by single-layer sintering methods. The mechanical properties of test specimens made from BFCP composites of three mixture ratios have been investigated. The results demonstrated that the mechanical properties of the specimens made by BFCP composite of 20/80 (wt/wt) were the best among those of the three mixture ratios and the average tensile strength, flexural strength, and impact strength of the specimens made from BFCP composite of 20/80 (wt/wt) were up to 4.14 MPa, 11.02 MPa, and 0.84 kJ m−2, respectively. The mechanical properties of specimens are extremely improved through infiltrating epoxy resin.


2022 ◽  
pp. 81-87
Author(s):  
ALEKSANDR SLIEPTSOV ◽  
RUSLAN ISKANDAROV ◽  
IGOR SLIEPTSOV ◽  
VYACHESLAV KOBZA

Purpose. Study of the influence of additive manufacturing parameters and post forming operations on complex mechanical properties of the articles formed from UV curable acrylic oligomer. Methodology. Determination of physical and mechanical properties of standard samples which was formed by additive manufacturing technics from UV curable polymer. Tensile strength and relative elongation at brake according to ISO 527-2:2012, impact strength according to: ISO 179-1:2010. Durometer hardness according to:ISO 2039-1:2001. Bending modulus according to: ISO 178:2010. Density according to: ISO 1183-1:2019Findings. Additive manufacturing parameters for stereolithography process was studied for liquid UV curable acrylic oligomer. Study was focused on influence of forming settings and post forming treatment of complex mechanical properties of final articles which was shaped as standard testing samples. Properties of additive manufactured samples was compared with the properties of samples which was cured by UV light is bulk inside shaped cavity with the same geometrical dimensions. Correct post forming treatment results in up to 2 – 3 times increase in tensile strength. Post forming treatment is necessary for achieving functional level of mechanical properties, comparable to the properties of typical industrial polymers. Study of influence of UV light exposure during additive manufacturing shows double fold increase in tensile strength but reduce overall forming speed. Impact strength increase with increasing exposure time and significantly increase with duration of post forming treatment. Post treatment operations with correct parameters can result in forming articles with level of properties sufficient for functional applications. Originality. Study was focused on mechanical properties of UV curable polymer in dependence from forming parameters of additive manufacturing process and post treatment operations. Application of correct post forming setting can lead to material properties with valuable for functional applications.Practical value Optimal parameters for additive manufacturing process based on UV curable resin and LCD exposure technology was investigated. Forming and post forming parameters significantly influence complex mechanical properties of formed articles.


2014 ◽  
Vol 911 ◽  
pp. 105-109 ◽  
Author(s):  
Nur Azrini Ramlee ◽  
C.T. Ratnam ◽  
N.H. Alias ◽  
T.A. Tengku Mohd

Addition of nanoparticles currently in polymer blends has brought tremendous transformation in polymer engineering field. Incorporation of TiO2 nanofillers is believed to enhance the physical and mechanical properties of PVC/ENR blends due to its excellent characteristics including non-toxicity, long term stability and UV light discoloration resistance. The main objective of this research work is to introduce titanium dioxide (TiO2) nanofillers in a range of 0 - 6 phr into polyvinyl chloride (PVC) and epoxidized natural rubber (ENR) blends. Modification on mechanical properties of PVC/ENR blends has successfully been carried via irradiation crosslinking technique. The addition of TiO2 nanofillers has improved the tensile strength and hardness of the nanocomposites. Nevertheless, at higher loading of 6 phr, the results obviously showed an insignificant difference of performances for both tensile strength and shore hardness properties. Upon radiation of 50 kGy, the increase in Ts of the PVC/ENR blends with addition of 4 phr TiO2 was found to be optimum before the Ts value drops with higher exposure to irradiation dose rate. Gel fraction of irradiated PVC/ENR/TiO2 nanocomposites indicates the nanocomposites are crosslinked upon electron beam irradiation. Degree of crosslink was also increased with the addition of 4 phr and 6 phr TiO2.


2010 ◽  
Vol 113-116 ◽  
pp. 1845-1848 ◽  
Author(s):  
Wei Liang Zeng ◽  
Yan Ling Guo ◽  
Zong Sheng Xin ◽  
Kai Yi Jiang

In this paper, Wood-Plastic Composite(WPC) is successfully developed to make parts by Selective Laser Sintering(SLS) rapid prototyping (RP) process according to its advantages, such as green biological, wood texture and recycled, but the most important advantage is low-cost. With optimal design of components, the parts made by WPC have good mechanical properties as well as with good laser sintering properties. In order to further improve the mechanical properties of the parts, the post-processing–infiltrating with wax–is introduced. Through post-processing, the void fraction is decreased from from 51% to 7%, the mechanical properties are significantly improved, the average tensile strength, bending strength, impact strength are 1.214 MPa, 2.73 MPa and 1.4125 kJ/m2, compared with those without post processing, the tensile strength is 87 times, the bending strength is 4.7 times and impact strength is 2.5 times, respectively.


2020 ◽  
Vol 27 (1) ◽  
pp. 139-147
Author(s):  
Jianlin Xu ◽  
Jinqiang Zhao ◽  
Chenghu Kang ◽  
Lei Niu ◽  
Jianbin Zhang ◽  
...  

AbstractIn view of the limitation of wide application of polypropylene(PP) with low strength, poor low-temperature brittleness and easy combustion, a kind of PP matrix nanocomposites was designed and prepared. Sb2O3 nanoparticles (nano-Sb2O3) modified by silane coupling agent of KH550 were dispersed into brominated polystyrene(BPS)-PP matrix by ball milling dispersion and melt blending method, respectively. And the nano-Sb2O3/BPS-PP composites samples were obtained by injection molding method. The effects of nano-Sb2O3 particles on mechanical properties of nano-Sb2O3/BPS-PP composites were investigated. The results showed that the surface of nano-Sb2O3 particles was successfully modified by the KH550 and the interfacial adhesion between nano-Sb2O3 and PP matrix was improved. With increasing of the mass fraction of nano-Sb2O3, the tensile strength and impact strength of nano-Sb2O3/BPS-PP composites were improved accompanying by increasing of crystallinity and refining grain of the composites. When the mass fraction of nano-Sb2O3 was 3 wt%, the tensile strength of nano-Sb2O3/BPS-PP composites was 43 MPa, which was 30.3% higher than that of PP. When the mass fraction of nano-Sb2O3 was 2 wt%, the impact strength of the composites was 44.19 kJ·m−2, which was 30.8% higher than that of PP.


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