scholarly journals Cellulose Acetate and Supercritical Carbon Dioxide: Membranes, Nanoparticles, Microparticles and Nanostructured Filaments

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 162 ◽  
Author(s):  
Stefano Cardea ◽  
Iolanda De Marco
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Organic Solvent ◽  
Cellulose Acetate ◽  
Polymer Concentration ◽  
Operating Conditions ◽  
Experimental Plant ◽  
Operating Pressure ◽  
Industrial Sectors ◽  
Supercritical Carbon

Cellulose acetate (CA) is a very versatile biocompatible polymer used in various industrial sectors. Therefore, depending on the application, different morphologies are required. Different processes at industrial scale are commonly employed to obtain CA micro or nanoparticles (discontinuous structures) or CA membranes (continuous structures with discontinuities). In this work, two supercritical carbon dioxide (scCO2) based techniques, such as the semi-continuous supercritical antisolvent process (SAS) and the supercritical fluid phase inversion process, in which scCO2 plays the role of antisolvent, were employed. Varying the kind of organic solvent used to prepare the polymeric solution, the polymer concentration, and operating pressure and temperature, it was possible to tune the characteristics of the obtained material. In particular, using acetone as the organic solvent, filaments constituted by nanoparticles, expanded microparticles, nanoparticles with a mean diameter lower than 80 nm, and microporous membranes were obtained, varying the operating conditions. The attainment of spherical micron-sized particles was instead achieved using a mixture of acetone and DMSO as the organic solvent. Therefore, the versatility of the supercritical carbon dioxide-based techniques has been confirmed, and it was possible to obtain, using a single experimental plant, various morphologies of cellulose acetate (with controllable particles’ or pores’ diameters) by varying the operating conditions.

Extraction and Identification of Vitamin E from Pithecellobium Jiringan Seeds Using Supercritical Carbon Dioxide

2015 ◽  
Vol 74 (7) ◽  
Author(s):  
Mohd Azizi Che Yunus ◽  
Salman Zhari ◽  
Saharudin Haron ◽  
Nur Husnina Arsad ◽  
Zuhaili Idham ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Vitamin E ◽  
Supercritical Carbon Dioxide ◽  
Potential Method ◽  
Operating Conditions ◽  
Oil Yield ◽  
Flight Mass Spectrometry ◽  
Carbon Dioxide Extraction ◽  
Natural Herb ◽  
Supercritical Carbon

Pithecellobium Jiringan (P. Jiringan) is traditionally known as natural herb consists of several medicinal compounds (vitamin E). Supercritical carbon dioxide extraction (SC-CO2) has been proven as potential method to extract interest compound from herbs. By altering pressure and temperature, the specific compound can be extracted. In this study, the SC-CO2 operating conditions are pressure (20.68 MPa to 55.16 MPa) and temperature (40°C to 80°C) in one hour extraction regime was used to extract vitamin E from P. jiringan. The quantification of vitamin E was analysed with Gas Chromatography Time of Flight Mass Spectrometry (GC-TOF-MS). The responses are overall oil yield and vitamin E yield. The overall oil yield was obtained at the highest condition of 55.16 MPa and 80°C with asymptotic yield of 8.06%. In contrast, the highest amount of vitamin E obtained is 0.0458mg/g sample (80.14 ppm) at the lowest extraction condition of 20.68 MPa and 40ᵒC.

Microcellular Polymeric Foams (MPFs) Generated Continuously in Supercritical Carbon Dioxide

2000 ◽  
Vol 629 ◽  
Author(s):  
Srinivas Siripurapu ◽  
Yvon J. Gay ◽  
Joseph R. Royer ◽  
Joseph M. DeSimone ◽  
Saad A. Khan ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Vinylidene Fluoride ◽  
Amorphous Polymer ◽  
Extrusion Process ◽  
Operating Conditions ◽  
Polymeric Foams ◽  
Poly Vinylidene Fluoride ◽  
Cell Densities ◽  
Supercritical Carbon

ABSTRACTMicrocellular polymeric foams (MPFs) hold tremendous promise for engineering applications as substitutes to their solid analogs in light of reduced manufacturing/materials costs and improved properties. We present a two-part study addressing the generation of such materials in the presence of supercritical carbon dioxide (scCO2). The first part describes the production of polystyrene MPFs in a continuous extrusion process, as well as the effect of operating conditions such as temperature and CO2 concentration on foam morphology. The second part discusses microcellular foaming of poly (vinylidene fluoride) (PVDF), a semicrystalline polymer, via blending with the amorphous polymer poly (methyl methacrylate) PMMA. Foams of pure PVDF possess ill-defined morphologies, whereas those of PVDF-PMMA blends show an improvement with cell sizes on the order of 10 mm or less and cell densities in excess of 109 cells/cm3.

Coatings from Liquid and Supercritical Carbon Dioxide

2004 ◽  
Author(s):  
Yury Chernyak ◽  
Florence Henon
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Physical Properties ◽  
Organic Liquid ◽  
Spray Coating ◽  
Organic Liquids ◽  
Liquid Density ◽  
Operating Pressure ◽  
Interfacial Tensions ◽  
Supercritical Carbon

This chapter describes several aspects of the use of carbon dioxide as a solvent or cosolvent in coating applications. The primary impetus for using carbon dioxide for this purpose has been the alleviation of volatile emissions and liquid solvent wastes. However, the special physical properties of liquid and supercritical carbon dioxide may offer some processing advantages over conventional organic or aqueous solvents. Liquid carbon dioxide is quite compressible, and a reduction in temperature results not only in a reduction in the operating pressure, but also in a significant increase in the liquid density to values of approximately 0.9 g/cm3. At these high liquid densities, carbon dioxide exhibits improved solvent performance, but with much lower viscosities and interfacial tensions than aqueous or organic liquid solvents. Under supercritical conditions, carbon dioxide also exhibits high densities, low viscosities, and improved solvent power. Low viscosities and interfacial tensions tend to facilitate the transport of the solvents into any crevices or imperfections on the surface to be covered, and this might prove advantageous in the coating of patterned or etched surfaces. Since carbon dioxide dissolves and diffuses easily into many different polymers and organic liquids, it can also be used to reduce the viscosity of coating solutions. Whether in the liquid or the supercritical state, the temperature and pressure of the mixture can be used to control its physical properties in ways that are impossible to achieve with traditional solvents. These distinguishing features have raised the level of industrial interest in carbon dioxide as a solvent for coating applications, beyond those based solely on environmental concerns. In this chapter, we will discuss current applications and research on the use of CO2 as a solvent for coatings. The first section deals with spray coating from supercritical CO2. Subsequent sections deal with the use of liquid coatings, such as spin and free meniscus coatings, and impregnation coatings. Since the start of the 20th century (ca. 1907), atomization has been the basis for conventional spray coating applications (Muirhead, 1974). Typically, atomization is caused by high shear of the coating fluid in air, leading to droplet or particle formation.

Visualization of Supercritical Carbon Dioxide Flow Through a Converging-Diverging Nozzle

2019 ◽  
Author(s):  
Chang Hyeon Lim ◽  
Gokul Pathikonda ◽  
Sandeep Pidaparti ◽  
Devesh Ranjan
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
High Speed ◽  
Operating Conditions ◽  
Higher Plant ◽  
Two Phase ◽  
Pressure Profiles ◽  
Flow Through ◽  
Supercritical Carbon

Abstract Supercritical carbon dioxide (sCO2) power cycles have the potential to offer a higher plant efficiency than the traditional Rankine superheated/supercritical steam cycle or Helium Brayton cycles. The most attractive characteristic of sCO2 is that the fluid density is high near the critical point, allowing compressors to consume less power than conventional gas Brayton cycles and maintain a smaller turbomachinery size. Despite these advantages, there still exist unsolved challenges in design and operation of sCO2 compressors near the critical point. Drastic changes in fluid properties near the critical point and the high compressibility of the fluid pose several challenges. Operating a sCO2 compressor near the critical point has potential to produce two phase flow, which can be detrimental to turbomachinery performance. To mimic the expanding regions of compressor blades, flow through a converging-diverging nozzle is investigated. Pressure profiles along the nozzle are recorded and presented for operating conditions near the critical point. Using high speed shadowgraph images, onset and growth of condensation is captured along the nozzle. Pressure profiles were calculated using a one-dimensional homogeneous equilibrium model and compared with experimental data.

Analysis of Advanced Supercritical Carbon Dioxide Power Cycles With a Bottoming Cycle for Concentrating Solar Power Applications

2013 ◽  
Vol 136 (1) ◽  
Author(s):  
Saeb M. Besarati ◽  
D. Yogi Goswami
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Solar Power ◽  
Waste Heat ◽  
Operating Conditions ◽  
Working Fluid ◽  
Brayton Cycle ◽  
Concentrating Solar Power ◽  
Working Fluids ◽  
Supercritical Carbon

A number of studies have been performed to assess the potential of using supercritical carbon dioxide (S-CO2) in closed-loop Brayton cycles for power generation. Different configurations have been examined among which recompression and partial cooling configurations have been found very promising, especially for concentrating solar power (CSP) applications. It has been demonstrated that the S-CO2 Brayton cycle using these configurations is capable of achieving more than 50% efficiency at operating conditions that could be achieved in central receiver tower type CSP systems. Although this efficiency is high, it might be further improved by considering an appropriate bottoming cycle utilizing waste heat from the top S-CO2 Brayton cycle. The organic Rankine cycle (ORC) is one alternative proposed for this purpose; however, its performance is substantially affected by the selection of the working fluid. In this paper, a simple S-CO2 Brayton cycle, a recompression S-CO2 Brayton cycle, and a partial cooling S-CO2 Brayton cycle are first simulated and compared with the available data in the literature. Then, an ORC is added to each configuration for utilizing the waste heat. Different working fluids are examined for the bottoming cycles and the operating conditions are optimized. The combined cycle efficiencies and turbine expansion ratios are compared to find the appropriate working fluids for each configuration. It is also shown that combined recompression-ORC cycle achieves higher efficiency compared with other configurations.

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