scholarly journals A Novel Zirconium Modified Arylacetylene Resin: Preparation, Thermal Properties and Ceramifiable Mechanism

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 684
Author(s):  
Qilin Mei ◽  
Honghua Wang ◽  
Xiaocheng Chen ◽  
Ying Wang ◽  
Zhixiong Huang
Keyword(s):  
Thermal Protection ◽  
Rapid Development ◽  
Char Yield ◽  
Curing Temperature ◽  
Dsc Analysis ◽  
High Glass Transition Temperature ◽  
Ozawa Method ◽  
Ceramic Phase ◽  
Thermal Protection Systems ◽  
Protection Systems

With the rapid development of thermal protection systems for the aerospace industry and power electronics, polyarylacetylene (PAA) resin plays an important role because of its good mechanical properties, high glass transition temperature (Tg), low water absorption, high char yield (Yc), and the fact that there is no byproduct released in the curing process. In order to further improve the thermal property of PAA based FRP for the thermal protection field, the introduction of a zirconium element into arylacetylene is promising. In this paper, zirconium modified arylacetylene (ZAA) resin was prepared by two-step synthesis. The FTIR analysis characterized its molecular structure and confirmed the products. The viscosity of ZAA was about 6.5 Pa·s when the temperature was above 120 °C. The DSC analysis showed that the ZAA had a low curing temperature, and its apparent activation energy was 103.86 kJ/mol in the Kissinger method and 106.46 kJ/mol in the Ozawa method. The dielectric constant at 1 MHz of poly(zirconium modified arylacetylene) (PZAA) was 3.4. The TG analysis showed that the temperatures of a weight loss of 5% (Td5) and char yield (Yc) at 800 °C of PZAA were 407.5 °C and 61.4%, respectively. The XRD results showed the presence of SiO2 and ZrO2 in the PZAA residue after ablation. The XRF results showed that the contents of SiO2 and ZrO2 in PZAA residual after ablation were, respectively, 15.3% and 12.4%. The SEM showed that the surface of PZAA after ablation had been covered with a dense and rigid ceramic phase composed of ZrO2 and SiO2. Therefore, the introduction of Zr into arylacetylene greatly improved the densification of the surface after ablation, and improved the heat resistant property.

Trends in the development of flexible thermal protection systems for modern aircraft

2020 ◽  
pp. 10-21
Author(s):  
V. G. Babashov ◽  
◽  
N. M. Varrik ◽  
Keyword(s):  
High Temperature ◽  
Thermal Protection ◽  
Heat Removal ◽  
Operating Conditions ◽  
Passive Protection ◽  
Thermal Protection Systems ◽  
Heat Protection ◽  
Protection Systems ◽  
Protected Surface ◽  
Flexible Panels

The emergence of new types of space and aviation technology necessitates the development of new types of thermal protection systems capable of operating at high temperature and long operating times. There are several types of thermal protection systems for different operating conditions: active thermal protection systems using forced supply of coolant to the protected surface, passive thermal protection systems using materials with low thermal conductivity without additional heat removal, high-temperature systems, which are simultaneously elements of the bearing structure and provide thermal protection, ablation materials. Heat protection systems in the form of rigid tiles and flexible panels, felt and mats are most common kind of heat protecting systems. This article examines the trends of development of flexible reusable heat protection systems intended for passive protection of aircraft structural structures from overheating.

scholarly journals Mechanical Stability of Hybrid Corrugated Sandwich Plates under Fluid-Structure-Thermal Coupling for Novel Thermal Protection Systems

2020 ◽  
Vol 10 (8) ◽  
pp. 2790
Author(s):  
Wenzheng Zhuang ◽  
Chao Yang ◽  
Zhigang Wu
Keyword(s):  
Mechanical Stability ◽  
Thermal Protection ◽  
Element Model ◽  
Parameter Study ◽  
The Novel ◽  
Thermal Coupling ◽  
Mechanical Instability ◽  
Fluid Structure ◽  
Thermal Protection Systems ◽  
Protection Systems

Hybrid corrugated sandwich (HCS) plates have become a promising candidate for novel thermal protection systems (TPS) due to their multi-functionality of load bearing and thermal protection. For hypersonic vehicles, the novel TPS that performs some structural functions is a potential method of saving weight, which is significant in reducing expensive design/manufacture cost. Considering the novel TPS exposed to severe thermal and aerodynamic environments, the mechanical stability of the HCS plates under fluid-structure-thermal coupling is crucial for preliminary design of the TPS. In this paper, an innovative layerwise finite element model of the HCS plates is presented, and coupled fluid-structure-thermal analysis is performed with a parameter study. The proposed method is validated to be accurate and efficient against commercial software simulation. Results have shown that the mechanical instability of the HCS plates can be induced by fluid-structure coupling and further accelerated by thermal effect. The influences of geometric parameters on thermal buckling and dynamic stability present opposite tendencies, indicating a tradeoff is required for the TPS design. The present analytical model and numerical results provide design guidance in the practical application of the novel TPS.

scholarly journals Methodology for Flight-Relevant Arc-Jet Testing of Flexible Thermal Protection Systems

2014 ◽  
Vol 51 (3) ◽  
pp. 789-800 ◽  
Author(s):  
Alireza Mazaheri ◽  
Walter E. Bruce ◽  
Nathaniel J. Mesick ◽  
Kenneth Sutton
Keyword(s):  
Thermal Protection ◽  
Thermal Protection Systems ◽  
Protection Systems

ZIRCONIA FIBERS AS A COMPONENT OF HIGH TEMPERATURE THERMAL INSULATION (review)

2021 ◽  
pp. 79-86
Author(s):  
V.G. Babashov ◽  
◽  
N.M. Varrik ◽  
Keyword(s):  
High Temperature ◽  
Thermal Insulation ◽  
Zirconium Oxide ◽  
Thermal Protection ◽  
Sol Gel ◽  
Precursor Solution ◽  
Technical Literature ◽  
Thermal Protection Systems ◽  
Insulation Materials ◽  
Protection Systems

Based on the analysis of recent publications of scientific and technical literature, data on the production of zirconium oxide fibers used for the manufacture of high-temperature thermal insulation materials are presented. Information is provided on various methods of obtaining zirconium oxide fibers (methods of impregnation of the template and molding of the mixture, sol-gel method of spinning a fiber-forming precursor solution), as well as on the technique of fiber molding (manual pulling, dry and wet spinning, blowing and electrospinning). The use of such fibers for the production of thermal insulation materials (felts, cords and blocks) instead of currently existing materials made of aluminum oxide-based fibers can significantly increase the operating temperatures of the thermal protection systems.

AERO-THERMO-DYNAMIC STUDY OF ULTRA-HIGH- TEMPERATURE CERAMIC COMPOSITES FOR THERMAL PROTECTION SYSTEMS AND ROCKET NOZZLES

2021 ◽  
Author(s):  
STEFANO MUNGIGUERRA ◽  
ANSELMO CECERE ◽  
RAFFAELE SAVINO
Keyword(s):  
High Temperature ◽  
Thermal Protection ◽  
Ceramic Composites ◽  
Thermal Protection Systems ◽  
Research Activities ◽  
Ablation Resistance ◽  
Protection Systems ◽  
Project Objectives ◽  
Ultra High Temperature

The most extreme aero-thermo-dynamic conditions encountered in aerospace applications include those of atmospheric re-entry, characterized by hypersonic Mach numbers, high temperatures and a chemically reacting environment, and of rocket propulsion, in which a combusting, high-pressure, supersonic flow can severely attack the surfaces of the motor internal components (particularly nozzle throats), leading to thermo-chemical erosion and consequent thrust decrease. For these applications, Ultra-High-Temperature Ceramics (UHTC), namely transition metal borides and carbides, are regarded as promising candidates, due to their excellent high-temperature properties, including oxidation and ablation resistance, which are boosted by the introduction of secondary phases, such as silicon carbide and carbon fibers reinforcement (in the so-called Ultra-High- Temperature Ceramic Matrix Composites, UHTCMC). The recent European H2020 C3HARME research project was devoted to development and characterization of new-class UHTCMCs for near-zero ablation thermal protection systems for re-entry vehicles and near-zero erosion rocket nozzles. Within the frame of the project and in collaboration with several research institutions and private companies, research activities at the University of Naples “Federico II” (UNINA) focused on requirements definition, prototypes design and test conditions identification, with the aim to increase the Technology Readiness Level (TRL) of UHTCMC up to 6. Experimental tests were performed with two facilities: an arc-jet plasma wind tunnel, where small specimens were characterized in a relevant atmospheric re-entry environment (Fig.1a), and a lab-scale hybrid rocket engine, where material testing was performed with different setups, up to complete nozzle tests, in conditions representative of real propulsive applications (Fig.1b). The characterization of the aero-thermo-chemical response and ablation resistance of different UHTCMC formulations was supported by numerical computations of fluiddynamic flowfields and materials thermal behavior. The UNINA activities provided a large database supporting the achievement of the project objectives, with development and testing of full-scale TPS assemblies and a large-size solid rocket nozzle.

scholarly journals Transformation Thermodynamics with Arbitrarily Shaped Non-Conformal Objects and Coatings

2018 ◽  
Vol 186 ◽  
pp. 01007
Author(s):  
Qingxiang Ji ◽  
Guodong Fang ◽  
Jun Liang
Keyword(s):  
Thermal Protection ◽  
Small Region ◽  
Heat Fluxes ◽  
Temperature Fields ◽  
Heat Flows ◽  
Thermal Protection Systems ◽  
Thermal Fields ◽  
Design Flexibility ◽  
Protection Systems ◽  
Concentrate Heat

In this paper we apply transformation optics theory to thermodynamics and design thermal cloaks and concentrators with arbitrarily shaped non-conformal objects and coatings. Expressions of the required material parameters are derived analytically and then validated by numerical simulations. We apply this method to design a thermal cloak which can guide the heat flow around the inner domain without perturbation to external thermal fields. In this way, the object inside the inner domain is protected from the invasion of external heat fluxes. In contrast, a concentrator is designed to concentrate heat flows into a small region without disturbing outside temperature fields, which can considerably enhance the heat density in the designed domain. The proposed method extends the design flexibility in manipulating heat flux and will find wide applications in thermal protection systems, solar cells and so on.

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