scholarly journals Quadratic Non-Linear Optical Properties of the poly(2,5-bis(but-2-ynyloxy) Benzoate Containing the 2-(ethyl(4-((4-nitrophenyl)buta-1,3-diynyl)phenyl)amino)ethanol) Chromophore

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 241
Author(s):  
Sandra L. Castañón-Alonso ◽  
Omar G. Morales-Saavedra ◽  
Marco A. Almaraz-Girón ◽  
Sandro Báez-Pimiento ◽  
Alejandro Islas-Jácome ◽  
...  
Keyword(s):  
Second Harmonic ◽  
Chemical Properties ◽  
Photonic Devices ◽  
Oriented Polymer ◽  
Non Linear ◽  
Linear Optical Properties ◽  
Linear Optical ◽  
532 Nm ◽  
Maker Fringes ◽  
And Chemical Properties

Excellent quadratic non-linear optical (ONL-2) properties of the poly(2,5-bis(but-2-ynyloxy) benzoate, containing a polar diacetylene as a chromophore, were found. According with the Maker fringes method, oriented polymer films showing an order parameter of ∼0.23 can display outstanding and stable Second Harmonic Generation (SHG) effects under off-resonant conditions (SHG-532 nm). Also, the macroscopic non-linear optical (NLO)-coefficients were evaluated under the rod-like molecular approximation, obtaining: χzzz(2) and χzxx(2) in the order of 280 ± 10 and 100 ± 10 pm V−1, respectively. The mechanical and chemical properties, in addition to the large ONL-2 coefficients exhibited by this polymer, make it a promising organic material in the development of optoelectronic/photonic devices.

scholarly journals L-alaninium perrhenate: crystal structure and non-linear optical properties

2014 ◽  
Vol 12 (10) ◽  
pp. 1016-1022 ◽  
Author(s):  
Vitor Rodrigues ◽  
Maria Costa ◽  
Etelvina Gomes ◽  
Dmitry Isakov ◽  
Michael Belsley
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Second Harmonic ◽  
Negative Ions ◽  
Damage Threshold ◽  
Linear Optics ◽  
Second Harmonic Generation Efficiency ◽  
Non Linear ◽  
Linear Optical Properties ◽  
Linear Optical

AbstractThe crystal structure and non-linear optical properties of L-alaninium perrhenate, C3H8NO2+ ReO4 −, are reported. The protonated amino acid and the perrhenate anion have their usual geometries. The three-dimensional hydrogen-bonded network can be seen as a stacking of layers parallel to the (100) planes. Each layer is formed by chains of alternating positive and negative ions along the b and c axes. Hydrogen bonding of adjacent layers forms alternating chains along the a axis. A high damage threshold and a second-harmonic generation efficiency three times that of KDP make this new material potentially useful in non-linear optics.

scholarly journals Quantum Confined Stark Effect on the Linear and Nonlinear Optical Properties of SiGe/Si Semi Oblate and Prolate Quantum Dots Grown in Si Wetting Layer

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1513
Author(s):  
Varsha ◽  
Mohamed Kria ◽  
Jawad El Hamdaoui ◽  
Laura M. Pérez ◽  
Vinod Prasad ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Quantum Dot ◽  
Electric Field ◽  
Harmonic Generation ◽  
Second Harmonic ◽  
Wetting Layer ◽  
Non Linear ◽  
Linear Optical Properties ◽  
Linear Optical

We have studied the parallel and perpendicular electric field effects on the system of SiGe prolate and oblate quantum dots numerically, taking into account the wetting layer and quantum dot size effects. Using the effective-mass approximation in the two bands model, we computationally calculated the extensive variation of dipole matrix (DM) elements, bandgap and non-linear optical properties, including absorption coefficients, refractive index changes, second harmonic generation and third harmonic generation as a function of the electric field, wetting layer size and the size of the quantum dot. The redshift is observed for the non-linear optical properties with the increasing electric field and an increase in wetting layer thickness. The sensitivity to the electric field toward the shape of the quantum dot is also observed. This study is resourceful for all the researchers as it provides a pragmatic model by considering oblate and prolate shaped quantum dots by explaining the optical and electronic properties precisely, as a consequence of the confined stark shift and wetting layer.

Aggregation-Induced Linear and Non-Linear Optical Properties of Four Hydroxy-Substituted Analogues of 2,4-Bis[4-(dibutylamino)phenyl]squaraine

1998 ◽  
Vol 51 (7) ◽  
pp. 599 ◽  
Author(s):  
Geoffrey J. Ashwell ◽  
Patricia C. Williamson ◽  
Andrew Green ◽  
Gurmit S. Bahra ◽  
Christopher R. Brown
Keyword(s):  
Second Harmonic ◽  
Solid Substrate ◽  
Molecular Structures ◽  
High Mass ◽  
Ionization Mass ◽  
Langmuir Blodgett ◽  
Non Linear ◽  
Langmuir Blodgett Films ◽  
Linear Optical Properties ◽  
Linear Optical

Langmuir films of the title compound, 2,4-bis[4-(dibutylamino)phenyl]squaraine, Sq0, and its substituted analogues, Sq1 (monohydroxy) to Sq4 (tetrahydroxy), exhibit three well defined phases at the air–water interface: λmax 525–550 nm (H-aggregate); 660–670 nm (intermediate); 760–770 nm (J-aggregate). The monolayer spectra are influenced by the surface pressure and the number of hydroxy substituents and, when the monolayers are transferred to a solid substrate, there is a correlation between the linear and non-linear optical behaviour of the Langmuir-Blodgett films. Second-harmonic generation has been observed even though the unit molecular structures of two analogues, Sq0 and Sq4, are centric. The behaviour is aggregation-induced and there is evidence that the dyes associate in dilute solution. The electrospray ionization mass spectra exhibit peaks with high mass/charge (m/z) ratios; the data conform to the dimeric aggregate and, for solutions of two or more squaraines, corroborate the existence of heteromolecular associates.

Synthesis, structure and non-linear optical properties of new isostructural β-D-fructopyranose alkaline halide metal–organic frameworks: a theoretical and an experimental study

2017 ◽  
Vol 73 (4) ◽  
pp. 737-743 ◽  
Author(s):  
Domenica Marabello ◽  
Paola Antoniotti ◽  
Paola Benzi ◽  
Carlo Canepa ◽  
Leonardo Mortati ◽  
...  
Keyword(s):  
Optical Properties ◽  
Second Harmonic ◽  
Theoretical Calculations ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
Intrinsic Nature ◽  
Non Linear ◽  
Metal Organic ◽  
Linear Optical Properties ◽  
Linear Optical

In this work four metal–organic framework isomorphs, based on fructose and alkali-earth halogenides, were investigated to better understand the effect of the size of the cation and the different polarizability of the anion on the calculated hyperpolarizability and optical susceptibility, which are correlated to non-linear optical properties. The compounds were characterized by X-ray diffraction and the first hyperpolarizability and the second-order susceptibility were obtained from theoretical calculations. Furthermore, a new method to measure the second-harmonic (SH) efficiency on a small quantity of powder at different wavelengths of excitation was optimized and an attempt was made to assess the reduction of the SH intensity for small quantities of nano-crystals, in order to ascertain the possibility of applications in biological systems. The results of this work show that both the intrinsic nature of the anion and the induced dissociation of cations and anions by fructose play a role in the second-harmonic generating properties of such compounds.

Synthesis, structure, thermal and non-linear optical properties of L-argininium hydrogen selenite

2001 ◽  
Vol 57 (6) ◽  
pp. 828-832 ◽  
Author(s):  
E. de Matos Gomes ◽  
E. Nogueira ◽  
I. Fernandes ◽  
M. Belsley ◽  
J. A. Paixão ◽  
...  
Keyword(s):  
Optical Properties ◽  
Second Harmonic ◽  
Unit Cell Parameters ◽  
Scanning Calorimetry ◽  
Cell Parameters ◽  
Non Linear ◽  
Powder Samples ◽  
Linear Optical Properties ◽  
Linear Optical ◽  
Harmonic Power

L-Argininium hydrogen selenite (C6H15N4O2HSeO3) is a new semiorganic compound of the hydrogen selenite family with non-linear optical properties. The crystal lattice is monoclinic with unit-cell parameters a = 22.493 (5), b = 5.1624 (13), c = 9.730 (4) Å, β = 95.68 (3)°, V = 1124.3 (6) Å3, Z = 4, space group C2. Second-harmonic generation measurements performed on powder samples, using a Q-switched Nd:Yag laser (λ = 1064 nm), showed the second-harmonic power to be about twice that of urea. Differential scanning calorimetry measurements revealed the existence of a phase transition with onset at 289 K.

Experimental and Theoretical (ab initio and DFT) Analysis of UV-Vis Spectra, Thermodynamic Functions and Non-linear Optical Properties of 2-Chloro-3,4-Dimethoxybenzaldehyde

2015 ◽  
Vol 8 (2) ◽  
pp. 2122-2134
Author(s):  
Sarvendra Kumar ◽  
Rajesh Kumar ◽  
Jayant Teotia ◽  
M. K. Yadav
Keyword(s):  
Thermodynamic Functions ◽  
Title Compound ◽  
Density Functional ◽  
Structural Characteristics ◽  
Basis Sets ◽  
Ultraviolet Absorption Spectrum ◽  
Non Linear ◽  
Different Temperatures ◽  
Linear Optical Properties ◽  
Linear Optical

In the present work, UV- Visible spectra of 2-Chloro-3,4-Dimethoxybenzaldehyde (2,3,4-CDMB) compound  have been carried out experimentally and theoretically. The ultraviolet absorption spectrum of title compound in three solvents (Acetone, Diethyl Ether, CCl4) of different polarity were examined in the range of 200–500 nm. The structure of the molecule was optimized and the structural characteristics were determined by HF and DFT (B3LYP) methods with 6-31+G(d,p) and 6-311++G(d,p) as basis sets. The excitation energy, wavelength corresponds to absorption maxima () and oscillator strength (f) are calculated by Time-Dependent Density Functional Theory (TD-DFT) using B3LYP/6-31+G(d,p) and B3LYP/6-311++G(d,p) as basis sets. The electric dipole moment (μ), polarizability (α) and the first hyperpolarizability (β ) have been computed to evaluate the non-linear optical (NLO) response of the investigated compound by HF and DFT (B3LYP) with already mentioned basis sets. Thermodynamic functions of the title compound at different temperatures were also calculated.

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