scholarly journals A Comprehensive Review on Water Diffusion in Polymers Focusing on the Polymer–Metal Interface Combination

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 138 ◽  
Author(s):  
Chao Yang ◽  
Xiao Xing ◽  
Zili Li ◽  
Shouxin Zhang
Keyword(s):  
Water Clusters ◽  
Water Diffusion ◽  
Metal Interface ◽  
Open Questions ◽  
Capacitance Method ◽  
Polymer Metal ◽  
Polymer Interactions ◽  
Diffusion In Polymers ◽  
Analysis Of Error ◽  
Metal Polymer

Water diffusion in polymers is relevant to a broad range of physicochemical phenomena and technological processes. Although many fields contributed to rapid progress in the fundamental knowledge of water–polymer interactions, detailed understandings come mainly from interpreting numerous experiments. These studies showed that a remarkably rich variety of diffusion forms between water and even seemingly simple polymers. In this review, focusing on the gravimetric and capacitance method, we discuss contradictions and problems existing for water diffusion in polymers in detail from perspectives of experiments and models, focusing on the analysis of error derived from widely used methods, especially for the Brasher–Kingsbury equation. We also provide a perspective on outstanding problems, challenges, and open questions, including water clusters, relaxation, and electrochemical reactions at the metal/polymer interface, as well as expanding the theoretical prospective.

Metal-Polymer Interactions in a Polymer/Metal Nanocomposite

1997 ◽  
Vol 78 (26) ◽  
pp. 5006-5009 ◽  
Author(s):  
Douglas H. Cole ◽  
Kenneth R. Shull ◽  
L. E. Rehn ◽  
P. Baldo
Keyword(s):  
Polymer Metal ◽  
Polymer Interactions ◽  
Metal Nanocomposite ◽  
Metal Polymer

scholarly journals A Mixed Numerical-Experimental Method to Characterize Metal-Polymer Interfaces for Crash Applications

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 818
Author(s):  
Jonas Richter ◽  
Moritz Kuhtz ◽  
Andreas Hornig ◽  
Mohamed Harhash ◽  
Heinz Palkowski ◽  
...  
Keyword(s):  
Experimental Parameter ◽  
Dissimilar Materials ◽  
Calibration Method ◽  
Parameter Determination ◽  
Failure Behavior ◽  
Cohesive Elements ◽  
Interface Failure ◽  
Wide Range ◽  
Polymer Metal ◽  
Metal Polymer

Metallic (M) and polymer (P) materials as layered hybrid metal-polymer-metal (MPM) sandwiches offer a wide range of applications by combining the advantages of both material classes. The interfaces between the materials have a considerable impact on the resulting mechanical properties of the composite and its structural performance. Besides the fact that the experimental methods to determine the properties of the single constituents are well established, the characterization of interface failure behavior between dissimilar materials is very challenging. In this study, a mixed numerical–experimental approach for the determination of the mode I energy release rate is investigated. Using the example of an interface between a steel (St) and a thermoplastic polyolefin (PP/PE), the process of specimen development, experimental parameter determination, and numerical calibration is presented. A modified design of the Double Cantilever Beam (DCB) is utilized to characterize the interlaminar properties and a tailored experimental setup is presented. For this, an inverse calibration method is used by employing numerical studies using cohesive elements and the explicit solver of LS-DYNA based on the force-displacement and crack propagation results.

INFLUENCE OF THE DYNAMICS OF FORCED MOTION ON THE STATIC FRICTION IN METAL-POLYMER SLIDING PAIRS

Tribologia ◽  
2021 ◽  
Vol 295 (1) ◽  
pp. 21-26
Author(s):  
Mariusz Opałka ◽  
Wojciech Wieleba ◽  
Angelika Radzińska
Keyword(s):  
Relative Motion ◽  
Friction Pair ◽  
Polymeric Materials ◽  
Static Friction ◽  
Metallic Materials ◽  
Test Results ◽  
Friction Resistance ◽  
Rate Of Increase ◽  
Polymer Metal ◽  
Metal Polymer

The resistance during the frictional interaction of polymeric materials with metallic materials is characterized by a significant dependence on the dynamics of the motion inputs. In a metal-polymer friction pair, the static friction resistance during standstill under load depends on the rate of growth of the force causing the relative motion. Tribological tests of selected (polymer-metal) sliding pairs were carried out. The selected polymers were polyurethane (TPU), polysulfone (PSU), and silicone rubber (SI). They interacted with a pin made of normalized C45 steel under unitary pressure p = 0.5 MPa in dry friction conditions at different gradients of the force driving the relative motion (dF/dt = 0.1-20 [N/s]). The static friction coefficient of the selected sliding pairs was determined on the basis of the recorded static friction force values. The test results show a significant influence of the rate of increase in the motion driving force on the values of static friction resistance. This is mainly due to the viscoelastic properties of polymers.

Effect of the Electrode Material on Electronic Switching in a Metal–Polymer–Metal Structure

2021 ◽  
Vol 15 (3) ◽  
pp. 601-606
Author(s):  
A. F. Galiev ◽  
A. A. Lachinov ◽  
D. D. Karamov ◽  
A. N. Lachinov ◽  
A. R. Yusupov ◽  
...  
Keyword(s):  
Electrode Material ◽  
Metal Structure ◽  
Electronic Switching ◽  
Polymer Metal ◽  
Metal Polymer

The Competition between Adhesive and Cohesive Fracture at Amicro-Patterned Polymer-Metal Interface

2013 ◽  
Vol 577-578 ◽  
pp. 225-228 ◽  
Author(s):  
Olaf van der Sluis ◽  
Joris J.C. Remmers ◽  
M.A.C. Thurlings ◽  
B.J. Welling ◽  
Sander P.M. Noijen
Keyword(s):  
Crack Deflection ◽  
Surface Roughening ◽  
Adhesive Failure ◽  
Cohesive Failure ◽  
Metal Interface ◽  
Cohesive Fracture ◽  
Micro Patterning ◽  
Polymer Metal ◽  
Metal Interfaces ◽  
Point Bend

It is Common Practice for Polymer-Metal Interfaces, Frequently Encountered in Microelec-Tronic Devices, to Improve Adhesion by Surface Roughening or Micro-Patterning. the Competitionbetween Adhesive Fracture and Cohesive Fracture in the Vicinity of a Patterned Interface, i.e., Inter-Face Crack Deflection, is One of these Key Mechanisms that Contribute Significantly to the Macroscopicadhesion. in this Paper, these Fracture Phenomena are Described Simultaneously by Cohesive Zoneelements with an Exponential Traction-Separation Law (TSL) for the Adhesive Failure and an Initiallyrigid, Exponentially Decaying, TSL for the Cohesive Failure. it is Demonstrated that the Conditions Atwhich Crack Kinking Occurs are Dominated by Fracture Strength Values as Opposed to the Commonlyused Fracture Toughness Values. Experimental Verification is Performed by Means of Four Point Bend-Ing Tests on Specifically Designed Micro-Patterned Polymer-Metal Samples.

Piezoelectric actuation of factigue crack growth along polymer/metal interface

2001 ◽  
pp. 187-192
Author(s):  
T. Du ◽  
M. Liu ◽  
S. Seghi ◽  
K.J. Hsia ◽  
J. Economy ◽  
...  
Keyword(s):  
Crack Growth ◽  
Piezoelectric Actuation ◽  
Metal Interface ◽  
Polymer Metal
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