scholarly journals Analysis of the Connecting Effectiveness of the Interphase Zone on the Tensile Properties of Carbon Nanotubes (CNT) Reinforced Nanocomposite

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 896 ◽  
Author(s):  
Yasser Zare ◽  
Kyong Yop Rhee
Keyword(s):  
Carbon Nanotubes ◽  
Tensile Properties ◽  
Polymer Nanocomposites ◽  
Simulation Study ◽  
Tensile Modulus ◽  
Excluded Volume ◽  
Interphase Region ◽  
Important Character

The establishment of interphase region around nanoparticles accelerates the percolating of carbon nanotubes (CNT) in polymer nanocomposites reinforced with CNT (PCNT), due to the linking productivity of interphase district before the physical connecting of nanoparticles. Therefore, the interphase is an important character in the networks of CNT in PCNT. Here, a simulation study is presented to investigate the interphase connection in the mechanical possessions of PCNT including tensile modulus and strength. A number of models comprising Takayanagi, Ouali, Pukanszky and Callister are developed by the assumption of an interphase district in the CNT excluded volume. The advanced models depict the optimistic influences of reedy and lengthy CNT besides dense interphase on the stiffness and tensile power of nanocomposites. The Pukanszky calculations depict that the interphase strength plays a more noteworthy role in the nanocomposites strength compared to the CNT length.

Interphase influences on the mechanical behavior of carbon nanotube–shape memory polymer nanocomposites: A micromechanical approach

2018 ◽  
Vol 30 (3) ◽  
pp. 463-478 ◽  
Author(s):  
MK Hassanzadeh-Aghdam ◽  
MJ Mahmoodi ◽  
R Ansari ◽  
A Darvizeh
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Shape Memory ◽  
Polymer Nanocomposites ◽  
Elastic Moduli ◽  
Volume Fraction ◽  
Shape Memory Polymer ◽  
Micromechanical Model ◽  
Elastic Behavior ◽  
Interphase Region

The effects of interphase characteristics on the elastic behavior of randomly dispersed carbon nanotube–reinforced shape memory polymer nanocomposites are investigated using a three-dimensional unit cell–based micromechanical method. The interphase region is formed due to non-bonded van der Waals interaction between a carbon nanotube and a shape memory polymer. The influences of temperature, diameter, volume fraction, and arrangement type of carbon nanotubes within the matrix as well as two interphase factors, including adhesion exponent and thickness on the carbon nanotube/shape memory polymer nanocomposite’s longitudinal and transverse elastic moduli, are explored extensively. Moreover, the results are presented for the shape memory polymer nanocomposites containing randomly oriented carbon nanotubes. The obtained results clearly demonstrate that the interphase region plays a crucial role in the modeling of the carbon nanotube/shape memory polymer nanocomposite’s elastic moduli. It is observed that the nanocomposite’s elastic moduli remarkably increase with increasing interphase thickness or decreasing adhesion exponent. It is found that when the interphase is considered in the micromechanical simulation, the shape memory polymer nanocomposite’s elastic moduli non-linearly increase as the carbon nanotube diameter decreases. The predictions of the present micromechanical model are compared with those of other analytical methods and available experiments.

scholarly journals Development of Expanded Takayanagi Model for Tensile Modulus of Carbon Nanotubes Reinforced Nanocomposites Assuming Interphase Regions Surrounding the Dispersed and Networked Nanoparticles

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 233 ◽  
Author(s):  
Yasser Zare ◽  
Kyong Yop Rhee
Keyword(s):  
Carbon Nanotubes ◽  
Volume Fraction ◽  
Tensile Modulus ◽  
Experimental Results ◽  
Volume Fractions ◽  
Interphase Region ◽  
Acceptable Agreement ◽  
Network Modulus ◽  
Neat Matrix

In this paper, we consider the interphase regions surrounding the dispersed and networked carbon nanotubes (CNT) to develop and simplify the expanded Takayanagi model for tensile modulus of polymer CNT nanocomposites (PCNT). The moduli and volume fractions of dispersed and networked CNT and the surrounding interphase regions are considered. Since the modulus of interphase region around the dispersed CNT insignificantly changes the modulus of nanocomposites, this parameter is removed from the developed model. The developed model shows acceptable agreement with the experimental results of several samples. “ER” as nanocomposite modulus per the modulus of neat matrix changes from 1.4 to 7.7 at dissimilar levels of “f” (CNT fraction in the network) and network modulus. Moreover, the lowest relative modulus of 2.2 is observed at the smallest levels of interphase volume fraction ( ϕ i < 0.017), while the highest “ ϕ i ” as 0.07 obtains the highest relative modulus of 11.8. Also, the variation of CNT size (radius and length) significantly changes the relative modulus from 2 to 20.

scholarly journals Study on the Effects of the Interphase Region on the Network Properties in Polymer Carbon Nanotube Nanocomposites

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 182 ◽  
Author(s):  
Yasser Zare ◽  
Kyong Yop Rhee
Keyword(s):  
Percolation Threshold ◽  
Polymer Nanocomposites ◽  
Volume Fraction ◽  
Excluded Volume ◽  
Positive Role ◽  
Interphase Region ◽  
Network Properties ◽  
High Fraction ◽  
Filler Network

The interphase region around nanoparticles changes the percolation threshold of long and thin nanoparticles, such as carbon nanotubes (CNT) in polymer nanocomposites. In this paper, the effects of the interphase region on the percolation threshold of nanoparticles and the network fraction are studied. New percolation threshold (φP) is defined by the role of the interphase in the excluded volume of nanoparticles (Vex). Moreover, the influences of filler and interphase size on the percolation volume fraction, the fraction of nanoparticles in the network as well as the volume fraction and relative density of the filler network are investigated. The least ranges of “φP” are obtained by thin and long CNT. Similarly, a thick interphase increases the “Vex” parameter, which causes a positive role in the percolation occurrence. Also, thin CNT and a thick interphase cause the high fraction of the filler network in the nanocomposites.

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