scholarly journals Study on the Printability through Digital Light Processing Technique of Ionic Liquids for CO2 Capture

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1932 ◽  
Author(s):  
Matteo Gillono ◽  
Annalisa Chiappone ◽  
Lorenzo Mendola ◽  
Manuel Gomez Gomez ◽  
Luciano Scaltrito ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
3D Printing ◽  
Co2 Capture ◽  
Chemical Properties ◽  
Processing Technique ◽  
High Complexity ◽  
Digital Light Processing ◽  
Physical Chemical

Here we present new 3D printable materials based on the introduction of different commercially available ionic liquids (ILs) in the starting formulations. We evaluate the influence of these additives on the printability of such formulations through light-induced 3D printing (digital light processing—DLP), investigating as well the effect of ionic liquids with polymerizable groups. The physical chemical properties of such materials are compared, focusing on the permeability towards CO2 of the different ILs present in the formulations. At last, we show the possibility of 3D printing high complexity structures, which could be the base of new high complexity filters for a more efficient CO2 capture.

scholarly journals Porous cage-derived nanomaterial inks for direct and internal three-dimensional printing

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Tangi Aubert ◽  
Jen-Yu Huang ◽  
Kai Ma ◽  
Tobias Hanrath ◽  
Ulrich Wiesner
Keyword(s):  
3D Printing ◽  
Structural Control ◽  
High Surface ◽  
High Surface Area ◽  
Three Dimensional ◽  
Processing Technique ◽  
Advanced Materials ◽  
Host Matrix ◽  
Digital Light Processing ◽  
Three Dimensional Printing

Abstract The convergence of 3D printing techniques and nanomaterials is generating a compelling opportunity space to create advanced materials with multiscale structural control and hierarchical functionalities. While most nanoparticles consist of a dense material, less attention has been payed to 3D printing of nanoparticles with intrinsic porosity. Here, we combine ultrasmall (about 10 nm) silica nanocages with digital light processing technique for the direct 3D printing of hierarchically porous parts with arbitrary shapes, as well as tunable internal structures and high surface area. Thanks to the versatile and orthogonal cage surface modifications, we show how this approach can be applied for the implementation and positioning of functionalities throughout 3D printed objects. Furthermore, taking advantage of the internal porosity of the printed parts, an internal printing approach is proposed for the localized deposition of a guest material within a host matrix, enabling complex 3D material designs.

Role of MgxCa1−xCO3 on the physical–chemical properties and cyclic CO2 capture performance of dolomite by two-step calcination

2015 ◽  
Vol 614 ◽  
pp. 199-206 ◽  
Author(s):  
Ke Wang ◽  
Dongtai Han ◽  
Pengfei Zhao ◽  
Xiumeng Hu ◽  
Zeguang Yin ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Chemical Properties ◽  
Physical Chemical

Synthesis and physical-chemical properties of ionic liquids based on 1-n-butyl-3-methylimidazolium cation

1998 ◽  
Vol 95 (7) ◽  
pp. 1626-1639 ◽  
Author(s):  
P. A.Z. Suarez ◽  
S. Einloft ◽  
J. E.L. Dullius ◽  
R. F. de Souza ◽  
J. Dupont
Keyword(s):  
Ionic Liquids ◽  
Chemical Properties ◽  
Physical Chemical

Physical-chemical properties of chiral ionic liquids derived from the phenylethylamine enantiomers

2017 ◽  
Vol 236 ◽  
pp. 435-444 ◽  
Author(s):  
Esdrey Rodríguez-Cárdenas ◽  
Judith Cardoso-Martínez ◽  
Antonio Nieto-Camacho ◽  
Bernardo A. Frontana-Uribe
Keyword(s):  
Ionic Liquids ◽  
Chemical Properties ◽  
Chiral Ionic Liquids ◽  
Physical Chemical

scholarly journals High-Complexity WO3-Based Catalyst with Multi-Catalytic Species via 3D Printing

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 840 ◽  
Author(s):  
Xiaofeng Wang ◽  
Wei Guo ◽  
Raed Abu-Reziq ◽  
Shlomo Magdassi
Keyword(s):  
3D Printing ◽  
Heterogeneous Catalysts ◽  
Three Dimensional ◽  
Structural Constraints ◽  
High Complexity ◽  
Digital Light Processing ◽  
New Approach ◽  
Complex Shapes ◽  
Metallic Salts ◽  
3D Printed

Three-dimensional (3D) printing has recently been introduced into the field of chemistry as an enabling tool employed to perform reactions, but so far, its use has been limited due to material and structural constraints. We have developed a new approach for fabricating 3D catalysts with high-complexity features for chemical reactions via digital light processing printing (DLP). PtO2-WO3 heterogeneous catalysts with complex shapes were directly fabricated from a clear solution, composed of photo-curable organic monomers, photoinitiators, and metallic salts. The 3D-printed catalysts were tested for the hydrogenation of alkynes and nitrobenzene, and displayed excellent reactivity in these catalytic transformations. Furthermore, to demonstrate the versatility of this approach and prove the concept of multifunctional reactors, a tungsten oxide-based tube consisting of three orderly sections containing platinum, rhodium, and palladium was 3D printed.

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