scholarly journals Enhanced Electrical Properties of Polyethylene-Graft-Polystyrene/LDPE Composites

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 124 ◽  
Author(s):  
Shuwei Song ◽  
Hong Zhao ◽  
Zhanhai Yao ◽  
Zhiyu Yan ◽  
Jiaming Yang ◽  
...  

Nanocomposite dielectrics show a great potential application in high voltage direct current cables for their obvious improvements in electrical properties. In the present manuscript, nanocomposite composed of low-density polyethylene and nanoscale polystyrene particles is studied by using low-density polyethylene grafted with polystyrene molecule. Fourier-transform infrared spectra reveal successful grafting of the polystyrene molecule onto the low-density polyethylene chain and the scanning electron microscope image shows the homogeneously dispersed nanoscale polystyrene particles. The presence of the polystyrene nanoparticles obviously improves the dielectric properties, such as the direct current breakdown strength and space charge inhibition. The conductivity and thermally stimulated current characteristics imply the deep traps in the composite increase obviously. Density functional theory calculation reveals that the grafted polystyrene can accommodate both shallow and deep electron carriers, and the depth of the hole traps are as deep as 2.07 eV.

2016 ◽  
Vol 30 (1) ◽  
pp. 76-81 ◽  
Author(s):  
Changming Li ◽  
Sixu Duan ◽  
Chengcheng Zhang ◽  
Jian Zhang ◽  
Baozhong Han

In this article, polyaniline (PANI) nanofibers were prepared and added to low-density polyethylene (LDPE) to produce PANI nanofibers/LDPE composites. LDPE and the composites were tested for direct current (DC) conductivity, breakdown strength, and space charge characteristics. The results suggested that DC breakdown strength of PANI nanofibers/LDPE composites significantly declined once PANI was added, and the decline was more evident with the increase of PANI nanofibers. Meanwhile, the addition of PANI nanofibers contributed to a decrease in the conductivity of LDPE. As the content of PANI nanofibers increased, the conductivity of the composites declined first and then raised. DC conductivity properties of LDPE could be improved by adding an appropriate amount of PANI nanofibers. Compared with LDPE, the space charge distribution was changed in LDPE due to the addition of PANI nanofibers. With the increase of content of PANI nanofibers, the amount of space charges close to the electrodes decreased gradually.


2018 ◽  
Vol 32 (3) ◽  
pp. 297-311 ◽  
Author(s):  
Yousef Ahmad Mubarak ◽  
Raghda Talal Abdulsamad

This work was intended to provide an understanding of the effect of microcrystalline cellulose (MCC) on the mechanical properties of low-density polyethylene (LDPE). The impact resistance and the tensile properties of low-density LDPE/MCC composites were investigated. The weight fraction of MCC was varied at (0, 0.5, 1, 2.5, 5, 10, 20, and 30 wt%). The obtained blends were then used to prepare the required tensile and impact testing samples by hot compression molding technique. It has been found that MCC has a strong influence on the mechanical properties of LDPE. At a low MCC weight fraction, there was a little improvement in the ultimate strength, fracture stress, and elongation at break, but at a high MCC weight fraction, the tensile properties were deteriorated and reduced significantly. The addition of 1 wt% MCC to LDPE enhanced the mentioned properties by 10, 25, and 6%, respectively. While at 30 wt% MCC, these properties were lowered by 36, 25, and 96%. The elastic modulus of LDPE composites was improved on all MCC weight fractions used in the study, at 20 wt% MCC, an increase in the elastic modulus by 12 folds was achieved. On the other hand and compared with the impact strength of pure LDPE, the addition of MCC particles enhanced the impact strength, the highest value obtained was for LDPE composites filled with 10 wt% MCC where the impact strength enhanced by two folds.


2021 ◽  
Vol 28 (4) ◽  
pp. 1181-1188
Author(s):  
Liuhao Jiang ◽  
Shihang Wang ◽  
Liuqing Yang ◽  
Shengtao Li ◽  
Yang Feng ◽  
...  

2013 ◽  
Vol 47 (4) ◽  
pp. 365-372 ◽  
Author(s):  
S Sultana ◽  
HP Nur ◽  
T Saha ◽  
M Saha

In this research work, cellulosic waste mango (Mangifera indica) saw dust used as the reinforcing material with low density polyethylene (LDPE). A number of samples of saw dust reinforced low density polyethylene (LDPE) composites were prepared by compression moulding technique. In order to improve the mechanical properties of saw dust-LDPE composites, unbleached raw saw dust fibers were modified by oxidation using sodium hypochlorite. FT-IR spectroscopic and scanning electron micrograph (SEM) analyses were done and the results showed the evidence of positive oxidation reaction. The effects of oxidized saw dust on the performance of oxidized saw dust reinforced LDPE composites were studied comparing with the raw saw dust-LDPE composites. The effects of fiber content on the physico-mechanical properties of composites were also studied by preparing the composites with different percentage of fiber loading (from 7.5 wt% to 30 wt%) for each type of composite. Mechanical properties such as tensile strength, tensile modulus, elongation at break, flexural strength, flexural modulus of the resulting composite were measured. Better results were obtained from oxidized saw dust-LDPE composites. Scanning electron micrograph and water absorption tests were carried out for all composites and improved results were found for oxidized saw dust-LDPE composites. Bangladesh J. Sci. Ind. Res. 47(4), 365-372, 2012 DOI: http://dx.doi.org/10.3329/bjsir.v47i4.14065


Sign in / Sign up

Export Citation Format

Share Document